Search results for "SSB"

CEMS Study of 57Fe Implanted in Diamond

2002

Conversion electron Mossbauer (CEMS) measurements have been made on a diamond sample implanted with 70 keV 57Fe to a dose of 5 × 1014 cm−2. CEMS spectra were collected in the as-implanted state and after annealing the diamond up to 1470 K. The lower temperature spectra were consistently fitted with three symmetric doublets. With annealing the areal fractions of two of the doublets increased to 44% and 48 %, respectively, while that of the third doublet decreased to be replaced by a single line component with isomer shift δ = 0.0 mm/s. Comparison of the observed isomer shifts with recent in-beam Mossbauer measurements and theoretical calculations allow us to attribute the singlet to intersti…

Structural and Mössbauer study of (Sb0.70Te0.30)100-x Snx alloys with x = 0, 2.5, 5.0 and 7.5

2019

(Sb 0.70 Te 0.30 ) 100-x Sn x alloys (with x = 0, 2.5, 5.0 and 7.5 at. %)have been synthesized and characterized in order to determine the crystalline structure and properties of materials obtained upon solidification and to extract information about the location of the Sn atom in the Sb-Te matrix. Powder X-ray diffraction (XRD)has been used to determine the crystalline structure, whereas Mössbauer spectroscopy has been utilized to determine the localization and the local structure of the Sn atom in the Sb-Te matrix through the hyperfine interactions of the 119 Sn probe with its environment. We found that Sb 70 Te 30 crystallizes in a trigonal structure belonging to P-3m1 space group, while…

ANNEALING EFFECT ON COERCIVITY AND MICROHARDNESS IN SINTERED (Nd, Tb)15(Fe, Co, Al)78B7 MAGNETS

1999

The variation of the coercivity and microhardness with annealing (475–1150°C/3.6 ks) of sintered (Nd, Tb) 15 (Fe, Co, Al) 78 B 7 permanent magnet have been investigated. The data indicate that the coercivity reaches the mininum and the maximum at 600°C and 775°C, respectively. Optical and scanning electron microscopy and magnetic domain structure observations give no hints to any change in microstructure. Fitting of the Mössbauer spectra of permanent magnets for different coercivity ( i H c ) values revealed that magnetic hyperfine fields (B Hf ) on all Fe sites are reduced with the increase in i H c value and the higher value of the i H c corresponds to the higher value of the Mössbauer l…

61Ni MÖSSBAUER EFFECT STUDIES OF THE FERRIMAGNETIC SPINEL NiCr2O4 IN AN APPLIED MAGNETIC FIELD

1980

Heat-capacity anomaly due to spin reorientation and thermodynamic functions of ErFeO3 and TmFeO3

2001

Abstract Heat capacities of orthoferrites, ErFeO 3 and TmFeO 3 , have been measured below room temperature by adiabatic calorimetry. A broad but definite anomaly due to the spin reorientation phenomenon was successfully detected in the expected temperature range (ca. 90 K). The results are compared with a vast anomaly reported for YbFeO 3 . The temperature dependence of the electric quadrupole splitting of the Fe nuclear levels was determined by Mossbauer spectroscopy through the spin reorientation. A heat capacity anomaly centered at 3.60 K due to the magnetic ordering of Er 3+ ions was clearly detected. Some Schottky anomalies were resolved and energy splittings involved were roughly esti…

MÖSSBAUER SPECTROSCOPIC STUDIES OF SPIN CROSSOVER COMPOUNDS

1979

A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

2018

The reaction of [Cr3IIIO(OAc)6(H2O)3]NO3·AcOH with 2-hydroxynaphthaldehyde, 2-amino-isobutyric acid and NiCl2·6H2O in MeOH, under basic and solvothermal conditions, led to the formation of the quasi-1D coordination polymer {[CrIII2NiII(L)4(MeOH)2]}n (where L = the dianion of the Schiff base between 2-hydroxynaphthaldehyde and 2-amino-isobutyric acid), which behaves as a ferromagnetic chain, displaying slow relaxation of magnetization.

Spin Crossover Phenomenon in Nanocrystals and Nanoparticles of [Fe(3-Fpy)2M(CN)4] (MII = Ni, Pd, Pt) Two-Dimensional Coordination Polymers

2010

The two-dimensional spin crossover (SCO) polymers [Fe(3-Fpy)2M(CN)4] (MII = Ni(1), Pd(2), Pt(3)) were nanostructured in the form of nanocrystals and nanoparticles, and their chemical, structural, and physical characterization was carried out using different experimental methods (powder X-ray diffraction, magnetic susceptibility measurements, Mossbauer and infrared spectroscopy, transmission and scanning electronic microscopy, etc.). Surfactant-free nanocrystals of average dimensions 400 × 400 × 30 nm (1a, 1a*, 2a, 3a) were synthesized from water in oil microemulsions (w/o) while nanoparticles of average size 200 × 100, 100 × 60, and 70 × 30 nm were obtained in poly(vinylpyrrolidone) (PVP) c…

The surface chemistry of iron oxide nanocrystals: surface reduction of γ-Fe2O3 to Fe3O4 by redox-active catechol surface ligands

2018

The effect of surface functionalization on the structural and magnetic properties of catechol-functionalized iron oxide magnetic (γ-Fe2O3) nanocrystals was investigated. γ-Fe2O3 nanocrystals (NCs) were synthesized from iron acetyl acetonate in phenyl ether with 1,2-tetradecanediol, oleic acid, and oleylamine. X-ray powder diffraction in combination with Mossbauer spectroscopy revealed the presence of γ-Fe2O3 (maghemite) particles only. Replacement of oleic acid (OA) with catechol-type 3,4-dihydroxyhydrocinnamic acid (DHCA) or polydentate polydopamine acrylate (PDAm) surface ligands leads to a pronounced change of the magnetic behavior of the γ-Fe2O3 nanocrystals and separated them into two …

Peculiarities of Forming of Magnetic Hardening in Sintered Nd15Fe76.2Ti1.0Al0.8B7 Permanent Magnet by Ageing

1999

Variations of the intrinsic coercivity ( i H c ) with ageing (at 293 to 1173 K for 0.45 to 57.6 ks) of sintered Nd 15 Fe 76.2 Ti 1.0 Al 0.8 B 7 have been investigated. The tests indicated minimum and maximum of intrinsic coercivity ( i H min c and i H max c ) at temperatures 725 K and 1025 K, respectively. The observed behaviour of i H c has been compared with microhardness measurements and microstructure observations (SEM, EDAX, domain structure (DS) and room temperature Mossbauer spectroscopy). SEM and DS investigations gave hints to a change in microstructure. Fitting of the Mossbauer spectra of permanent magnets for different i H c has shown that the magnetic hyperfine field Bhf of 8j2 …