Search results for "SOI"
showing 10 items of 4823 documents
The lithium isotope response to the variable weathering of soils in Iceland
2021
Abstract This study has analysed Li isotopes ratios from well-studied soil and pore water profiles from Iceland that have the same parent material but have experienced different degrees of chemical weathering. Thus, from least to most weathered, we have analysed vitrosols (V), gleyic andosols (GA), brown andosols (BA), Histosols (H) and Histic Andosols (HA). Although the most weathered H and HA soils have the highest content in clay-sized material, they have the least fractionated δ7Lipore water values. In contrast, the least weathered GA and BA pore waters are most fractionated for Li isotopes. Given that Li isotope ratios are fractionated by clay mineral formation, this appears counter-in…
Ring diameter effects on determination of field-saturated hydraulic conductivity of different loam soils
2017
Abstract Establishing ring diameter effects on the field-saturated soil hydraulic conductivity, Kfs, determined with ponding infiltrometer methods can help to find a compromise between the need to sample a large area with an individual measurement and the impracticality of using large rings in the field. Five ring sizes (diameter, D = 5.5, 10.9, 16.0, 27.8 and 31.8 cm) were used to determine Kfs by the simplified falling head (SFH) technique in four loamy soils with different salinity (electrical conductivity of saturated extract, ECe = 0.9–29.4 dS/m) and sodicity (exchangeable sodium percentage, ESP = 2.7–81.3%) levels. According to USDA classification, two soils were non-saline, non-sodic…
Interlamellar Reactions of Tetracalcium Aluminate Hydrates with Water and Organic Compounds
1967
Tetracalcium aluminate hydrates are the first example of layer-structured crystals containing neutral sheets, which are highly capable of interlamellar adsorption of water and neutral organic compounds. In this respect tetracalcium aluminate hydrates present new aspects of the phenomenon of swelling, and bring about the challenge of comparison with the frequently examined clay-organic compounds. This report is concerned with the probable monolayer structure of tetracalcium aluminate hydrate which forms five hydration stages. A summary concerning configuration and properties of adsorption complexes with approximately 500 selected organic substances follows. As far as these substances are hom…
FeMnOx-1: A new microanalytical reference material for the investigation of Mn–Fe rich geological samples
2016
Suitable Mn-Fe rich microanalytical reference materials (MRMs) as calibration material for laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) have not been available. The United States Geological Survey (USGS) in collaboration with the Max Planck Institute for Chemistry has prepared a synthetic MRM, FeMnOx-1, with elevated mass fractions of MnO (25 g/100 g), Fe2O3 (8.5 g/100 g) and high mass fractions of 25 trace elements varying between 200 and 5000 mg/kg. This new MRM has been designed as calibration material for a wide range of different Mn-Fe deposits, such as desert/rock varnish, ocean crusts and nodules as well as Mn accumulations in soils and lakes. Small-scale an…
2-[(1-Methyl-1H-pyrrol-2-yl)carbonyl-meth-yl]isoindoline-1,3-dione.
2009
The asymmetric unit of the title compound, C15H12N2O3, contains two almost identical molecules forming an nearly C2-symmetric dimeric pattern. The dihedral angles between the pyrrole ring and the phthalimide unit are 82.95 (8) and 86.57 (8)° for the two molecules. Within such a dimer, the phthalimide units of the two molecules form a dihedral angle of 1.5 (5)°.
EDXRF and TXRF analysis of elemental size distributions and environmental mobility of airborne particles in the city of Riga, Latvia
2004
Airborne particles were investigated in the central part of Riga during October 2000. Mass, black carbon and elemental concentrations of airborne particles were measured on Teflon filters from a dichotomous impactor, which samples fine (<2.5 µm) and coarse (2.5‐10 µm) fractions of particles. In order to obtain more detailed information on the size distributions of different elements, a seven-stage Batelle cascade impactor was used, in which quartz plates treated with silicone grease were utilized as backing for the different stages. Total reflection x-ray fluorescence (TXRF) and energy-dispersive x-ray fluorescence (EDXRF) spectrometry were used for elemental analysis on the quartz plates a…
Changes of humic substances characteristics from forested to cultivated soils in Ethiopia
2006
The dynamics of the stable fractions of soil organic matter (SOM), the humic substances, has been rarely studied in tropical soils. We evaluated extraction yields, elemental composition, isotopic d 13 C abundance and solid-state 13 C NMR spectra of humic fractions isolated from five forested and cultivated soils in Ethiopia in order to assess the influence of deforestation and subsequent cultivation on the composition of humic fractions. In all locations, humic (HA) and fulvic (FA) acids, humin (HU) and a humic hydrophobic fraction extracted with an acetone–HCl solution (HE) were decreased as a result of deforestation and cultivation, but the magnitude of decrease was site-specific. While t…
Determination of Platinum-Group Elements (PGE) from catalytic converters in soil by means of docimasy and INAA.
1996
The nickelsulfide fire assay (docimasy) for the enrichment of platinum-group elements (PGEs) has been modified for the use with small samples and combined with instrumental neutron-activation analysis (INAA). This procedure has been applied to the determination of PGEs exhausted from catalytic converters and deposited in soil near the Wiesbadener Kreuz (highway A3, Frankfurt-Koln). Our results show a considerable enhancement of the Pt (up to 330 ng/g), Pd (6.6 ng/g) and Rh (7.5 ng/g) contents close to the highway.
Use of semipermeable membrane devices for assessment of air quality in Tangier (Morocco)
2009
Semipermeable membrane devices (SPMDs) have been used for the evaluation of the contamination of air in both the urban and the industrial area in Tangier (Morocco). Benzene, toluene, ethylbenzene a...
Determination of mineral and trace element concentrations in pine needles by ICP-OES: evaluation of different sample pre-treatment methods
2008
In the present study, the determination of mineral and trace elements (Al, B, Ca, Cu, Fe, K, Mg, Mn, Na, P and Zn) from pine needles using three sample pre-treatment methods followed by inductively coupled plasma optical emission spectrometry, was examined. Sample pre-treatment methods tested were microwave digestion, ultrasound-assisted digestion and dry ashing. The new ultrasound-assisted digestion method was optimised by the analysis of the standard reference material (SRM) 1575a (pine needles) sample. The speed of dry ashing method was significantly increased by ultrasound dissolution after ashing. All the ICP-OES measurements were performed in robust plasma conditions which were tested…