Search results for "Self assemble"

showing 10 items of 43 documents

Recent developments in dipyrrin based metal complexes: Self-assembled nanoarchitectures and materials applications

2020

While dipyrrin-boron complexes (BODIPYs) and their derivatives have attracted much attention, dipyrrin-based metal complexes recently appeared as a novel luminescent material. So far, dipyrrin-metal complexes have been regarded as non-luminescent or weakly luminescent. Interestingly, introduction of steric hindrance at the meso-position and the development of heteroleptic complexes with proper frontier orbital ordering are two recent strategies that have been developed to improve their luminescent ability. Compared with BODIPYs, one of the distinctive advantages of dipyrrin-metal complexes is that they can form a series of self-assembled supramolecules and polymer assemblies via facile coo…

MetalChemistryvisual_artLuminescent materialvisual_art.visual_art_mediumNanotechnologyGeneral ChemistrySelf assembledJournal of Porphyrins and Phthalocyanines
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Surface plasmons and vibrations of self-assembled silver nanocolumns

2006

6 pags. ; 5 figs. 1 tab.

Models MolecularLightSurface Properties[ PHYS.COND.CM-MS ] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Physics::OpticsBioengineering02 engineering and technologyVibration01 natural sciencesMolecular physicsSelf assembledsymbols.namesakeOpticsMaterials Testing0103 physical sciencesPhysics::Atomic and Molecular ClustersComputer SimulationGeneral Materials ScienceParticle SizeSurface plasmon resonance010306 general physicsCouplingNanotubesChemistrybusiness.industryMechanical EngineeringSurface plasmonGeneral ChemistrySurface Plasmon Resonance021001 nanoscience & nanotechnologyCondensed Matter PhysicsVibrationTransverse planeModels ChemicalMolecular vibrationsymbolsCrystallization0210 nano-technologybusinessRaman scattering
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A self-assembled M8L6 cubic cage that selectively encapsulates large aromatic guests.

2011

Porphyrins cubed: A series of self-assembled M8L6 cubic cages that enclose a volume in excess of 1300 A3 were synthesized (see scheme). The porphyrinic walls of the cubes provide favorable sites for pnp interactions, leading to selectivity between large and chemically similar aromatic guests: three molecules of coronene are incorporated and the higher fullerenes C70nC84 are selectively bound in the presence of

Models MolecularMagnetic Resonance SpectroscopyMolecular StructureCapsulesGeneral ChemistryCrystallography X-RayHydrocarbons AromaticCatalysisCoroneneHigher fullerenesSelf assembledchemistry.chemical_compoundchemistryNickelPolymer chemistryPhysics::Atomic and Molecular ClustersMoleculePolycyclic CompoundsFullerenesCageSelectivityAngewandte Chemie (International ed. in English)
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Dynamical Properties of Self-Assembled Surfactant-Based Mixtures: Triggering of One-Dimensional Anomalous Diffusion in Bis(2-ethylhexyl)phosphoric Ac…

2013

The dynamic features of bis(2-ethylhexyl)phosphoric acid (HDEHP)/n-octylamine (NOA) mixtures have been investigated as a function of the NOA mole fraction and temperature by (1)H NMR spectroscopy and rheometry. All data consistently suggest a composition-induced glass-forming behavior. The microscopic factors responsible for this behavior have been highlighted and have been explained in terms of driving forces given by HDEHP-to-NOA proton transfer, the tendency of the resulting species to establish H bonds and to spatially segregate the alkyl chains. The study sheds light on the molecular mechanism responsible for the peculiar behavior of transport properties in such systems and furnishes b…

Models Molecularsurfactant mixtures self-assembly dynamical propertiesProtonAnomalous diffusionMole fractionSelf assembledDiffusionSurface-Active Agentschemistry.chemical_compoundPulmonary surfactantElectrochemistryOrganic chemistryGeneral Materials ScienceAminesPhosphoric acidSpectroscopyAlkylSettore CHIM/02 - Chimica Fisicachemistry.chemical_classificationMolecular StructureRheometryChemistrySurfaces and InterfacesCondensed Matter PhysicsOrganophosphatesThermodynamicsPhysical chemistryRheologyLangmuir
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Nanocomposites by Electrostatic Interactions:  1. Impact of Sublayer Quality on the Organization of Functionalized Nanoparticles on Charged Self-Asse…

2000

Bis-benzamidines were studied as linkers for the formation of gold nanoparticle assemblies on planar gold surfaces modified with ω-mercaptohexadecanoic acid. In situ ellipsometry, external reflecti...

NanocompositeMaterials scienceNanoparticleNanotechnologySurfaces and InterfacesCondensed Matter PhysicsElectrostaticsSelf assembledQuality (physics)Functionalized nanoparticlesEllipsometryElectrochemistryGeneral Materials ScienceSpectroscopyLangmuir
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Size filtering effect in vertical stacks of In(Ga)As/GaAs self-assembled quantum rings

2006

3 páginas, 3 figuras.

NanostructurePhotoluminescenceMaterials sciencebusiness.industryBioengineeringRing (chemistry)SignalSelf assembledBiomaterialsLaser linewidthMechanics of MaterialsQuantum ringsVertical stackOptoelectronicsbusinessQuantumPhotoluminescenceMolecular beam epitaxy
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Self — Assembled System: Semiconductor and Virus Like Particles

2008

Virus like nanoparticles (VLP) are in use to be absorbed by cells to cause biological effects. To increase a local concentration of VLP, nanoparticles-carriers bringing the latter to the target cell could be employed. N-type and p-type Si semiconductor nanoparticles, to control adhesion of VLP were applied. Optical absorbance spectra and electron microscopy evidenced that VLP became connected to Si nanoparticles. Moreover, a density of the adhered VLP depended on the type of both semiconductor and VLP.

Optical absorbanceMaterials sciencebusiness.industryvirusesvirus diseasesNanoparticleAdhesioncomplex mixturesVirusSelf assembledlaw.inventionSemiconductorChemical engineeringlawElectron microscopebusinessSemiconductor Nanoparticles
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Self-Assembled System of Semiconductor and Virus Like Nanoparticles

2009

Virus like nanoparticles (VLP) are in use to be absorbed by cells to cause biological effects. To increase a local concentration of VLP, nanoparticles-carriers bringing the latter to the target cell could be employed. N-type and p-type Si semiconductor nanoparticles, to control adhesion of VLP were applied. Optical absorbance spectra and electron microscopy evidenced that VLP became connected to Si nanoparticles. Moreover, a density of the adhered VLP depended on the type of both semiconductor and VLP.

Optical absorbanceMaterials sciencebusiness.industryvirusesvirus diseasesNanoparticleNanotechnologyAdhesioncomplex mixturesViruslaw.inventionSelf assembledSemiconductorChemical engineeringlawElectron microscopebusinessSemiconductor Nanoparticles
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Exciton recombination in self-assembled InAs/GaAs small quantum dots under an external electric field

2002

5 páginas, 3 figuras.-- PACS: 73.63.Kv; 78.55.Cr; 78.67.Hc; S7.12.-- Trabajo presentado en la 7th International Conference on Optics and Excitons in Confined Systems (OECS7).

PhotoluminescenceCondensed matter physicsQuantum dotChemistryElectric fieldExcited stateExcitonAtomic physicsCondensed Matter PhysicsRecombinationBiexcitonElectronic Optical and Magnetic MaterialsSelf assembled
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Vertical stacks of small InAs/GaAs self-assembled dots: resonant and non-resonant excitation

2003

4 páginas, 2 figuras.-- PACS: 78.67.Hc; 73.21.La; 78.55.Cr.-- Proceedings of the International Conference on Superlattices, Nano-structures and Nano-devices ICSNN 2002.

PhotoluminescenceMaterials sciencebusiness.industryQuantum dotsCondensed Matter::Mesoscopic Systems and Quantum Hall EffectCondensed Matter PhysicsLine widthAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsSelf assembledBlueshiftCondensed Matter::Materials ScienceEmission bandQuantum dotOptoelectronicsVertical stacksbusinessLayer (electronics)PhotoluminescenceExcitation
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