Search results for "STANDARD"
showing 10 items of 3299 documents
Evaluation of Terra/MODIS atmospheric profiles product (MOD07) over the Iberian Peninsula: a comparison with radiosonde stations
2014
Remote sensing techniques are a useful tool for continuous observation of the Earth at global scale. However, products derived from remote sensing data require a rigorous validation using in situ data. Moderate Resolution Imaging Spectroradiometer (MODIS) is not really a sounding instrument, but it does have 16 infrared bands (bands 20–36 covering the spectral range from 3 µm to 14 µm) that allow the retrieval of temperature and moisture profiles as well as total column integrated magnitudes. In this paper we show the results obtained in the evaluation of MOD07 daytime and nighttime products over the Iberian Peninsula during the decade from 2000 to 2010 using nine radiosonde stations. Altho…
Equilibrium properties of the reaction H2⇌ 2H by classical molecular dynamics simulations
2013
We have developed a classical molecular dynamics model for the hydrogen dissociation reaction, containing two- and three-particle potentials derived by Kohen, Tully and Stillinger. Two fluid densities were investigated for a wide range of temperatures, and 11 fluid densities were considered for one temperature. We report the temperature range where the degree of reaction is significant, and also where a stable molecule dominates the population in the energy landscape. The three-particle potential, which is essential for the reaction model and seldom studied, together with the two-particle interaction lead to a large effective excluded volume diameter of the molecules in the molecular fluid.…
B-parameters for ΔS=2 supersymmetric operators
1998
We present a calculation of the matrix elements of the most general set of DeltaS=2 dimension-six four-fermion operators. The values of the matrix elements are given in terms of the corresponding B-parameters. Our results can be used in many phenomenological applications, since the operators considered here give important contributions to K^0--K^0bar mixing in several extensions of the Standard Model (supersymmetry, left-right symmetric models, multi-Higgs models etc.). The determination of the matrix elements improves the accuracy of the phenomenological analyses intended to put bounds on basic parameters of the different models, as for example the pattern of the sfermion mass matrices. Th…
Imidazole-amino acids. Conformational switch under tautomer and pH change.
2022
AbstractReplacement of the main chain peptide bond by imidazole ring seems to be a promising tool for the peptide-based drug design, due to the specific prototropic tautomeric as well as amphoteric properties. In this study, we present that both tautomer and pH change can cause a conformational switch of the studied residues of alanine (1–4) and dehydroalanine (5–8) with the C-terminal peptide group replaced by imidazole. The DFT methods are applied and an environment of increasing polarity is simulated. The conformational maps (Ramachandram diagrams) are presented and the stability of possible conformations is discussed. The neutral forms, tautomers τ (1) and π (2), adapt the conformations…
Length of endodontic files measured in digital radiographs with and without noise-suppression filters: an ex-vivo study
2011
The aim of this study is to evaluate if theoretically possible edge shifts induced by noise-suppression filters potentially occur on objects found in digital radiographs. Most manufacturers carry out noise-suppression filtering of their images before they are displayed to the user. It is not usually possible for the user to disrupt the function of the filters. The use of these filters can lead to deletion of small image structures.K-files (ISO size 06, 08, 10 and 15) were placed in the root canals of 6 human teeth located in cadaver jaw segments. File tip positions were measured on original and filtered digital images by three observers. The file position was marked on each filtered image a…
Income Differences in Regions of Latvia – Problems and Challenges
2019
Income differences in regions of Latvia is becoming a greater problem for families as there are made decisions for emigration, for municipalities as there are significant reductions in tax (income and property) payers and for entrepreneurs as there are less customers for their products and services: those aspects are on great importance but not enough researched and discussed in academic research. Purpose of the study is to analyse income differences in the regions of Latvia. The tasks of the study: 1 to review theoretical background of income differences in context of regional development; 2 to review existing research of income differences in the regions in EU; 3 to analyse problems of in…
On-line analysis of carbonyl compounds with derivatization in aqueous extracts of atmospheric particulate PM10 by in-tube solid-phase microextraction…
2011
Abstract A new device for carbonyl compounds based on coupling on-line and miniaturizing both, sample pretreatment and chromatographic separation, is reported. Two capillary columns, a GC capillary column (95% methyl–5% phenyl substituted backbone, 70 cm × 0.32 mm i.d., 3 μm film thickness) in the injection valve for in-tube solid-phase microextraction (IT-SPME) and a Zorbax SB C18 (150 mm × 0.5 mm i.d., 5 μm particle diameter) LC capillary column were employed. Different combinations of IT-SPME and derivatization using 2,4-dinitrophenylhydrazine (DNPH) were examined for mixtures containing 15 carbonyl compounds (aliphatic, aromatic and unsaturated aldehydes and ketones). A screening analys…
Analyser of chromium and/or cobalt
2003
Abstract Two stopped-flow manifolds have been proposed for individual or simultaneous determination of chromium and cobalt in water samples. Automated procedures based on multicommutation systems have emphasised the differences of their catalytic effect in luminol–hydrogen peroxide chemiluminescence reaction. A more rapid decay of signal was observed for Co for both configurations (flow injection or continuous injection). The influence of chemical and hydrodynamic variables has been studied in order to establish the robustness of method. The analysis rate was lower 1.5 min per replicate. Chemometric tools have been employed for the resolution of their contributions. Partial least squares (P…
Determination of Phenol by Preconcentration‐Direct Chemiluminescence in a FIA Assembly
2005
Abstract The determination of phenol in water samples is proposed with the aid of a flow‐injection system. The analytical procedure is based on the direct chemiluminometric emission by oxidation of the analyte with potassium permanganate in acidic medium. The flow assembly is provided with a solid‐phase reactor filled with a resin type XAD‐4 for analyte preconcentration. A large study of potential interferences, namely, amino acids reaching water through degradation of organic matter; metals and inorganic metal ions typically present in water interfering with the CL emission of the parent compound, was performed. The calibration graph was linear over the phenol concentration range 1.0–20.0 …
Determination of tea tree oil terpenes by headspace gas chromatography mass spectrometry
2016
An alternative procedure was developed for determining quality control of terpenes in tea tree oil commercial samples. The method is based on static headspace gas chromatography mass spectrometry measurements. Absolute limits of detection ranged from 1 ng for p-cymene to 71 ng for terpinen-4-ol. The accuracy of the developed methodology was evaluated by comparing the obtained eucalyptol and terpinen-4-ol concentrations with those provided for a certified sample and by comparing the developed procedure with literature tea tree oil analysis methodology. In the same way, spiked commercial samples provided recovery values ranging between 94% and 100% for all the target analytes with relative st…