Search results for "Selenide"

showing 10 items of 100 documents

CCDC 637412: Experimental Crystal Structure Determination

2007

Related Article: M.Seredyuk, M.Haukka, I.O.Fritsky, H.Kozlowski, R.Kramer, V.A.Pavlenko, P.Gutlich|2007|Dalton Trans.||3183|doi:10.1039/b702574b

Space GroupCrystallographyCrystal Systemcatena-((mu~2~-trans-bis(35-dimethyl-1H-pyrazol-4-yl)selenide)-bis(mu~2~-thiocyanato)-bis(thiocyanato)-di-mercury(ii))Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 637413: Experimental Crystal Structure Determination

2007

Related Article: M.Seredyuk, M.Haukka, I.O.Fritsky, H.Kozlowski, R.Kramer, V.A.Pavlenko, P.Gutlich|2007|Dalton Trans.||3183|doi:10.1039/b702574b

Space GroupCrystallographyCrystal Systemcatena-(bis(mu~2~-cis-bis(35-Dimethyl-1H-pyrazol-4-yl)selenide)-(mu~2~-trans-bis(35-dimethyl-1H-pyrazol-4-yl)selenide)-tetrachloro-di-copper(ii) dimethylsulfoxide solvate dihydrate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 299921: Experimental Crystal Structure Determination

2011

Related Article: M.Seredyuk, I.O.Fritsky, R.Kramer, H.Kozlowski, M.Haukka, P.Gutlich|2010|Tetrahedron|66|8772|doi:10.1016/j.tet.2010.08.071

Space GroupCrystallographybis(3-(2-pyridinio)-5-methyl-1H-pyrazol-4-yl) selenide dinitrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 637414: Experimental Crystal Structure Determination

2007

Related Article: M.Seredyuk, M.Haukka, I.O.Fritsky, H.Kozlowski, R.Kramer, V.A.Pavlenko, P.Gutlich|2007|Dalton Trans.||3183|doi:10.1039/b702574b

Space GroupCrystallographycatena-(bis(mu2-cis-bis(35-Dimethyl-1H-pyrazol-4-yl)selenide)-aqua-copper(ii) dibromide monohydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 637416: Experimental Crystal Structure Determination

2007

Related Article: M.Seredyuk, M.Haukka, I.O.Fritsky, H.Kozlowski, R.Kramer, V.A.Pavlenko, P.Gutlich|2007|Dalton Trans.||3183|doi:10.1039/b702574b

Space GroupCrystallographycatena-(bis(mu~2~-cis-bis(35-Dimethyl-1H-pyrazol-4-yl)selenide)-bis(mu~2~-thiocyanato)-cadmium(ii))Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 637417: Experimental Crystal Structure Determination

2007

Related Article: M.Seredyuk, M.Haukka, I.O.Fritsky, H.Kozlowski, R.Kramer, V.A.Pavlenko, P.Gutlich|2007|Dalton Trans.||3183|doi:10.1039/b702574b

Space GroupCrystallographycatena-(bis(mu~2~-cis-bis(35-Dimethyl-1H-pyrazolyl)selenide)-tetrakis(mu~2~-cyano)-dicyano-tri-cadmium(ii) methanol solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 637415: Experimental Crystal Structure Determination

2007

Related Article: M.Seredyuk, M.Haukka, I.O.Fritsky, H.Kozlowski, R.Kramer, V.A.Pavlenko, P.Gutlich|2007|Dalton Trans.||3183|doi:10.1039/b702574b

Space GroupCrystallographycatena-(bis(mu~2~-trans-bis(35-Dimethyl-1H-pyrazol-4-yl)selenide)-zinc(ii) dinitrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Chalcogenide-capped triiron clusters [Fe3(CO)9(μ3-E)2], [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] and [Fe3(CO)7(μ3-E)2(μ-dppm)] (E = S, Se) as proton-reduction…

2019

Chalcogenide-capped triiron clusters [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] and [Fe3(CO)7(μ3-E)2(μ-dppm)] (E = S, Se) have been examined as proton-reduction catalysts. Protonation studies show that [Fe3(CO)9(μ3-E)2] are unaffected by strong acids. Mono-capped [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] react with HBF4.Et2O but changes in IR spectra are attributed to BF3 binding to the face-capping carbonyl, while bicapped [Fe3(CO)7(μ3-E)2(μ-dppm)] are protonated but in a process that is not catalytically important. DFT calculations are presented to support these protonation studies. Cyclic voltammetry shows that [Fe3(CO)9(μ3-Se)2] exhibits two reduction waves, and upon addition of strong acids, proton-reducti…

SulfideInfrared spectroscopyProtonationorganometalliyhdisteetSulfonic acid010402 general chemistryElectrochemistry01 natural sciencesBiochemistryMedicinal chemistryCatalysisInorganic Chemistrychalcogenidechemistry.chemical_compoundSelenideElectrochemistryMaterials ChemistryPhysical and Theoretical Chemistryclusterta116proton-reductionchemistry.chemical_classification010405 organic chemistryChalcogenideOrganic Chemistrytriironsähkökemia0104 chemical scienceselectrochemistrychemistryClusterTriironProton-reductionCyclic voltammetryJournal of Organometallic Chemistry
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Fabrication of CZTSe/CIGS Nanowire Arrays by One-Step Electrodeposition for Solar-Cell Application

2021

The paper reports some preliminary results concerning the manufacturing process of CuZnSnSe (CZTSe) and CuInGaSe (CIGS) nanowire arrays obtained by one-step electrodeposition for p-n junction fabrication. CZTSe nanowires were obtained through electrodeposition in a polycarbonate membrane by applying a rectangular pulsed current, while their morphology was optimized by appropriately setting the potential and the electrolyte composition. The electrochemical parameters, including pH and composition of the solution, were optimized to obtain a mechanically stable array of nanowires. The samples were characterized by scanning electron microscopy, Raman spectroscopy, and energy-dispersion spectros…

Technologynanowires solar cellsFabricationMaterials scienceScanning electron microscope020209 energytemplate electrodepositionNanowireCZTSe solar cell02 engineering and technologyArticlelaw.inventionsymbols.namesakelawSettore ING-IND/17 - Impianti Industriali MeccaniciSolar cellnanostructures0202 electrical engineering electronic engineering information engineeringGeneral Materials ScienceThin filmMicroscopyQC120-168.85business.industryTCZTSe solar cell nanostructures nanowires solar cells template electrodepositionQH201-278.5Engineering (General). Civil engineering (General)021001 nanoscience & nanotechnologyCopper indium gallium selenide solar cellsTK1-9971Settore ING-IND/23 - Chimica Fisica ApplicataDescriptive and experimental mechanicssymbolsOptoelectronicsElectrical engineering. Electronics. Nuclear engineeringTA1-20400210 nano-technologybusinessRaman spectroscopyChemical bath depositionMaterials
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Indium-Gallium Segregation inCuInxGa1−xSe2: AnAb Initio–Based Monte Carlo Study

2010

Thin-film solar cells with ${\mathrm{CuIn}}_{x}{\mathrm{Ga}}_{1\ensuremath{-}x}{\mathrm{Se}}_{2}$ (CIGS) absorber are still far below their efficiency limit, although lab cells already reach 20.1%. One important aspect is the homogeneity of the alloy. Large-scale simulations combining Monte Carlo and density functional calculations show that two phases coexist in thermal equilibrium below room temperature. Only at higher temperatures, CIGS becomes more and more a homogeneous alloy. A larger degree of inhomogeneity for Ga-rich CIGS persists over a wide temperature range, which contributes to the observed low efficiency of Ga-rich CIGS solar cells.

Thermal equilibriumMaterials scienceCondensed matter physicsMonte Carlo methodAlloyAb initioGeneral Physics and Astronomychemistry.chemical_elementThermodynamicsAstrophysics::Cosmology and Extragalactic Astrophysicsengineering.materialAtmospheric temperature rangeCopper indium gallium selenide solar cellschemistryengineeringGalliumIndiumPhysical Review Letters
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