Search results for "SHIFT"

XPS study of pumice-supported palladium and platinum catalysts

1992

An XPS study has been performed on samples of monometallic of palladium and platinum and on bimetallic Pd-Pt catalysts supported on pumice. A negative shift of about 0.5 eV in the Pd 3d and Pt 4f binding energies of the catalysis relative to the energies of the same levels in the pure metals suggested an increase in the electron density in both metals. A quantitative XPS analysis indicated that the supported metals did not modify the surface atomic composition of pumice

Physicochemical properties of Ru(bpy)32+ entrapped in silicate bulks and fiber thin films prepared by the sol–gel method

1999

Silicate porous xerogels doped with ruthenium bipyridine (Ru(bpy)32+) complex have been obtained in the bulk form and in thin films on optical fibers. The hypsochromic shifts in the absorption and emission maxima are accompanied by fourfold increase in the lifetimes of the entrapped complex. The temperature-dependent lifetimes reveal that silicate xerogels induce two competing thermally activated processes in the excited state decay of the immobilized complex. The excited state lifetimes of the doped bulk xerogels and the fibers coated with thin films containing Ru(bpy)32+ are virtually identical to those obtained for the fibers coated with additional gas-impermeable layers.

2016

Light shifts are an important source of noise and systematics in optically pumped magnetometers. We demonstrate that the long spin-coherence time in paraffin-coated cells leads to spatial averaging of the vector light shift over the entire cell volume. This renders the averaged vector light shift independent, under certain approximations, of the light-intensity distribution within the sensor cell. Importantly, the demonstrated averaging mechanism can be extended to other spatially varying phenomena in anti-relaxation-coated cells with long coherence times.

DFT calculations of structures, 13C NMR chemical shifts and Raman RBM mode of simple models of ultra small diameter (4,0) zigzag hydroxylated single …

2012

Abstract Selected acenes, cyclic acenes and model zigzag (4,0) single wall carbon nanotubes (SWCNTs) with one hydroxylic group at the open end were fully optimized at the B3LYP/6-31G* level of theory. The impact of molecule size on the B3LYP/pcS-2 calculated 13 C NMR chemical shifts was studied to characterize pristine and tip-monofunctionalized ultra narrow SWCNTs. The harmonic frequency of Raman radial breathing mode (RBM) was determined for monohydroxylated cyclic acenes and correlated with their diameter. A regular convergence of selected CC bond lengths, RBM frequency and carbon chemical shifts upon increasing the size of the systems was observed and fitted toward very large systems wi…

In-fiber time-resolved acousto-optics

2014

Time-resolved in-fiber acousto-optics permit the measurement of sub-ppm perturbations of the modal dispersion curves along sections of fiber exceeding 1 m long, with a spatial resolution in the order of few cm.

Dispersion induced effects of high-order optical sidebands in the performance of millimeter-wave fiber-optic links

2006

In this paper, chirped fiber Bragg gratings (CFBGs) are proposed as signal-phase controllers for microwave-photonic wireless downstream fiber links. The effect of high-order modulation optical sidebands that disturbs the output mm-wave signal due to the chromatic dispersion induced by the gratings is studied theoretically and experimentally. The 1st and 2nd mm-wave harmonics of the output signal have been measured for conventional intensity modulation and for intensity modulation with optical carrier suppression. In the last case, data transmission at 2.5 Gb/s is demonstrated through a chirped grating of 280 ps/nm dispersion in a 40-GHz modulated link.

Extremely efficient evaluation of chromatic dispersion in realistic photonic crystal fibers

2004

We present a fast and accurate procedure for the evaluation of chromatic dispersion in photonic crystal fibers. It combines an iterative Fourier technique to compute the propagation constant at any fixed wavelength and an analytical approach to calculate its derivatives.

Suppression of pulse pedestal using nonlinear optical loop mirrors in grating-compensated dispersion-managed fiber transmission systems

2006

Pulse pedestal suppression by nonlinear optical loop mirrors is utilized to reduce the intersymbol interference caused by the group delay ripples of a real grating profile in dispersion-managed communication systems compensated by chirped fiber gratings.

Muon Knight-shift measurements in CeSn3and some isostructural rare-earth compounds

1984

Time-domain fiber laser hydrogen sensor.

2004

We report a novel scheme for a fiber-optic hydrogen sensor based on an erbium-doped fiber laser with a palladium-coated tapered fiber within the laser cavity. The tapered fiber acts as a hydrogen-sensing element. When the sensing element is exposed to a hydrogen atmosphere, its attenuation decreases, changing the cavity losses and leading to a modification of the laser transient. The hydrogen concentration is obtained by simple measurement of the buildup time of the laser. This technique translates the measurement of hydrogen concentration into the time domain, and it can be extended to many intensity-based fiber sensors. Relative variations in the buildup time of up to 55% at an increase o…