Search results for "SSC"
showing 10 items of 69 documents
Prediction of water's isotropic nuclear shieldings and indirect nuclear spin–spin coupling constants (SSCCs) using correlation‐consistent and polariz…
2009
Density functional theory (DFT) was used to estimate water's isotropic nuclear shieldings and indirect nuclear spin-spin coupling constants (SSCCs) in the Kohn-Sham (KS) complete basis set (CBS) limit. Correlation-consistent cc-pVxZ and cc-pCVxZ (x = D, T, Q, 5, and 6), and their modified versions (ccJ-pVxZ, unc-ccJ-pVxZ, and aug-cc-pVTZ-J) and polarization-consistent pc-n and pcJ-n (n = 0, 1, 2, 3, and 4) basis sets were used, and the results fitted with a simple mathematical formula. The performance of over 20 studied density functionals was assessed from comparison with the experiment. The agreement between the CBS DFT-predicted isotropic shieldings, spin-spin values, and the experimenta…
Electro-optical characterization of ruthenium-based dye sensitized solar cells: A study of light soaking, ageing and temperature effects
2017
Abstract In this work, we report on the electro-optical characterization of Dye Sensitized Solar Cells (DSSCs) which use ruthenium complexes as sensitizers. In particular, several kinds of measurements have been performed to study the electrical performances and the efficiency levels of the cells at different operating conditions. In detail, the measurements have been conducted at varying temperatures and hours of light soaking. Our results show that the short circuit current density J SC , the open circuit voltage V OC and the conversion efficiency η increase with the hours of light soaking, while they decrease with temperature. A thorough investigation on the light soaking process at the …
One diode circuital model of light soaking phenomena in Dye-Sensitized Solar Cells
2018
Abstract In this work, we report on the modelling of light soaking effect on Ruthenium-based Dye Sensitized Solar cells (DSSCs). Such a phenomenon can be detected when exposing the cells at increasing hours of illumination and produces a reversible performance increase. Starting from the results obtained through the electro-optical characterization of the cells, we applied a one-diode circuital-model. Our results show a good agreement between the experimental and the simulated data, with a mean square error in the order of 10−12 and a maximum error in current lower than 0.6%. Finally such results allowed us to infer some precise trends followed by the cells main electrical parameters and of…
DNA-methylation dependent regulation of embryo-specific 5S ribosomal DNA cluster transcription in adult tissues of sea urchin Paracentrotus lividus
2013
Abstract We have previously reported a molecular and cytogenetic characterization of three different 5S rDNA clusters in the sea urchin Paracentrotus lividus and recently, demonstrated the presence of high heterogeneity in functional 5S rRNA. In this paper, we show some important distinctive data on 5S rRNA transcription for this organism. Using single strand conformation polymorphism (SSCP) analysis, we demonstrate the existence of two classes of 5S rRNA, one which is embryo-specific and encoded by the smallest (700 bp) cluster and the other which is expressed at every stage and encoded by longer clusters (900 and 950 bp). We also demonstrate that the embryo-specific class of 5S rRNA is ex…
Comparison on the use of PV systems in the vertical walls
2015
In this article the preliminary evaluation of the performance of a photovoltaic window is presented. The aim is to trace the behavior of next-generation systems, which favor architectonical integration. Three different systems have been taken into account: a dye sensitized solar cell (DSSC), blue and grey caved silicon panels. The systems can be placed behind a window or behind a wall of glass blocks.
DSSC-integrated Glassblocks for the construction of Sustainable Building Envelopes
2014
The paper shows the first results of the optical performance analysis carried out on the DSSC integrated glassblock, an innovative building product developed at the Department of Architecture of the University of Palermo. In the field of a research that is being conducted in order to define innovative solutions for the construction of photovoltaic and energy efficient translucent building envelopes, different hypotheses of integration of DSSC into the glassblock have been foreseen. The integration of glassblock with third generation PV systems allows to define a novel building-PV product that meets the current requirements of the BIPV (Building Integrated Photovoltaics) market. By means of …
Performance of the Glass Block in Photovoltaic Generation
2015
In this article is presented the preliminary evaluation of the performance of radiation transmission of glass block, used in support of photovoltaic cells, investigating different internal surface points of the block, which are subject to different shading during daylight hours. The aim is to establish how the edging setting, the only opaque element, can reduce the amount of light radiation during the day, introducing in this way a reduction of efficiency of the entire generation system. The generation system can be based on traditional photovoltaic cells or on the most suitable dye sensitized solar cells. An experimental measurement setup employing a microprocessor-based instrument has bee…
PV systems in the vertical walls: A comparison of innovative structures
2016
This paper presents the performance comparison of PV windows with the purpose of tracing the behavior of next-generation systems, which could favor architectonical integration. More in detail, a dye sensitized solar cell (DSSC) and blue and grey thin film silicon panels have been analyzed. The systems can be placed behind a window or behind a wall of glass blocks. The three generation systems are then compared in terms of both efficiency and Fill Factor.
Scrotal Masses
2009
No abstract available
A new Frequency Domain Measure of Causality based on Partial Spectral Decomposition of Autoregressive Processes and its Application to Cardiovascular…
2019
We present a new method to quantify in the frequency domain the strength of directed interactions between linear stochastic processes. This issue is traditionally addressed by the directed coherence (DC), a popular causality measure derived from the spectral representation of vector autoregressive (AR) processes. Here, to overcome intrinsic limitations of the DC when it needs to be objectively quantified within specific frequency bands, we propose an approach based on spectral decomposition, which allows to isolate oscillatory components related to the pole representation of the vector AR process in the Z-domain. Relating the causal and non-causal power content of these components we obtain…