Search results for "SPECTROSCOPIC"

Zn2+ and Cu2+ complexes of a fluorescent scorpiand-type oxadiazole azamacrocyclic ligand: crystal structures, solution studies and optical properties

2020

A ligand comprised of a macrocyclic pyridinophane core having a pendant arm containing a secondary amine group linked through a methylene spacer to a pyridyl–oxadiazole–phenyl (PyPD) fluorescent system has been prepared (L). The crystal structures of [ZnL](ClO4)2 and [CuL](ClO4)2 show that M2+ is coordinated to all the nitrogen atoms of the macrocyclic core, the secondary amine of the pendant arm and the nitrogen atom of the pyridine group of the fluorescent moiety, the latter bond being clearly weaker than the one with the pyridine of the macrocycle. Solution studies showed the formation of a highly stable Cu2+ complex with 1 : 1 stoichiometry, whereas with Zn2+ least stable complexes were…

α-decay spectroscopy of the N = 130 isotones 218Ra and 220Th: Mitigation of α-particle energy summing with implanted nuclei

2019

An analysis technique has been developed in order to mitigate energy summing due to sequential short-lived α decays from nuclei implanted into a silicon detector. Using this technique, α-decay spectroscopy of the N=130 isotones 218Ra (Z=88) and 220Th (Z=90) has been performed. The energies of the α particles emitted in the 218Ra→214Rn and 220Th→216Ra ground-state-to-ground-state decays have been measured to be 8381(4) keV and 8818(13) keV, respectively. The half-lives of the ground states of 218Ra and 220Th have been measured to be 25.99(10) μs and 10.4(4) μs, respectively. The half-lives of the ground states of the α-decay daughters, 214Rn and 216Ra, have been measured to be 259(3) ns and …

Determination of β-decay ground state feeding of nuclei of importance for reactor applications

2020

In β-decay studies the determination of the decay probability to the ground state (g.s.) of the daughter nucleus often suffers from large systematic errors. The difficulty of the measurement is related to the absence of associated delayed γ-ray emission. In this work we revisit the 4πγ−β method proposed by Greenwood and collaborators in the 1990s, which has the potential to overcome some of the experimental difficulties. Our interest is driven by the need to determine accurately the β-intensity distributions of fission products that contribute significantly to the reactor decay heat and to the antineutrinos emitted by reactors. A number of such decays have large g.s. branches. The method is…

Synthesis, Electrochemistry, and Photophysics of Aza-BODIPY Porphyrin Dyes

2016

International audience; The synthesis of dyad and triad aza-BODIPY-porphyrin systems in two steps starting from an aryl-substituted aza-BODIPY chromophore is described. The properties of the resulting aza-BODIPY-porphyrin conjugates have been extensively investigated by means of electrochemistry, spectroelectrochemistry, and absorption/emission spectroscopy. Fluorescence measurements have revealed a dramatic loss of luminescence intensity, mainly due to competitive energy transfer and photoinduced electron transfer involving charge separation followed by recombination.

Development of 2D & 3D cadmium–zinc–telluride spectroscopic imagers for X-ray and gamma ray applications

2021

Indoor pollutant identification by means of spectroscopic techniques

1995

Coronal properties of active G-type stars in different evolutionary phases

2005

We report on the analysis of XMM-Newton observations of three G-type stars in very different evolutionary phases: the "weak-line" T Tauri star HD 283572, the Zero Age Main Sequence star EK Dra and the Hertzsprung-gap giant star 31 Corn. The X-ray luminosities of the three stars are all in the range 10(30) - 10(31) erg/s. We compare the Emission Measure Distributions of these bright sources, derived from high-resolution X-ray spectra, as well as the pattern of elemental abundances vs. First Ionization Potential (FIP). The results of our analysis suggest that the coronae of these stars are very similar in terms of dominant coronal magnetic structures, in spite of differences in their evolutio…

The structure of coronal plasma in active stellar coronae from density measurements

2005

We have analyzed high-resolution X-ray spectra of a sample of 22 active stars observed with the High Energy Transmission Grating Spectrometer (HETGS) on Chandra in order to investigate their coronal plasma density, using the lines of the He-like ions O VII, Mg XI, and Si XIII. Si XII lines in all stars of the sample axe compatible with the low-density limit (i.e. n(e) = 10(30) erg/s); O VII lines yield much lower densities of a few 10(10) cm(-3). Our results indicate that the "hot" and "cool" plasma resides in physically different structures. Our findings imply remarkably compact coronal structures, especially for the hotter (similar to 7 MK) plasma emitting the Mg xi lines characterized by…

Chandra study of the eclipsing M dwarf binary, YY Gem

2012

The eclipsing M dwarf binary system, YY Gem, was observed using Chandra covering 140 ks (2Prot) in total, split into two even exposures separated by 0.76 d (0.94 Prot). The system was extremely active: three energetic flares were observed over the course of these observations. The flaring and non-flaring states of the system are analysed in this paper. The activity level increased between the first and second observations even during the quiescent (non-flaring) phases. An analysis of the dynamics of the X-ray-emitting plasma suggests that both components are significantly active. Contemporaneous Hα spectra also suggest that both components show similar levels of activity. The primary star i…