Search results for "STAI"
showing 10 items of 5922 documents
Reduced grey brookite for noble metal free photocatalytic H2evolution
2021
Herein we introduce for the first time a reduced “grey” brookite TiO2 photocatalyst, produced by thermal hydrogenation of brookite nanoparticles, that shows a remarkable noble metal free photocatalytic H2 evolution. Its activity is substantially higher than that of other TiO2 polymorphs, i.e. anatase or rutile, comparably sized and activated by hydrogenation under optimized conditions. Along with brookite powders, an oriented brookite single crystal was investigated as a defined surface to confirm the effects of the hydrogenation treatment. By a combination of electron paramagnetic resonance (EPR), electron and X-ray characterization techniques applied to the powders and single crystal, we …
Stabilizing nanostructured lithium insertion materials via organic hybridization: A step forward towards high-power batteries
2014
Abstract Herein, we present the electrochemical characterization of carbon-coated TiO 2 nanorods, obtained by carbonizing RAFT (reversible addition fragmentation chain transfer) polymerization derived block copolymers anchored on anatase TiO 2 nanorods. These carbon-coated TiO 2 nanorods show an improved electrochemical performance in terms of first cycle reversibility, specific capacity, cycling stability, and high rate capability. More importantly, however, the structural disordering observed in the uncoated TiO 2 nanorods by means of galvanostatic and potentiodynamic cycling as well as ex situ XRD analysis, does not occur for the carbon-coated material. Preventing this structural disorde…
Photoelectrochemical characterization of anatase-rutile mixed TiO2 nanosponges
2016
This work studies the influence of using hydrodynamic conditions during anodization on the morphology and electrochemical properties of anatase/rutile mixed TiO2 nanotubes (Reynolds number, Re = 0) and nanosponges (Re > 0). To this purpose different techniques were used, such as: microscopy techniques (Field-Emission Scanning Electron Microscope, FE-SEM, and Confocal Laser-Raman Spectroscopy), Electrochemical Impedance Spectroscopy (EIS), Mott Schottky (MS) analysis and photoelectrochemical water splitting tests. This investigation demonstrates that the morphology of TiO2 nanostructures may be greatly affected due to the hydrodynamic conditions and it can be adjusted in order to increase th…
Photocatalytic Selective Oxidation of 5-(Hydroxymethyl)-2-furaldehyde to 2,5-Furandicarbaldehyde in Water by Using Anatase, Rutile, and Brookite TiO2…
2013
5-(Hydroxymethyl)-2-furaldehyde (HMF) was selectively oxidized to 2,5-furandicarbaldehyde (FDC) in; aqueous medium by using home prepared (HP) anatase, rutile, and brookite TiO2 nanoparticles. HP samples were prepared via a sol-gel method by using TiCl4 as the TiO2 precursor. Commercial TiO2 catalysts were also used for, comparison. All samples were characterized by BET specific surface area, XRD, TGA, and SEM, and the reactivity results showed that HP catalysts are predominantly amorphous and give rise to selectivities toward FDC more than twice that of commercial and well crystallized catalysts.
Generalized power-angle control for grid-forming converters: A structural analysis
2022
Several control schemes have been recently proposed and studied as grid-forming controls for power converters. In all these schemes, the power-angle control loop is the part which defines the fundamental capabilities of the grid-forming control: that control loop governs in fact the inherent synchronization mechanism of the power converter, the power sharing with the other generation sources in the system and the oscillatory characteristics of the converter-based resource. This article introduces a general formulation for the power-angle control characterizing the grid-forming concept for power converters. The generalized power-angle control is based on a polynomial fraction formulation, an…
Pedotechnique applications in large-scale farming: Economic value, soil ecosystems services and soil security
2019
Abstract Since ancient times Humans and Soil have experienced interwoven links. Nowadays soil scientists continue to stress such links highlighting the importance of soil in: i) satisfying the ever growing Human demand for food, water and energy, and ii) providing ecosystem services that mitigate climate changes, influence human health and improve biodiversity. Pedotechniques are recently used to generate soils suitable for table grape cultivation in order to increase productivity and grape quality, thus to get substantial financial returns. We show one emblematic study case of pedotechniques applied in Sicily (Italy). Aims of the investigation were: i) stressing threats to soil security de…
Premature ovarian senescence and a high miscarriage rate impair fertility in women with HCV
2017
Background & Aims Premenopausal women who are HCV positive (HCV+) have failing ovarian function, which is likely to impact their fertility. Thus, we investigated the reproductive history, risk of infertility, and pregnancy outcomes in women of childbearing age who were HCV+. Methods Three different groups were studied: (1) Clinical cohort: 100 women who were HCV+ and also had chronic liver disease (CLD), age matched with 50 women who were HBV+ with CLD and with 100 healthy women; all women were consecutively observed in three gastroenterology units in hospitals in Italy; (2) 1,998 women who were HCV+ and enrolled in the Italian Platform for the Study of Viral Hepatitis Therapies (PITER)…
Characterization of cell wall proteins from yeast and mycelial cells of Candida albicans by labelling with biotin: Comparison with other techniques
1992
Candida albicans ATCC 26555 blastoconidia and blastoconidia bearing germ tubes were metabolically labelled by incubating the cells with 14C-labelled protein hydrolysate and were subsequently tagged with biotin. Double-labelled (radioactive and biotinylated) cell wall proteins and glycoproteins were extracted from intact cells of both growth forms by treatment with 2-mercaptoethanol (beta ME) and with beta-glucanases (Zymolyase) after treatment with beta ME. The beta ME- and Zymolyase-extracts were separated by sodium dodecyl sulfate-polyacrylamide gel electrophoresis and western blotted (immunoblotted) to nitrocellulose paper. Polyacrylamide gels were stained with Coomassie blue and process…
Pastaigas ar suni pilsētā: vienošanās par telpu un sociālā mijiedarbība
2021
Bakalaura darba "Pastaigas ar suni pilsētā: vienošanās par telpu un sociālā mijiedarbība" mērķis ir izpētīt desmit cilvēku, kuri ikdienā pastaigājas ar saviem suņiem Rīgas centrālajā daļā, neformālo praksi. Šīs tēmas nozīmīgums ir divējāds. Viens no iemesliem ir suņu adopcijas un iegādes pieaugums pandēmijas laikā, kas tiešā veidā attiecas uz vienošanās par telpu biežumu un intensitāti. Un otrs attiecas uz noteikumiem, kas ir spēkā, lai pārraudzītu šo praksi un to, kā tā īstenojas realitātē. Šī darba mērķis ir saprast, kā notiek tas, ka cilvēkiem, kuri pastaigājas ar suņiem, ir pastāvīgi jāvienojas par telpu, kā izskatās šīs telpas koplietošanas tikšanās un kā šī mijiedarbības prakse veido …
ACTIVE HOUSE PROTOCOL APPLICATION IN MEDITERRANEAN CLIMATE : an energy-efficient kindergarden in Coppito
2022
La U.E. intende raggiungere la neutralità climatica entro il 2050. Questo articolo mira a colmare il divario nella scelta di soluzioni migliorative delle condizioni di vita negli assetti territoriali (SDG n.11) per il raggiungimento delle prestazioni energetiche attese (SDG n.7) e diffondere l’adozione di nuovi approcci e misure per la progettazione sostenibile (SDG n.13). Tali obiettivi sono stati conseguiti mediante l’applicazione di un processo di reverse engineering all’asilo Ape Tau, L’Aquila, località Coppito, dopo il sisma del 2009. Le soluzioni progettuali impiegate nell’edificio sono state analizzate secondo livelli quantitativi suggeriti dall’approccio olistico del protocollo Acti…