Search results for "SMALL-ANGLE NEUTRON"

showing 10 items of 111 documents

Inelastic neutron and low-frequency Raman scattering in niobium-phosphate glasses: the role of spatially fluctuating elastic and elasto-optic constan…

2011

We investigate the low-frequency enhancement of vibrational excitations ('boson peak') in niobium-phosphate glasses through the combination of inelastic neutron and polarization-resolved Raman scattering. The spectra of these glasses reveal an enhancement of the vibrational density of states and of the cross section for spontaneous Raman scattering in the frequency range below 150?cm ? 1. A recent theoretical model that is based on fluctuating elastic and elasto-optic (Pockels) constants provides a unified description of the measured neutron and Raman spectra, including the depolarization ratio.

Condensed matter physicsChemistryInelastic scatteringNeutron scatteringCondensed Matter PhysicsMolecular physicsSmall-angle neutron scatteringsymbols.namesakeX-ray Raman scatteringsymbolsDepolarization ratioGeneral Materials ScienceCoherent anti-Stokes Raman spectroscopyRaman spectroscopyRaman scatteringJournal of Physics: Condensed Matter
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Small-angle neutron scattering reveals an oxygen-dependent conformational change of the immunogen keyhole limpet hemocyanin type 1 (KLH1).

2001

The respiratory protein of the keyhole limpet, Megathura crenulata, the hemocyanin (KLH), commonly used as an immunogen, binds oxygen cooperatively, which implies the existence of different conformations. For the first time, two different conformations of KLH1 were detected upon oxygenation, a deoxy and an oxy state, using small-angle neutron scattering. Rearrangements in the quaternary structure of KLH1 were predicted from the different radii of gyration and the shifts of the minima and maxima in the scattering curves. Upon oxygenation, KLH1 becomes smaller and more compact. Model reconstruction of KLH1 indicates a hollow cylinder with two rings located close to both ends, which move sligh…

Conformational changeProtein Conformationmedicine.medical_treatmentBiophysicsNeutron scatteringMegathura crenulataBiophysical PhenomenamedicineAnimalsScattering RadiationProtein Structure QuaternaryNeutronsbiologyChemistryScatteringHemocyaninGeneral Medicinebiology.organism_classificationSmall-angle neutron scatteringRespiratory proteinOxygenCrystallographyMolluscaHemocyaninsbiology.proteinKeyhole limpet hemocyaninProtein BindingEuropean biophysics journal : EBJ
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Structural effects of macrocyclic compounds and their partition in sodium dodecylsulphate aqueous solutions

2003

The partition of 1,4,7,10,13,16-esaoxacyclooctadecane (18C6), 4,7,13,16-tetraoxa-1,10-diazacyclooctadecane (2.2), 2,5,8,11,14,17-esaoxabicyclo[16.4.0]dicosane (B18C6) and 2,5,8,15,18,21-esoxatricyclo[20.4.0.09.14]esacosane (Cy218C6) in sodium dodecyl sulfate (SDS) aqueous solutions and their effect on the structure of surfactant aggregates has been investigated by small-angle neutron scattering. Results from data analysis have shown that by increasing macrocycle concentration the SDS micelles dimensions reduce for all systems investigated. At the same time information on macrocycles partition between the micellar and the continuous phase have been obtained. It was found that an appreciable …

CryptandsAqueous solutionSANSChemistryAdditive partitionSodiumInorganic chemistryCryptandchemistry.chemical_elementMicelleSmall-angle neutron scatteringGeneral Biochemistry Genetics and Molecular BiologyCrystallographychemistry.chemical_compoundPulmonary surfactantMoleculeCrown ethersSodium dodecyl sulfateMicellesSettore CHIM/02 - Chimica FisicaJournal of Applied Crystallography
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Incoherent quasi-elastic neutron scattering in isomeric alcohols

1992

Abstract Incoherent quasi-elastic neutron scattering (IQENS) data on liquid isomeric alcohols normal-pentanol (n-PeOH) and 2-methyl-2-butanol (2M-2BuOH) and on their mixture are presented. The diffusive motion of protons, as a function of temperature, is analyzed in the framework of the random jump diffusion model. The temperature dependence of the parameters obtained confirms the more “fragile” behaviour of the more sterically hindered 2M-2BuOH with respect to that of the linear n-PeOH.

DYNAMICSMaterials scienceNuclear magnetic resonanceJump diffusionFunction (mathematics)Physics::Chemical PhysicsElectrical and Electronic EngineeringNeutron scatteringCondensed Matter PhysicsTEMPERATURESmall-angle neutron scatteringMolecular physicsElectronic Optical and Magnetic MaterialsPhysica B: Condensed Matter
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Tuning the Structure of Galacturonate Hydrogels: External Gelation by Ca, Zn, or Fe Cationic Cross-Linkers

2019

International audience; We show here how the nature of various divalent cations M2+ (Ca2+, Zn2+, or Fe2+) influences the structure and mechanical properties of ionotropic polygalacturonate (polyGal) hydrogels designed by the diffusion of cations along one direction (external gelation). All hydrogels exhibit strong gradients of polyGal and cation concentrations, which are similar for all studied cations with a constant ratio R = [M2+]/[Gal] equal to 0.25, showing that every M2+ cation interacts with four galacturonate (Gal) units all along the gels. The regions of the hydrogels formed in the early stages of the gelation process are also similar for all cations and are homogeneous, with the s…

DenticityPolymers and PlasticsDiffusionIronBioengineering02 engineering and technology010402 general chemistry01 natural sciencesDivalentBiomaterialsCations[SDV.IDA]Life Sciences [q-bio]/Food engineeringMaterials ChemistrypolyGal and cation concentrationsColloidschemistry.chemical_classificationChemistryHexuronic AcidsCationic polymerizationHydrogelsDynamic mechanical analysis021001 nanoscience & nanotechnologySmall-angle neutron scattering0104 chemical sciencesionotropic polygalacturonate (polyGal) hydrogelsCrystallographyZincCross-Linking ReagentsHomogeneousSelf-healing hydrogelsCalcium0210 nano-technology
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Existence of two time scales in the phase transitions of BaTiO3

1991

Abstract We report new Raman scattering measurements in the tetragonal phase of a single domain BaTiO3 crystal. Data reveal the occurence of a large quasi elastic scattering. The Raman profile is analysed in terms of coexisting soft phonon and Debye relaxation.

Elastic scatteringMaterials sciencePhonon scatteringCondensed matter physicsScattering lengthInelastic scatteringCondensed Matter PhysicsSmall-angle neutron scatteringElectronic Optical and Magnetic MaterialsCondensed Matter::Materials Sciencesymbols.namesakeX-ray Raman scatteringCondensed Matter::SuperconductivitysymbolsRaman spectroscopyRaman scatteringFerroelectrics
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Elastic scattering cross sections for 6Li and 7Li scattering by aluminum, silicon and titanium below 12 MeV at angles of 140∘ and 170∘

1999

Abstract Elastic scattering cross sections for 6Li and 7Li scattering by natural aluminum, silicon and titanium have been measured in the energy range of 4–11 MeV. Scattering angles were 140∘ and 170∘ for 6Li and 140∘ for 7Li. The threshold energies above which Rutherford backscattering becomes invalid have been determined. Above this threshold the cross sections decrease rapidly, rendering backscattering analysis impractical. For 7Li scattering by Al and Si the observed threshold values were higher than for 6Li scattering. This behavior was reversed for scattering by Ti. The findings were systematic for both scattering angles. The present cross section and threshold data have been compared…

Elastic scatteringNuclear and High Energy PhysicsMaterials science010308 nuclear & particles physicsScatteringScattering lengthMott scatteringInelastic scattering01 natural sciences7. Clean energySmall-angle neutron scatteringsymbols.namesakeX-ray Raman scattering0103 physical sciencessymbolsRutherford scatteringAtomic physics010306 general physicsInstrumentationNuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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The influence of the nuclear medium on inclusive electron and neutrino scattering off nuclei

2007

We present a model for inclusive electron and neutrino scattering off nuclei paying special attention to the influence of in-medium effects on the quasi-elastic scattering and pion-production mechanisms. Our results for electron scattering off Oxygen are compared to experimental data at beam energies ranging from 0.7-1.5 GeV. The good description of electron scattering serves as a benchmark for neutrino scattering.

Elastic scatteringPhysicsNuclear and High Energy PhysicsParticle physicsQuasielastic scatteringNuclear TheoryNuclear TheoryFOS: Physical sciencesMott scatteringInelastic scatteringSmall-angle neutron scatteringNuclear physicsNuclear Theory (nucl-th)High Energy Physics - PhenomenologyHigh Energy Physics - Phenomenology (hep-ph)Quasielastic neutron scatteringHigh Energy Physics::ExperimentNeutrinoNuclear ExperimentElectron scattering
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Elastic scattering of 35Cl and 37Cl on 24Mg

1990

Abstract Elastic scattering of 35Cl and 37Cl on 24Mg was measured at two c.m. energies. Optical model analysis with different potentials are compared. Isotopics effects on absorption are observed. The closure approximation model is found to give a good reproduction of experimental data.

Elastic scatteringPhysicsNuclear reactionNuclear and High Energy Physics010308 nuclear & particles physics0103 physical sciencesClosure (topology)[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]Atomic physics010306 general physicsAbsorption (electromagnetic radiation)01 natural sciencesSmall-angle neutron scatteringNuclear Physics A
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NUCLEAR MAGNETIC ORDER, USE OF SPIN DEPENDENT AMPLITUDES

1993

The use of the spin dependent part of the nuclear scattering length gives access to neutron scattering to the field of nuclear magnetism. This paper presents the theoretical and experimental background for such experiments. The available results on nuclear order will be reviewed and put if possible in the larger frame of many body physics. The possibilities of using nuclear magnetism for new applications or the improvement of scattering techniques will be stressed as well.

Elastic scatteringPhysicsSpin polarizationScatteringNuclear TheoryStatistical and Nonlinear PhysicsSpin engineeringNeutron scatteringMott scatteringCondensed Matter PhysicsSmall-angle neutron scatteringNuclear physicsNuclear ExperimentSpin (physics)International Journal of Modern Physics B
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