Search results for "SETS"

Excited State N−H Tautomer Selectivity in the Singlet Energy Transfer of a Zinc(II)-Porphyrin-Truxene-Corrole Assembly

2017

International audience; An original corrole-containing polyad for S-1 energy transfer, in which one zinc(II)-porphyrin donor is linked to two free-base corrole acceptors by a truxene linker, is reported. This polyad exhibits a rapid zinc(II)-porphyrin*free-base corrole transfer (4.83x10(10)s(-1); 298K), even faster than the tautomerization in the excited state processes taking advantage of the good electronic communication provided by the truxene bridge. Importantly, the energy transfer process shows approximately 3-fold selectivity for one corrole N-H tautomer over the other even at low temperature (77K). This selectivity is due to the difference in the J-integral being effective in both t…

Metal Dependence on the Bidirectionality and Reversibility of the Singlet Energy Transfer in Artificial Special Pair-Containing Dyads

2017

International audience; The demetalation of a precursor dyad, 3, built upon a zinc(II)-containing artificial special pair and free-base antenna, leads to a new dyad, 4, for singlet energy transfer composed of cofacial free-base porphyrins (acceptor), [Fb](2) bridged by a 1,4-C6H4 group to a free-base antenna (donor), [Fb]. This dyad exhibits the general structure [M](2)-C6H4-[Fb], where [M](2) = [Fh](2), and completes a series reported earlier, where [M](2) = [Mg](2) (2) and [Zn](2) (3). The latter dyads exhibit a bidirectional energy-transfer process at 298 K for 2 and at 77 K for 3. Interestingly, a very scarce case of cycling process is observed for the zinc-containing dyad at 298 K. The…

Ferromagnetic exchange in a twisted, oxime-bridged [mniii2] dimer

2012

Journal article The dimeric complex [MnIII2(Naphth-sao)2(Naphth-saoH)2(MeOH)2][middle dot]4MeOH (1[middle dot]4MeOH), acts as a simple model complex with which to examine the magneto-structural relationship in polymetallic, oxime-bridged MnIII complexes. Dc magnetic susceptibility studies reveal that ferromagnetic exchange is mediated through the heavily twisted Mn-O-N-Mn moiety (J = +1.24 cm-1) with magnetisation measurements at low temperatures and high fields suggesting significant anisotropy. Simulations of high field, high frequency EPR data reveal a single ion anisotropy, D(MnIII) = -3.94 cm-1. Theoretical studies on simplified model complexes of 1 reveal that calculated values of the…

The association between stress mindset and physical and psychological wellbeing : testing a stress beliefs model in police officers

2020

Objective: Emergency service workers like police officers experience high levels of stress in the course of their regular duties. Holding particular stress mindsets may help to mitigate the deleterious effects of stress and promote wellbeing in workers experiencing regular stress. The study aimed to examine the processes by which stress mindsets relate to health and wellbeing in police officers. A stress beliefs model in which perceived somatic symptoms and coping behaviours mediate effects of stress mindsets on outcomes was tested. Design: Police officers (N = 134) completed an online cross-sectional survey. Main outcome measures: Perceived somatic symptoms, proactive coping behaviours, ph…

Scalable robust clustering method for large and sparse data

2018

Datasets for unsupervised clustering can be large and sparse, with significant portion of missing values. We present here a scalable version of a robust clustering method with the available data strategy. Moreprecisely, a general algorithm is described and the accuracy and scalability of a distributed implementation of the algorithm is tested. The obtained results allow us to conclude the viability of the proposed approach. peerReviewed

Tunnettuja salapoliisihahmoja ja rikosetsiviä

Generalized dimension estimates for images of porous sets in metric spaces

2016

Structure of equilibrium states on self-affine sets and strict monotonicity of affinity dimension

2016

A fundamental problem in the dimension theory of self‐affine sets is the construction of high‐dimensional measures which yield sharp lower bounds for the Hausdorff dimension of the set. A natural strategy for the construction of such high‐dimensional measures is to investigate measures of maximal Lyapunov dimension; these measures can be alternatively interpreted as equilibrium states of the singular value function introduced by Falconer. While the existence of these equilibrium states has been well known for some years their structure has remained elusive, particularly in dimensions higher than two. In this article we give a complete description of the equilibrium states of the singular va…

Juridiskā zinātne, Nr. 12

2019

The publishing of Journal “Law” of the University of Latvia is financed by the Faculty of Law of the University of Latvia. The publishing of issue No. 11 is supported by “Eversheds Sutherland Bitāns” Law Office.

Modeling of female human body shapes for apparel design based on cross mean sets

2014

This paper is concerned with a method to build prototypes of human bodies that can be used for apparel design. One of the most important issues in the apparel development process is to define a sizing system to provide a good fitting for the majority of the population. Since anthropometric measures do not present the same linear growth with size in each dimension, it is very important to find a prototype that represents as accurately as possible each class in the sizing system. In this paper we propose a method based on the concept of random compact mean set to define prototypes in apparel design. From a cloud of 3D points obtained with a 3D scanner a solid that represents the human body is…