Search results for "STATES"
showing 10 items of 1532 documents
Spin Crossover and Long-Lived Excited States in a Reduced Molecular Ruby.
2020
Abstract The chromium(III) complex [CrIII(ddpd)2]3+ (molecular ruby; ddpd=N,N′‐dimethyl‐N,N′‐dipyridine‐2‐yl‐pyridine‐2,6‐diamine) is reduced to the genuine chromium(II) complex [CrII(ddpd)2]2+ with d4 electron configuration. This reduced molecular ruby represents one of the very few chromium(II) complexes showing spin crossover (SCO). The reversible SCO is gradual with T 1/2 around room temperature. The low‐spin and high‐spin chromium(II) isomers exhibit distinct spectroscopic and structural properties (UV/Vis/NIR, IR, EPR spectroscopies, single‐crystal XRD). Excitation of [CrII(ddpd)2]2+ with UV light at 20 and 290 K generates electronically excited states with microsecond lifetimes. This…
Succession of States in Respect of Treaties on Human Rights
2022
1. Preliminary Remarks. 2. The Vienna Convention on Succession of States in respect of Treaties. 2.1 Scope of Application. 2.2 Reduction in its Scope of Application. 2.3 Increased Scope of Application. 3. Succession of States Practice in respect of United Nations Human Rights Treaties. 3.1 Membership in the United Nations Organization and Succession of States. 3.1.1 Membership in the United Nations Organization. 3.1.2 Succession of States to Membership in the United Nations Organization. 3.2 Succession of States and United Nations Human Rights Treaties. 4. Succession of States Practice in respect of Human Rights Treaties Concluded by the Council of Europe. 4.1 Membership in the Council of E…
Self-Regulation in High-Level Ice Hockey Players: An Application of the MuSt Theory
2021
The purpose of the study was to examine the validity of core action elements and feeling states in ice hockey players in the prediction of performance. A second aim of the study was to explore the effectiveness of a 30-day program targeting action and emotion regulation. Participants were male ice hockey players drawn from two teams competing at the highest level of the junior Finnish ice hockey league. They were assigned to a self-regulation (n = 24) and a control (n = 19) group. The self-regulation program focused on the recreation of optimal execution of core action elements and functional feeling states. Separate repeated measures MANOVAs indicated significant differences in ratings of …
Perfectionism and performance-related psychobiosocial states: The mediating role of competition appraisals.
2022
Using the multi-states (MuSt) theory as a framework, the present study focused on the individual (personality) antecedents of psychobiosocial states. Psychobiosocial states comprise emotional subjective experiences and their correlates (cognitive, motivational, volitional, bodily, motor-behavioural, operational, and communicative), that can be functional for performance (helpful) or dysfunctional (harmful). Specifically, we examined the relationships between two perfectionism dimensions (perfectionistic strivings and concerns) and functional and dysfunctional psychobiosocial states. The hypothesised mediational role of competitive appraisals was also tested. Participants (N = 271, 138 femal…
On the correlation of psychological characteristics within recreational marathon runners
2015
Oschwald Miles, 2015. On the Correlation of Psychological Characteristics Within Recreational Marathon Runners. Master’s Thesis in Sport and Exercise Psychology. Department of Sport Science. University of Jyväskylä. University of Jyväskylä. 40 p. The purpose of this research study was to explore the performance related experiences of recreational marathon runners. Specifically, the relationship these experiences have with other psychological constructs involved in undertaking and maintaining participation in a given sport. Using self-report measures the psychobiosocial states prior to most successful performances, achievement goal orientations, motivation and regulation for sport participat…
Flat-band superconductivity in strained Dirac materials
2016
We consider superconducting properties of a two-dimensional Dirac material such as graphene under strain that produces a flat band spectrum in the normal state. We show that in the superconducting state, such a model results in a highly increased critical temperature compared to the case without the strain, inhomogenous order parameter with two-peak shaped local density of states and yet a large and almost uniform and isotropic supercurrent. This model could be realized in strained graphene or ultracold atom systems and could be responsible for unusually strong superconductivity observed in some graphite interfaces and certain IV-VI semiconductor heterostructures.
Competition of electron-phonon mediated superconductivity and Stoner magnetism on a flat band
2018
The effective attractive interaction between electrons, mediated by electron-phonon coupling, is a well-established mechanism of conventional superconductivity. In metals exhibiting a Fermi surface, the critical temperature of superconductivity is exponentially smaller than the characteristic phonon energy. Therefore, such superconductors are found only at temperatures below a few kelvin. Systems with flat energy bands have been suggested to cure the problem and provide a route to room-temperature superconductivity, but previous studies are limited to only BCS models with an effective attractive interaction. Here we generalize Eliashberg's theory of strong-coupling superconductivity to syst…
Field dependence of the vortex-core sizes in dirty two-band superconductors
2019
We study the structure of Abrikosov vortices in two-band superconductors for different external magnetic fields and different parameters of the bands. The vortex core size determined by the coherence lengths are found to have qualitatively different behaviour from that determined by the quasiparticle density of states spatial variation. These different vortex core length scales coincide near the upper critical field, while the discrepancy between them becomes quite significant at lower fields. Within the diffusive approximation we demonstrate several generic regimes in the field dependence of the vortex core sizes determined by the disparity of diffusion constants in the two bands.
Electron-phonon interaction in flat-band superconductivity
2017
Parhaiten tunnettu suprajohtavuuden syntymekanismi perustuu fononien välittämään vetovoimaan elektronien välillä. Tässä tutkielmassa tutkin fononien välittämää suprajohtavuutta systeemeissä, jossa elektronivyöt ovat tasomaisia. Tasovyöllä elektronien dispersio on erittäin heikko, jolloin tilatiheys on tavanomaista suurempi. Tämän takia suprajohtavuus tasovyöllä on tavanomaista voimakkaampi silloin kun elektronien välinen vetovoima on heikko. Eliashbergin teoria on elektroni–fononi-suprajohtavuuden teoria, joka ottaa luonnollisella tavalla fononien äärellisen nopeuden huomioon elektronien välisessä vuorovaikutuksessa. Pohjustuksena tasovyösuprajohtavuuteen perehdyn Eliashbergin teoriaan ensi…
Contributions of mean and shape of blood pressure distribution to worldwide trends and variations in raised blood pressure: A pooled analysis of 1018…
2018
Background: Change in the prevalence of raised blood pressure could be due to both shifts in the entire distribution of blood pressure (representing the combined effects of public health interventions and secular trends) and changes in its high-blood-pressure tail (representing successful clinical interventions to control blood pressure in the hypertensive population). Our aim was to quantify the contributions of these two phenomena to the worldwide trends in the prevalence of raised blood pressure. Methods: We pooled 1018 population-based studies with blood pressure measurements on 88.6 million participants from 1985 to 2016. We first calculated mean systolic blood pressure (SBP), mean dia…