Search results for "SPECTRA"
showing 10 items of 3542 documents
A fluorescence retrieval method for the flex sentinel-3 tandem mission
2014
A new fluorescence retrieval method is proposed to support ESA's 8th Earth Explorer Fluorescence EXplorer (FLEX) candidate mission. Most hyperspectral fluorescence retrieval algorithms available in the literature are very sensitive to true reflectance modelization and/or they assume the atmospheric status as known. The proposed algorithm delivers the retrieval of full fluorescence spectrum at canopy level by using only Top Of Atmosphere (TOA) radiances as input. The proposed method starts with (1) the atmospheric correction of TOA radiances, characterizing the state of the atmosphere without assuming any a-priori classification on aerosols models, (2) performing a first estimation of fluore…
Quantitative thermoelastic stress analysis by means of low-cost setups
2020
Abstract A low-cost Thermoelastic Stress Analysis (TSA) experimental setup is proposed which uses an ordinary micro-bolometer and in-house developed signal processing scripts. The setup is evaluated by analysing the thermoelastic signal from a tensile and a SENT specimen made of stainless steel AISI 304L, and the bolometer performances are compared with those of a state of the art photon detector. Signal processing is based on off-line cross-correlation, using a self-reference signal which is retrieved from the acquired thermal data. Procedures are in particular developed to recognise, quantify and correct errors due to spectral leakage and loss of streamed frames. The thermoelastic signal …
Multi-spectral mapping of in vivo skin hemoglobin and melanin
2010
The multi-spectral imaging technique has been used for distant mapping of in-vivo skin chromophores by analyzing spectral data at each reflected image pixel and constructing 2-D maps of the relative concentrations of oxy-/deoxyhemoglobin and melanin. Instead of using a broad visible-NIR spectral range, this study focuses on narrowed spectral band 500-700 nm, so speeding-up the signal processing procedure. Regression analysis confirmed that superposition of three Gaussians is optimal analytic approximation for the oxy-hemoglobin absorption tabular spectrum in this spectral band, while superposition of two Gaussians fits well for deoxy-hemoglobin absorption and exponential function - for mela…
Proba-V cloud detection Round Robin: Validation results and recommendations
2017
This paper discusses results from 12 months of a Round Robin exercise aimed at the inter-comparison of different cloud detection algorithms for Proba-V. Clouds detection is a critical issue for satellite optical remote sensing, since potential errors in cloud masking directly translates into significant uncertainty in the retrieved downstream geophysical products. Cloud detection is particularly challenging for Proba-V due to the presence of a limited number of spectral bands and the lack of thermal infrared bands. The main objective of the project was the inter-comparison of several cloud detection algorithms for Proba-V over a wide range of surface types and environmental conditions. Prob…
Support Vector Machines Framework for Linear Signal Processing
2005
This paper presents a support vector machines (SVM) framework to deal with linear signal processing (LSP) problems. The approach relies on three basic steps for model building: (1) identifying the suitable base of the Hilbert signal space in the model, (2) using a robust cost function, and (3) minimizing a constrained, regularized functional by means of the method of Lagrange multipliers. Recently, autoregressive moving average (ARMA) system identification and non-parametric spectral analysis have been formulated under this framework. The generalized, yet simple, formulation of SVM LSP problems is particularized here for three different issues: parametric spectral estimation, stability of I…
Mutual Information Analysis of Brain-Heart Interactions in Epileptic Children
2021
In this work we apply the network physiology paradigm to retrieve information from central and autonomic nervous systems before focal epileptic seizure, represented respectively by electroencephalogram (EEG) signals and R-R intervals (RRI), and investigate on the presence and strength of brain-heart interactions by computing mutual information (MI) measures. Statistical significance of MI values was tested through surrogate time series generated with the random shuffle approach. Our results suggest that the proposed method for aligning signals representing brain and heart activity measured with different sampling rates, is capable of revealing coupling between RRI representing heart system,…
Spectral estimators for Doppler analysis of intracoronary ultrasound catheters
2002
With the zero-cross-detection method (ZCD) it has been shown that it is not possible to achieve a reproducible quantitative, and robust evaluation of an inter-coronary audio signal. The authors define spectral estimators to analyze the Doppler-audio signal. Measurements in a blood flow model have shown that the ZCD method underestimates the expected velocity at all speeds. Spectral analysis allows the determination of the actual and peak velocity more robustly and precisely. >
Probing the radio emission from air showers with polarization measurements
2014
The emission of radio waves from air showers has been attributed to the so-called geomagnetic emission process. At frequencies around 50 MHz this process leads to coherent radiation which can be observed with rather simple setups. The direction of the electric field induced by this emission process depends only on the local magnetic field vector and on the incoming direction of the air shower. We report on measurements of the electric field vector where, in addition to this geomagnetic component, another component has been observed which cannot be described by the geomagnetic emission process. The data provide strong evidence that the other electric field component is polarized radially wit…
Non-degenerate 1,2-silyl shift in silyl substituted alkyltrimethylcyclopentadienes
2005
Abstract The five new silanes C5Me3RSiMenCl3 − n (n = 3, R = i-Pr (5); n = 2, R = i-Pr (6); n = 2, R = s-Bu (7); n = 2, R = cyclohexyl (8); and n = 3, R = t-Bu (9)) were synthesized by reaction of 1-alkyl-2,3,4-trimethylcyclopentadienyl lithium salts with appropriate chlorosilane and characterized by NMR, MS, and IR spectra. At elevated temperatures (250–360 K), all the silanes undergo a non-degenerate sigmatropic silyl rearrangement, which generates non-equivalent structures a and b. The presence of minor structure c was observed in compounds 5 and 7 only. The Diels–Alder cycloaddition of 5 with strong dienophiles tetracyanoethylene (TCNE), and dimethylacetylenedicarboxylate (DMAD) provide…
Defect-related visible luminescence of silica nanoparticles
2013
The high photon emissivity in the visible spectral range is one of the most relevant phenomena emerging from the reduction of silica down to nanoscale; hence it is promising for the development of optical nanotechnologies (down converter, probes, display). It is well accepted that the origin of this luminescence is related to the high specific surface (~100 m2/g) that favors the formation of optically active defects at the nanosilica surface. With the aim to clarify the role of specific luminescent defects, here we report a detailed study of spectral and decay features by time-resolved photoluminescence spectra under a visible-UV tunable laser excitation. Our study is carried out on differe…