Search results for "SPECTRA"

showing 10 items of 3542 documents

CARS methane spectra: Experiments and simulations for temperature diagnostic purposes

2007

International audience; CARS laboratory experiments were done in the 2905-2925 cm(-1) range, in the vicinity of the v, band of the methane molecule, for pressures ranging from I to 50 bar, and temperatures up to 1100 K. These experiments were carried out in order to retrieve the pressure evolution of the CH4 spectrum, as well as to confirm its temperature dependance. After a brief recall on the theory used to compute pressure broadening coefficients and relaxation rates, we consider the v(3) and v(4) infrared bands of methane for benchmark calculations purposes. Next, we present recent experimental CARS spectra and calculated ones. Lastly, we discuss flame experiments as well as comparisons…

Materials scienceInfrared010402 general chemistryCombustion7. Clean energy01 natural sciencesTemperature measurementMethaneSpectral linechemistry.chemical_compoundsymbols.namesakeline-mixingNuclear magnetic resonancepressure broadening0103 physical sciences(CH4)-C-12CARSPhysical and Theoretical ChemistryRamanSpectroscopy[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics][ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]010304 chemical physicsmethaneRelaxation (NMR)Atomic and Molecular Physics and Optics0104 chemical sciencesComputational physicschemistry13. Climate actionsymbolsRaman spectroscopytemperature measurementBar (unit)combustion
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High-Resolution Spectroscopy and Analysis of the ν3 and ν4 Fundamentals of Monoisotopic 70GeF4

2001

The first high-resolution study on germanium tetrafluoride is reported. We used a monoisotopic sample of (70)GeF(4). The FTIR spectra of the two infrared active fundamentals, namely the nu(4) (bending) and nu(3) (stretching) modes, were recorded at a temperature of ca. 210 K and a resolution (1/maximum optical path difference) of 0.0031 and 0.0023 cm(-1), respectively. These spectra were analyzed using the STDS software developed in Dijon. In both cases, we obtained a fit with a root mean square better than 1x10(-3) cm(-1). Both bands show very regular structures with no detectable perturbation. Copyright 2001 Academic Press.

Materials scienceInfraredAnalytical chemistryHigh resolutionGermanium tetrafluorideAtomic and Molecular Physics and OpticsSpectral lineRoot mean squarechemistry.chemical_compoundNuclear magnetic resonancechemistryMonoisotopic massPhysical and Theoretical ChemistrySpectroscopySpectroscopyOptical path lengthJournal of Molecular Spectroscopy
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Transition from polarization disorder to antiphase polarization domains in a fiber laser

2014

Adjusting polarization coupling in a fiber ring laser may lead to anti-synchronization of spatio-temporal disorder into ordered laminar states of orthogonal polarization temporal domains, as well as stable lattices of soliton trains.

Materials scienceKerr effectPolarization rotatorCondensed matter physicsOrthogonal polarization spectral imagingbusiness.industryRing laserLaserPolarization (waves)law.inventionOpticslawFiber laserbusinessSelf-phase modulation
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Transient absorption and luminescence of LiNbO3 and KNbO3

2001

Abstract The results of time-resolved optical absorption spectra in congruent and stoichiometric LiNbO3 as well as KNbO3 crystals are reported. The role of different polaron types in transient absoiption and luminescence spectra and decay kinetics are discussed.

Materials scienceKineticsAnalytical chemistryLuminescence spectraCondensed Matter PhysicsPolaronElectronic Optical and Magnetic MaterialsOptical absorption spectraControl and Systems EngineeringUltrafast laser spectroscopyMaterials ChemistryCeramics and CompositesTransient (oscillation)Electrical and Electronic EngineeringLuminescenceStoichiometryIntegrated Ferroelectrics
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Multi-spectral photoplethysmography technique for parallel monitoring of pulse shapes at different tissue depths

2011

A photoplethysmography (PPG) signal can provide very useful information about a subject's hemodynamic status in a hospital or home environment. A newly developed portable multi-spectral photoplethysmography device has been used for studies of 11 healthy subjects. Multi-spectral photoplethysmography (MS-PPG) biosensor intended for analysis of peripheral blood volume pulsations at different vascular depths has been designed and experimentally tested. Multi-spectral monitoring was performed by means of a three–wavelengths (405 nm, 660 nm and 780 nm) laser diode and a single photodiode with multi-channel signal output processing. The proposed methodology and potential clinical applications are …

Materials scienceLaser diodePulse (signal processing)lawPhotoplethysmogramAnalytical chemistryMulti spectralPulse shapingSignalPhotodiodelaw.inventionSemiconductor laser theoryBiomedical engineeringClinical and Biomedical Spectroscopy and Imaging II
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Detection of deuterium retention by LIBS at different background pressures

2017

ITER plans foresee the quantitative diagnostics of fuel retention in reactor walls at near-atmospheric pressures. Using laser induced breakdown spectroscopy (LIBS) for this purpose assumes a reliable resolving of Balmer α-lines of hydrogen isotopes in spectra of plasma produced by focused laser radiation onto the target surface. To develop LIBS for quantitative diagnostics of fuel retention during the maintenance breaks of ITER, the effect of background gas pressure on the laser-induced plasma characteristics has been studied. The background pressure limits the expansion rate of plasma and as a result it leads to higher plasma concentrations. At the same time the limiting factor of the reso…

Materials scienceLaser induced plasmaHydrogenHydrogen isotopeAtomic emission spectroscopychemistry.chemical_elementLaser induced breakdown spectroscopy01 natural sciencesSpectral line010305 fluids & plasmaslaw.inventionSignal-to-noise ratio decreasesymbols.namesakeLaser diagnosticsNuclear reactorsIsotopeslaw0103 physical sciencesBackground pressureLaser-induced breakdown spectroscopyLaserinduced breakdown spectroscopy (LIBS)010306 general physicsPlasma concentrationMathematical PhysicsSignal to noise ratioAtmospheric pressureSignal to noise ratio Background pressureAtomic emission spectroscopyPlasmaSignal-to-noise ratio decrease Laser produced plasmasCondensed Matter PhysicsLaserAtomic and Molecular Physics and OpticschemistryStark effectDeuterium retentionElectron concentrationsymbolsLaser produced plasmasAtmospheric pressureAtomic physicsPhysica Scripta
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Dielectric properties of PMN+2%Li 2 O at low frequencies

2012

The reported study is focused on effects of the admixture of lithium (2% Li2O) on the low-frequency dielectric response in lead magnesium niobate ceramics over the 100 -300 K range of temperature. The obtained results reveal an essential thermal broadening of the e′(ν) spectra specific to relaxor ferroelectrics. Dispersion Δe′ = e′1Hz-e′1kHz and values of e′′(ν) in lead magnesium niobate ceramics containing Li are well described by the Cole-Cole equation at temperatures below the e′(T) maximum. Based on the analysis of the experimental data admixture of lithium is suggested to promote formation of domains in lead magnesium niobate ceramics (© 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)

Materials scienceLead magnesium niobateAnalytical chemistryMineralogychemistry.chemical_elementDielectricCondensed Matter PhysicsDielectric responseSpectral linechemistryvisual_artvisual_art.visual_art_mediumLithiumCeramicDispersion (chemistry)physica status solidi c
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Charge trapping processes and energy transfer studied in lead molybdate by EPR and TSL

2019

Abstract Charge trapping and energy transfer processes are investigated in PbMoO4 single crystals by electron paramagnetic resonance (EPR) and wavelength-resolved thermally stimulated luminescence (TSL) in a correlated manner. New signals produced by two differently perturbed Mo5+ centers (Mo2 and Mo3) were observed in EPR spectra measured in the crystals after 420 nm light irradiation. Two sets of spin-Hamiltonian parameters, g tensor and the 95,97Mo, 207Pb (super) hyperfine tensors, have been determined and analyzed in terms of crystal field and LCAO-MO theories. A significant overlap of the Mo 5d1 and 6s6p ligand Pb orbitals was deduced for the Mo3 whereas the Mo2 center seemed to be not…

Materials scienceLead molybdateBiophysics02 engineering and technologyTrapping010402 general chemistry01 natural sciencesBiochemistryMolecular physicsSpectral lineWavelength resolved TSLElectron traplaw.inventionCrystallawElectron paramagnetic resonanceHyperfine structureGeneral ChemistryRadioluminescence021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and Optics0104 chemical sciencesFIS/01 - FISICA SPERIMENTALERadioluminescenceCharge carrierEPR0210 nano-technologyLuminescenceJournal of Luminescence
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Assessment of age-related skin changes using hyperspectral polarization imaging

2019

Abstract We report a development of hyperspectral polarization imaging approach for assessment of age-related skin changes. The degree of residual polarization is used as a quantitative marker of the age-related pathological malformations. The developed approach in frame of express analysis of the degree of residual polarization in each pixel of the image are shown.

Materials scienceLight detectionPixelHyperspectral imagingPolarization imagingHyperspectral imagingPolarization (waves)Diabetes mellitusSDG 3 - Good Health and Well-beingAge relatedPolarization/dk/atira/pure/sustainabledevelopmentgoals/good_health_and_well_beingCollagensense organsResidual polarizationAdvanced glycation end-productsBiomedical engineering
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Smartphone snapshot mapping of skin chromophores under triple-wavelength laser illumination

2017

Abstract Chromophore distribution maps are useful tools for skin malformation severity assessment and for monitoring of skin recovery after burns, surgeries, and other interactions. The chromophore maps can be obtained by processing several spectral images of skin, e.g., captured by hyperspectral or multispectral cameras during seconds or even minutes. To avoid motion artifacts and simplify the procedure, a single-snapshot technique for mapping melanin, oxyhemoglobin, and deoxyhemoglobin of in-vivo skin by a smartphone under simultaneous three-wavelength (448–532–659 nm) laser illumination is proposed and examined. Three monochromatic spectral images related to the illumination wavelengths …

Materials scienceLightMonte Carlo methodMultispectral imageBiomedical Engineeringsmartphone applicationsImage processing02 engineering and technologyDermatologylaser illumination design01 natural sciencesSkin Diseaseslaw.invention010309 opticsBiomaterialsOpticslaw0103 physical sciencesmultispectral imagingHumansLightingSkinbusiness.industryLasersHyperspectral imagingskin chromophore mappingChromophore021001 nanoscience & nanotechnologyLaserAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsRGB color modelMonochromatic colorSmartphone0210 nano-technologybusiness
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