Search results for "Scheme"

showing 10 items of 527 documents

Structural and Luminescent Properties of Homoleptic Silver(I), Gold(I), and Palladium(II) Complexes with nNHC-tzNHC Heteroditopic Carbene Ligands

2019

Novel silver(I), gold(I), and palladium(II) complexes were synthesized with bidentate heteroditopic carbene ligands that combine an imidazol-2-ylidene (nNHC) with a 1,2,3-triazol-5-ylidene (tzNHC) connected by a propylene bridge. The silver(I) and gold(I) complexes were dinuclear species, [M-2(nNHC-tzNHC)(2)](PF6)(2) (M = Ag or Au), with the two bidentate ligands bridging the metal centers, whereas in the palladium(II) complex [Pd(nNHC-tzNHC)(2)]-(PF6)(2), the two ligands were chelated on the same metal center. Because of the presence of two different carbene units, isomers were observed for the gold(I) and palladium(II) complexes. The molecular structures of the head-to-tail isomer for gol…

Denticity010405 organic chemistryGeneral Chemical EngineeringINTEGRATION SCHEMEchemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesArticleREACTIVITY0104 chemical scienceslcsh:ChemistryELECTRONIC-PROPERTIESchemistry.chemical_compoundchemistrylcsh:QD1-999Polymer chemistrySTATISTICAL AVERAGEMETAL-COMPLEXESHomolepticLuminescenceCarbenePalladiumAPPROXIMATION
researchProduct

Rivestimenti di varietà algebriche contenuti in fibrati di piani proiettivi

Determinantal varietyprojective bundleCohen-Macaulay schemerivestimentiSettore MAT/03 - Geometriapoints in generic positionCover
researchProduct

A Unifying Framework for Perturbative Exponential Factorizations

2021

We propose a framework where Fer and Wilcox expansions for the solution of differential equations are derived from two particular choices for the initial transformation that seeds the product expansion. In this scheme, intermediate expansions can also be envisaged. Recurrence formulas are developed. A new lower bound for the convergence of theWilcox expansion is provided, as well as some applications of the results. In particular, two examples are worked out up to a high order of approximation to illustrate the behavior of the Wilcox expansion.

Differential equationGeneral MathematicsEquacions diferencials01 natural sciencesUpper and lower bounds010305 fluids & plasmas0103 physical sciencesConvergence (routing)Fer expansionComputer Science (miscellaneous)Applied mathematicsZassenhaus formula010306 general physicsEngineering (miscellaneous)Mathematicslcsh:MathematicsBellman problemWilcox expansionOrder (ring theory)lcsh:QA1-939Exponential functionTransformation (function)sequences of linear transformationsProduct (mathematics)Scheme (mathematics)MatemàticaMathematics
researchProduct

Pattern formation in clouds via Turing instabilities

2020

Pattern formation in clouds is a well-known feature, which can be observed almost every day. However, the guiding processes for structure formation are mostly unknown, and also theoretical investigations of cloud patterns are quite rare. From many scientific disciplines the occurrence of patterns in non-equilibrium systems due to Turing instabilities is known, i.e. unstable modes grow and form spatial structures. In this study we investigate a generic cloud model for the possibility of Turing instabilities. For this purpose, the model is extended by diffusion terms. We can show that for some cloud models, i.e special cases of the generic model, no Turing instabilities are possible. However,…

Diffusion (acoustics)Structure formation010504 meteorology & atmospheric scienceslinear stability analysisQC1-999Pattern formationCloud computingDynamical Systems (math.DS)01 natural sciences86A10 (Primary) 37G02 (Secondary)numerical simulationspattern formationMeteorology. ClimatologyFOS: MathematicsStatistical physicsMathematics - Dynamical Systems0101 mathematicsSpecial caseTuringspatial patterns0105 earth and related environmental sciencescomputer.programming_languagePhysicsbusiness.industryPhysicscloud schemes010101 applied mathematicsNonlinear systemSpatial ecologyQC851-999businesscomputerMathematics of Climate and Weather Forecasting
researchProduct

On Strong Convergence of Halpern’s Method for Quasi-Nonexpansive Mappings in Hilbert Spaces

2016

In this paper, we introduce a Halpern’s type method to approximate common fixed points of a nonexpansive mapping T and a strongly quasi-nonexpansive mappings S, defined in a Hilbert space, such that I − S is demiclosed at 0. The result shows as the same algorithm converges to different points, depending on the assumptions of the coefficients. Moreover, a numerical example of our iterative scheme is given.

Discrete mathematics010102 general mathematicsHilbert spaceApproximation algorithmFixed pointType (model theory)variational inequality01 natural sciences010101 applied mathematicssymbols.namesakefixed pointModeling and SimulationScheme (mathematics)Variational inequalityConvergence (routing)symbolsQA1-9390101 mathematicsAnalysisapproximation algorithmMathematicsMathematicsMathematical Modelling and Analysis
researchProduct

Admissible perturbations of alpha-psi-pseudocontractive operators: convergence theorems

2016

In the last decades, the study of convergence of fixed point iterative methods has received an increasing attention, due to their performance as tools for solving numerical problems. As a consequence of this fact, one can access to a wide literature on iterative schemes involving different types of operators; see [2, 4, 5]. We point out that fixed point iterative approximation methods have been largely applied in dealing with stability and convergence problems; see [1, 6]. In particular, we refer to various control and optimization questions arising in pure and applied sciences involving dynamical systems, where the problem in study can be easily arranged as a fixed point problem. Then, we …

Discrete mathematicsDynamical systems theoryIterative methodGeneral Mathematics010102 general mathematicsGeneral EngineeringHilbert spacePerturbation (astronomy)Krasnoselskij type fixed point iterative schemeFixed point01 natural sciences010101 applied mathematicssymbols.namesakeSettore MAT/08 - Analisi Numericaalpha-psi-pseudocontractive operatorFixed point problemSettore MAT/05 - Analisi Matematicaalpha-admissible mappingsymbolsApplied mathematicsIterative approximation0101 mathematicsApplied scienceMathematics
researchProduct

Subgroups of $$SF(\omega )$$ S F ( ω ) and the relation of almost containedness

2016

The relations of almost containedness and orthogonality in the lattice of groups of finitary permutations are studied in the paper. We define six cardinal numbers naturally corresponding to these relations by the standard scheme of $$P(\omega )$$P(ź). We obtain some consistency results concerning these numbers and some versions of the Ramsey theorem.

Discrete mathematicsLogic010102 general mathematics0102 computer and information sciencesLattice (discrete subgroup)01 natural sciencesOmegaCombinatoricsMathematics::LogicPhilosophyOrthogonality010201 computation theory & mathematicsConsistency (statistics)Scheme (mathematics)FinitaryRamsey's theorem0101 mathematicsRelation (history of concept)MathematicsArchive for Mathematical Logic
researchProduct

M-valued Measure of Roughness for Approximation of L-fuzzy Sets and Its Topological Interpretation

2015

We develop a scheme allowing to measure the “quality” of rough approximation of fuzzy sets. This scheme is based on what we call “an approximation quadruple” \((L,M,\varphi ,\psi )\) where L and M are cl-monoids (in particular, \(L=M=[0,1]\)) and \(\psi : L \rightarrow M\) and \(\varphi : M \rightarrow L\) are satisfying certain conditions mappings (in particular, they can be the identity mappings). In the result of realization of this scheme we get measures of upper and lower rough approximation for L-fuzzy subsets of a set equipped with a reflexive transitive M-fuzzy relation R. In case the relation R is also symmetric, these measures coincide and we call their value by the measure of rou…

Discrete mathematicsSet (abstract data type)Identity (mathematics)Transitive relationScheme (mathematics)Fuzzy setTopologyMeasure (mathematics)Realization (systems)Interpretation (model theory)Mathematics
researchProduct

Conditional Random Quantities and Iterated Conditioning in the Setting of Coherence

2013

We consider conditional random quantities (c.r.q.’s) in the setting of coherence. Given a numerical r.q. X and a non impossible event H, based on betting scheme we represent the c.r.q. X|H as the unconditional r.q. XH + μH c , where μ is the prevision assessed for X|H. We develop some elements for an algebra of c.r.q.’s, by giving a condition under which two c.r.q.’s X|H and Y|K coincide. We show that X|HK coincides with a suitable c.r.q. Y|K and we apply this representation to Bayesian updating of probabilities, by also deepening some aspects of Bayes’ formula. Then, we introduce a notion of iterated c.r.q. (X|H)|K, by analyzing its relationship with X|HK. Our notion of iterated conditiona…

Discrete mathematicsSettore MAT/06 - Probabilita' E Statistica MatematicaSettore INF/01 - Informaticaconditional random quantitiesCoherence (statistics)Bayesian inferencebayesian updatingcoherenceCombinatoricsconditional previsionsBayes' theoremIterated functionbayesian updating; conditional random quantities; betting scheme; conditional previsions; coherence; iterated conditioning; iterated conditioning.Coherence betting scheme conditional random quantities conditional previsions Bayesian updating iterated conditioning.Scheme (mathematics)iterated conditioningConditioningRepresentation (mathematics)betting schemeEvent (probability theory)Mathematics
researchProduct

High Order in Space and Time Schemes Through an Approximate Lax-Wendroff Procedure

2017

This paper deals with the scheme proposed by the authors in Zorio, Baeza and Mulet (J Sci Comput 71(1):246–273, 2017). This scheme is an alternative to the techniques proposed in Qiu and Shu (SIAM J Sci Comput 24(6):2185–2198, 2003) to obtain high-order accurate schemes using Weighted Essentially Non Oscillatory finite differences and approximating the flux derivatives required by the Cauchy-Kovalevskaya procedure by simple centered finite differences. We analyse how errors in first-order terms near discontinuities propagate through both versions of the Cauchy-Kovalevskaya procedure. We propose a fluctuation control, for which the approximation of the first-order derivative to be used in th…

Discrete mathematicsSpacetimeLax–Wendroff methodSimple (abstract algebra)Scheme (mathematics)Finite differenceApplied mathematicsFluxClassification of discontinuitiesInterpolationMathematics
researchProduct