Search results for "Scaling"
showing 10 items of 754 documents
Critical Micelle Concentration of Micelles with Different Geometries in Diblock Copolymer/Homopolymer Blends
2011
Summary In this paper, we have investigated the shape transition ofanisolatedmicelleformedintheAB-diblockcopolymerandA-homopolymer blends. SCFT has been employed tocompute the CMC for three different morphologies:lamellar, cylindrical and spherical. By comparing theCMC for different shapes, we can determine the preferredmicelle geometry. Several factors can influence the micellemorphology,andwehaveexploredtheeffectsofthediblockasymmetry, the homopolymer/copolymer length ratio andthe monomer–monomer interaction, on the micelle shapetransitions. It is found the micelle undergoes a sequenceof shape transitions, lamellar ! cylindrical ! spherical,when the A-block of the copolymer becomes longer.…
Effects of partial self-ordering of Si dots formed by chemical vapor deposition on the threshold voltage window distribution of Si nanocrystal memori…
2006
We study the role that the denuded zone around Si nanocrystals obtained by chemical vapor deposition plays on the fluctuations of the dot surface coverage. In fact, the capture mechanism of the silicon adatoms in the proximity of existing dots restricts the number of possible nucleation sites, the final dot size, and the dot position, thus driving the process toward partial self-order. We numerically evaluate the relative dispersion of surface coverage for several gate areas and compare the results to the fully random case. The coverage dispersion is related to the fluctuations from bit to bit of the threshold voltage window (Δ Vth) distribution of nanocrystal memories. The evaluations, com…
Study of silicon crystal surface formation based on molecular dynamics simulation results
2014
Abstract The equilibrium shape of 〈 110 〉 -oriented single crystal silicon nanowire, 8 nm in cross-section, was found from molecular dynamics simulations using LAMMPS molecular dynamics package. The calculated shape agrees well to the shape predicted from experimental observations of nanocavities in silicon crystals. By parametrization of the shape and scaling to a known value of { 111 } surface energy, Wulff form for solid-vapor interface was obtained. The Wulff form for solid–liquid interface was constructed using the same model of the shape as for the solid–vapor interface. The parameters describing solid–liquid interface shape were found using values of surface energies in low-index dir…
Phonons of hexagonal BN under pressure: Effects of isotopic composition
2021
Raman scattering experiments on isotopically enriched hexagonal boron nitride have been performed under pressure up to 11 GPa at room temperature. The sublinear increase of the Raman-active E2g mode frequencies has been characterized. The pressure behavior has been analyzed by means of a bond-stiffness–bond-length scaling parameter γ which takes into consideration the vast differences in a- and c-axis compressibilities. The interlayer shear mode exhibits a γ parameter similar to that of graphite, and the mode frequency in isotopically pure samples separates faster at low pressures as a result of van der Waals interactions. Because of the extremely low a-axis compressibility, the intralayer …
Supramolecular Order of Solution-Processed Perylenediimide Thin Films
2011
N,N ′ -1 H ,1 H -perfl uorobutyl dicyanoperylenecarboxydiimide (PDIF-CN 2 ), a soluble and air stable n-type molecule, undergoes signifi cant reorganization upon thermal annealing after solution deposition on several substrates with different surface energies. Interestingly, this system exhibits an exceptional edge-on orientation regardless of the substrate chemistry. This preferential orientation is rationalized in terms of strong intermolecular interactions between the PDIF-CN 2 molecules. The presence of a pronounced π– π stacking is confi rmed by combining near-edge X-ray absorption fi ne structure spectroscopy (NEXAFS), dynamic scanning force microscopy (SFM) and surface energy measure…
Temperature control during Spark Plasma Sintering and application to up-scaling and complex shaping
2013
International audience; The determination and the homogeneity of the sample temperature during consolidation of powders by Spark Plasma Sintering (SPS) are addressed. Densifications were carried out in three different facilities differing by their constructors and their size. A structural transformation activated in a TiAl alloy was used as a marker of the sample temperature and finite element modeling were performed to evaluate the temperature at each point of the set-up. A good agreement between experimental and simulated data is exhibited. Alloys with identical microstructures were sintered and the homogeneity of the microstructure was better in the largest machines or when the sample wa…
Long-cavity all-fiber ring laser actively mode locked with an in-fiber bandpass acousto-optic modulator.
2013
We demonstrate low-frequency active mode locking of an erbium-doped all-fiber ring laser. As the mode locker, we used a new in-fiber bandpass acousto-optic modulator showing 74% modulation depth, 3.7 dB power insertion losses, 4.5 nm of optical bandwidth, and 20 dB of nonresonant light suppression. The laser generates 330 ps mode-locked pulses over a 10 ns pedestal, at a 1.538 MHz frequency, with 130 mW of pump power. Fil: Cuadrado Laborde, Christian Ariel. Universidad de Valencia; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de In…
Raman spectra of (PbS)1.18(TiS2)2 misfit compound
2007
Abstract A Raman study on the (PbS)1.18(TiS2)2 semiconductor structure with incommensurate layers (misfit) is reported. The different bands observed in the spectra are attributed to both the TiS2 host layers, at 219 (Eg) and 333 (A1g) cm−1, and the intercalated PbS layers: the LO(Γ), 2LO and 3LO phonons at 203, 412 and 634 cm−1, respectively. A phonon peak probably related to the superposition of TiS2 and PbS vibrations, was observed near 286 cm−1. The decrease of the phonon wave numbers (of the modes located at 203, 333, 412, and 634 cm−1) with increasing laser power pointed out negative temperature coefficients of these modes. A peak appearing with laser power near 151 cm−1 is discussed. …
Scaling the Sensitivity of Integrated Plasmo-Photonic Interferometric Sensors
2019
We present a new optical biosensing integration approach with multifunctional capabilities using plasmonic and photonic components on the same chip and a new methodology to design interferometric b...
Influence of Cavity Loss Upon Performance of Q-Switched Erbium-Doped Fiber Laser
2013
Performance of an actively Q-switched erbium-doped fiber laser in function of intracavity loss is discussed. We show experimentally and theoretically (employing a distributed model that takes into account two contra-propagating laser waves) that the laser performance strongly depends on the intracavity loss of different kinds. We reveal in particular that the dominant source of smaller than expected pulse energy is the loss via excited-state absorption, inherent in erbium-doped fibers. We also discuss the other important processes involved in active Q-switching, such as passive losses and residual active fiber charge, the impact of which is clarified by a straightforward comparison of the m…