Search results for "Self-absorption"
showing 3 items of 3 documents
Qualitative-portable to quantitative-laboratory LIBS
2012
No abstract
Determination of mass attenuation coefficient by numerical absorption calibration with Monte-Carlo simulations at 59.54 keV
2016
Abstract This study presents a numerical method in order to determine the mass attenuation coefficient of a sample with an unknown chemical composition at low energy. It is compared with two experimental methods: a graphic method and a transmission method. The method proposes to realise a numerical absorption calibration curve to process experimental results. Demineralised water with known mass attenuation coefficient ( 0.2066 cm 2 g − 1 at 59.54 keV) is chosen to confirm the method. 0.1964 ± 0.0350 cm 2 g − 1 is the average value determined by the numerical method, that is to say less than 5% relative deviation compared to more than 47% for the experimental methods.
Self-absorption in a light-emitting electrochemical cell based on an ionic transition metal complex
2015
We report on the quantitative and qualitative effects of self-absorption in light-emitting electrochemical cells (LECs) based on ionic transition metal complexes (iTMCs), as measured in-situ during electric driving. A yellow-emitting iTMC-LEC comprising an active material thickness of 95 nm suffers a 4% loss of the emission intensity to self-absorption, whereas the same type of device but with a larger active-material thickness of 1 mu m will lose a significant 40% of the light intensity. We also find that the LEC-specific effect of doping-induced self-absorption can result in a drift of the emission spectrum with time for iTMC-LECs, but note that the overall magnitude of doping-induced sel…