Search results for "Section"
showing 10 items of 7305 documents
Organisational and individual resources as antecedents of older nursing professionals’ organisational commitment : Investigating the mediating effect…
2021
Aim and objectives To investigate how organisational and individual resources are linked to older (50+) nursing professionals’ organisational commitment, and to examine the possible mediating role of the active use of selection, optimisation and compensation (SOC) strategies. Background Many healthcare organisations need to find ways to retain their older nursing professionals due to nursing shortage. Design To test a set of hypotheses, cross-sectional survey data (n = 396) were used. Data were analysed using correlation analysis and partial least-squares structural equation modelling. STROBE Statement for cross-sectional studies has been followed in this study. Results The results exhibite…
Variables Determining Higher Home Care Effectiveness in Patients with Chronic Cardiovascular Disease
2022
The aim of this cross-sectional study was to analyze the variables that influence the effectiveness of home care in patients with chronic cardiovascular disease and their informal caregivers. The study was conducted in 193 patients and their 161 informal caregivers. The study used the WHOQOL-BREF Quality of Life Questionnaire, the health behavior inventory questionnaire (HBI), the Camberwell assessment of need short appraisal schedule (CANSAS) and the hospital anxiety and depression scale–modified (HADS–M) version. Spearman’s rank correlation coefficient test and logistic regression were used for analyses. Analysis of patients revealed an association between home care effe…
Results of Angioplasty With Double-Layer Mesh Stent and Protection Systems of the Extra- and Intracranial Dissection of Cephalic Arteries
2023
Purpose: Although a majority of cervical artery dissections can be managed conservatively, patients presenting with cerebral embolization or significant stenosis require a more aggressive approach. However, complications associated with endovascular repair are quite frequent and optimal interventional technique still remains to be established. Materials and methods: The aim of this post hoc survey was to analyze results of endovascular treatments for symptomatic dissections of the internal carotid and vertebral arteries, which were performed under protection and with the use of double-layer mesh stents. During endovascular procedure catheters, stents and protection systems were tailored acc…
$MC$-hypercentral groups
2007
This paper is devoted to the imposition of some chain conditions on groups having a generalized central series. It is also given a characterization of MC-groups with finite abelian section rank: such class of groups is a suitable enlargement of the class of FC-groups. Mathematics Subject Classification: 20F24; 20F14
Mechanism of excited state deactivation of indan-1-ylidene and fluoren-9-ylidene malononitriles.
2016
Herein, we report complementary computational and experimental evidence supporting the existence, for indan-1-ylidene malononitrile and fluoren-9-ylidene malononitrile, of a non-radiative decay channel involving double bond isomerisation motion. The results of UV-Vis transient absorption spectroscopy highlight that the decay takes place within hundreds of picoseconds. In order to understand the related molecular mechanism, photochemical reaction paths were computed by employing multiconfigurational quantum chemistry. The results indicate that the excited state deactivation occurs via concerted double bond twisting of the dicyanovinyl (DCV) unit coupled with a pyramidalisation of its substit…
Polymer Processing and Performance: 2018–2019
2020
The section “Polymer Processing and Performance” of Polymers has published, in the last two years, 175 high quality papers investigating the processing and properties of several polymer based systems [...]
Fractional viscoelastic characterization of laminated glass beams under time-varying loading
2021
Abstract Laminated glass is a composite made of elastic glass layers sandwiching thin viscoelastic polymeric interlayers. There are several types of polymers, traditionally modelled as linear viscoelastic materials using a Prony’s series of units in the Maxwell-Wiechert arrangement. We show that one single element with fractional viscoelastic properties (two constitutive parameters that depend on environmental temperature), is sufficient to provide an accurate description of the polymer response under arbitrary time-varying actions. This is a great advantage over the classical viscoelastic characterization, which requires at least 10–15 terms in the Prony’s series, each one characterized by…
Electrospray ion mobility mass spectrometry of positively charged sodium bis[2-ethythexyl)sulfosuccinate aggregates.
2014
Collision cross-sections (CCS) of positively singly and multiply charged aggregates of the surfactant sodium bis(2-ethylhexyl)sulfosuccinate (AOTNa) in the gas phase have been measured by quadrupole ion mobility time-of-flight mass spectrometry. Calibration of the observed drift times to the CCS of the AOTNa non-covalent aggregates was achieved by collecting, under the same experimental conditions, the drift times of a range of singly and multiply charged polyalanine peptides whose CCS had been obtained by conventional ion mobility spectrometry. Together with an obvious increase of the aggregate cross-section with the aggregation number, it was found that the aggregate cross-section increa…
Quantum Chemistry of Excited States in Polyhedral Boranes
2015
In this Chapter we describe the electronic structure of ground states and excited states of the two isomers of octadecaborane (22), anti- and syn-B18H22, and the new derivative of anti-B18H22, the polyhedral substituted borane 4,4′-(HS)2-anti-B18H20. A theoretical interpretation is given on the fluorescence of the anti-B18H22 isomer, and the non-radiative decay of the syn-B18H22 isomer, an unsolved problem since 1962. For the new derivative of anti-B18H22, substitution of hydrogen atoms in positions 4 and 4′ by SH groups allows the tuning of the photophysical properties in 4,4′-(HS)2-anti-B18H20, facilitating intersystem crossing from the excited singlet state to the triplet state.
Theoretical CASPT2 study of the excited state double proton transfer reaction in the 7-azaindole dimer
2006
Accurate CASPT2 calculations on the excited state double proton transfer reaction in the 7-azaindole dimer have been performed on different symmetric and asymmetric pathways along the protons interchange. The presence of a conical intersection connecting the initially photoinduced singlet excited state with a charge transfer state leading both to asymmetric ionic and neutral structures promotes a step-wise mechanism, probably taking place through the ionic intermediate. The concerted path is computed slightly higher in energy in the gas phase.