Search results for "SQUID"
showing 10 items of 49 documents
Phase separated Cu@Fe3O4 heterodimer nanoparticles from organometallic reactants
2011
Cu@Fe3O4 heteroparticles with distinct morphologies were synthesized from organometallic reactants. The shape of the magnetic domains could be controlled by the solvent and reaction conditions. They display magnetic and optical properties that are useful for simultaneous magnetic and optical detection. After functionalization, the Cu@Fe3O4 heterodimers become water soluble. The morphology, structure, magnetic and optical properties of the as-synthesized heterodimer nanoparticles were characterized using transmission electron microscopy (TEM), X-ray diffraction (XRD), mossbauer spectroscopy, superconducting quantum interference device (SQUID) magnetometry, and dark field imaging. A special a…
Temperature Dependence of Electronic and Magnetic Properties of (DOEO)<sub>4</sub>[HgBr<sub>4</sub>]·TCE Single Crystals
2015
The temperature dependence of electronic and magnetic properties of the organic charge-transfer salt (DOEO)4[HgBr4]·TCE was investigated using magnetometry. The magnetic susceptibility shows a maximum at 40 K followed by an onset of a pronounced increase at 70 K and a constant behavior above 120 K. Implications on the charge carrier density are discussed. Combining the magnetometry with resistivity and ESR measurements we propose a sequence of insulating, metallic and semiconducting behavior with increasing temperature. Our results indicate that (DOEO)4[HgBr4]·TCE is close to the boundary between an insulating and conducting ground state.
Analysis of magnetization relaxation in MgB2 bulk samples obtained by electric-field assisted sintering
2008
Abstract The relaxation of the irreversible magnetization of MgB2 bulk samples obtained by electric-field assisted sintering was investigated using the SQUID magnetometry for a magnetic field H up to 50 kOe applied in zero-field-cooling conditions. We observed a crossover plastic creep at high temperatures T-elastic creep at low T, described by H ∝ T−2 in the low T range, which appears to be caused by the macroscopic currents induced in the sample during magnetization measurements. By decreasing T below this line the determined creep exponent rapidly overcomes the widely accepted theoretical values for elastic (collective) pinning. This behaviour can easily be explained through the occurren…
Magnetic polyorganosiloxane core–shell nanoparticles: Synthesis, characterization and magnetic fractionation
2010
Abstact Here, we present the synthesis, characterization and magnetic separation of magnetic polyorganosiloxane nanoparticles. Magnetic iron oxide nanoparticles with average particle radii of 3.2 nm had been synthesized by a simple coprecipitation process of iron(II) and iron(III) salt in basic solution. Afterwards, the particles were successfully incorporated into a polyorganosiloxane network via a polycondensation reaction of trimethoxymethylsilane (T), diethoxydimethylsilane (D) and the functional monomer (chloromethylphenyl)trimethoxysilane (ClBz-T) in aqueous dispersion. A core–shell system was chosen to increase the flexibility of the system concerning size, composition and functional…
Fluoreno[2,1-a]fluorene: an ortho-naphthoquinodimethane-based system with partial diradical character.
2019
Fluoreno[2,1-a]fluorene, a molecule comprising fused ortho-quinodimethane units in a 1,5-napthoquinodimethane core, has been prepared and investigated with spectroscopy (UV-Vis-NIR, 1H-NMR and Raman), SQUID magnetometry, spectroelectrochemistry and quantum chemistry. While para-quinodimethanes with a 2,6-substitution pattern exist as closed-shell species and meta-quinodimethanes with 2,7-substitution favour a ground electronic state with very large diradical character, our 1,5-substituted ortho-naphthoquinodimethane-based system exhibits an intermediate degree of diradical character.
Epitaxial films of the magnetic shape memory material
2007
Abstract By DC-sputtering from a stoichiometric target onto sapphire substrates we prepared epitaxial films of Ni 2 MnGa . X-ray diffraction in two circle geometry shows only the Ni 2 MnGa peaks corresponding to a (1 1 0) oriented growth on the (1 1 0) oriented sapphire substrate. Rocking curve scans shows that the out of plane orientation has a width of only 1 . 1 ∘ . By four circle X-ray diffraction we find an in-plane aligned growth. The Curie temperature as determined by SQUID magnetometry is 368 K. On cooling down the low field magnetization drops at around 260–280 K indicating the austenite to martensite transition. The presence of two different phases at high and low temperature also…
Structural and Magnetic Properties of Nickel Oxide Nanopowders
2010
Structure and magnetic properties of nickel oxide (NiO) nanopowders have been studied by X-ray/neutron diffraction, SQUID magnetometer, and micro-Raman spectroscopy. Our diffraction data indicate that at room temperature all NiO powders are antiferromagnetically ordered and have a rhombohedral (R-3m) phase. The SQUID magnetometry and Raman spectroscopy measurements support the presence of the antiferromagnetic ordering.
Superconductor-ferromagnet tunnel junction thermoelectric bolometer and calorimeter with a SQUID readout
2020
Superconductor-ferromagnet thermoelectric detector (SFTED) is a novel ultrasensitive radiation detector based on the giant thermoelectric effect in superconductor-ferromagnet tunnel junctions. This type of detector can be operated without the need of additional bias lines, and is predicted to provide a performance rivaling transition-edge sensors and kinetic inductance detectors. Here we report our numerical studies on the SFTED noise equivalent power, energy resolution and time constant, and the feasibility of a SQUID readout in both bolometric and calorimetric regimes, with the goal to provide practical design parameters for the detector fabrication and the readout circuitry implementatio…
Reversible stress softening of collagen based networks from the jumbo squid mantle (Dosidicus gigas).
2014
Dosidicus gigas is the largest and one of the most abundant jumbo squids in the eastern Pacific Ocean. In this paper we have studied the muscle of the mantle of D. gigas (DGM). Morphological, thermal and rheological properties were assessed by means of atomic force microscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, differential scanning calorimetry, thermogravimetry and oscillatory rheometry. This study allowed us to assess the morphological and rheological properties of a collagen based network occurring in nature. The results showed that the DGM network displays a nonlinear effect called reversible stress softening (RSS) that has been previously described for …
Probing the magnetic properties of cobalt–germanium nanocable arrays
2005
We report the synthesis of high density arrays of coaxial nanocables, consisting of germanium nanowires surrounded by cobalt nanotube sheaths, within anodic aluminium oxide membranes. The nanocable arrays were prepared using a supercritical fluid inclusion process, whereby the cobalt nanotubes were first deposited on the pore walls of the nanoporous membranes and subsequently filled with germanium to form coaxial nanocables. The composition and structure of the metal–semiconductor nanostructures was investigated by electron microscopy, energy dispersive X-ray mapping and X-ray diffraction at high angles. The magnetic properties of the co-axial nanocables were probed using a superconducting …