Search results for "STABILITY"

Mise en évidence d'une production de protéases exocellulaires par les levures au cours de la fermentation alcoolique du moût de raisin

1980

<p style="text-align: justify;">La durée d'activité très limitée dans le temps des protéases du raisin est confirmée en vinification en blanc, mais une nouvelle activité protéolytique peut être caractérisée à 37 °C et à pH 3,7 dans le moût au cours de la fermentation alcoolique.</p><p style="text-align: justify;">Cette activité doit être attribuée à des protéases exocellulaires libérées dans le milieu des levures. Parmi les souches essayées <em>S. bayanus</em> a une activité protéolytique plus importante que <em>S. cerevisiae</em>, ce qui se traduit par l'obtention de vins plus riches en azote soluble, donc plus stables du point de vue protéique et …

Stability of melt flow due to a traveling magnetic field in a closed ampoule

2004

The linear three-dimensional instability of the flow due to a low frequency traveling magnetic field in a regular cylinder is studied numerically for height-to-diameter ratios in the range [0.5:2.5]. The first instability has the form of an azimuthal wave with wave numbers between 1 and 6 depending on the aspect ratio. It is shown that the flow is stable if the Reynolds number is below 290. Even stronger stationary flows may be obtained in a flattened cylinder.

Novel synthesis of spherical MCM-48

1999

Abstract A novel synthesis route was developed for the cubic member of the M41S family, MCM-48, with a three-dimensional pore system allowing the formation of submicrometre- to micrometre-sized beads with a narrow pore-size distribution. The synthesis is based on the modified Stober method applying tetraethoxysilane, ethanol, water, ammonia and n -hexadecyltrimethylammonium bromide as template. The specific surface area, the specific pore volume and the average pore diameter were varied in the following ranges: 900–1600 m 2  g −1 , 0.5–0.9 cm 3  g −1 and 2–3 nm. Aluminium-, chromium-, gallium-, niobium- and vanadium-MCM-48 were also synthesized following this procedure.

The surface electronic structure of stoichiometric and defective LiF surfaces studied with MIES and UPS in combination with ab-initio calculations

1997

Abstract UPS (He I) and metastable impact electron spectroscopy (MIES) spectra of the LiF(100) single crystal surface and stoichiometric LiF films are presented. The spectra are interpreted on the basis of ab-initio electronic structure calculations. Defective surfaces, produced by electron dosing, were studied in the same manner. The MIES spectra reveal that the electron dosing produces metallic patches on the surface, but no uniform Li adlayer. The calculation show that the F-center contribution to the electron emission is very close in energy to that from the metallic patches; thus, the two contributions cannot be distinguished by the present experimental techniques.

Atomic and electronic structure of the corundum (0001) surface: comparison with surface spectroscopies

1997

Abstract The electronic structure and geometry of the Al-terminated corundum (0001) surface were studied using a slab model within the ab-initio Hartree-Fock technique. The distance between the top Al plane and the next O basal plane is found to be considerably reduced on relaxation (by 0.57 A, i.e. by 68% of the corresponding interlayer distance in the bulk). An interpretation of experimental photoelectron spectra (UPS He I) and metastable impact electron spectra (MIES) is given using the calculated total density of states of the slab and the projections to the atoms, atomic orbitals, and He 1s floating atomic orbital at different positions above the surface. Calculated projected densities…

Van't Hoff's stability rule

1931

Pyrenyl substituted 1,8-naphthalimide as a new material for weak efficiency-roll-off red OLEDs: a theoretical and experimental study

2018

Based on the theoretical calculations of excited states and semiconducting properties, a new 1,8-naphthalimide derivative having an electron-donating 1-pyrenyl group at the C-4 position was designed and synthesized. This derivative exhibited an excellent thermal stability and bipolar charge carrier transport ability. It was successfully utilized as a host in red phosphorescent organic light-emitting diodes showing an efficient energy transfer from the host to the phosphorescent emitter. The derivative may be a single material electroplex-forming host for PhOLEDs. The best fabricated red emitting device demonstrated maximum current, power, and external quantum efficiencies of 10.8 cd A−1, 7 …

Arylazopyrazoles for Long-Term Thermal Energy Storage and Optically Triggered Heat Release below 0 °C.

2020

Arylazopyrazole derivatives based on four core structures (4pzMe, 3pzH, 4pzH, and 4pzH-F2) and functionalized with a dodecanoate group were demonstrated to store thermal energy in their metastable Z isomer liquid phase and release the energy by optically triggered crystallization at -30 °C for the first time. Three heat storage-release schemes were discovered involving different activation methods (optical, thermal, or combined) for generating liquid-state Z isomers capable of storing thermal energy. Visible light irradiation induced the selective crystallization of the liquid phase via Z-to-E isomerization, and the latent heat stored in the liquid Z isomers was preserved for longer than 2 …

Comparison of thermal stratification, light attenuation and Chlorophyll-a dynamics between the ends of Lake Tanganyika

2002

Thermal structure, light attenuation, and chlorophyll-a dynamics within the upper 100 m at the northern and southern ends of Lake Tanganyika were measured from August 1995–July 1996. Pronounced variability of thermal structure in time, depth and region were observed. During the dry windy season (June–September), the water column in the south was largely isothermal down to 100 m, while in the north stratification was detectable. Subsequently, in October, cessation of winds coincided with a reestablishment and strengthening of thermal stratification in the south, and a distinct rise of a weakened thermocline in the north was accompanied by an increase in epilimnetic concentrations of dissolve…

Water-Soluble Chlorophyll Protein (WSCP) Stably Binds Two or Four Chlorophylls

2017

Water-soluble chlorophyll proteins (WSCPs) of class IIa from Brassicaceae form tetrameric complexes containing one chlorophyll (Chl) per apoprotein but no carotenoids. The complexes are remarkably stable toward dissociation and protein denaturation even at 100 °C and extreme pH values, and the Chls are partially protected against photooxidation. There are several hypotheses that explain the biological role of WSCPs, one of them proposing that they function as a scavenger of Chls set free upon plant senescence or pathogen attack. The biochemical properties of WSCP described in this paper are consistent with the protein acting as an efficient and flexible Chl scavenger. At limiting Chl concen…