Search results for "Separation"

Effect of the anode composition on the performance of reversible chlor-alkali electro-absorption cells

2020

Abstract In this work, the performances of a reversible electrochemical cell for the storage of energy using the chloralkaline process was investigated. The cell operates at room temperature with liquid electrolytes in both compartments. In the electrolyzer mode, the cell transforms a sodium chloride solution into hydrogen and chlorine, which is then disproportionated to form hypochlorous acid and hypochlorite. In fuel cell operation mode, the cell becomes an electro-absorber to oxidize hydrogen at the anode while reducing hypochlorous acid at the cathode. Because of the low solubility of hydrogen, a special mechanical device is used to produce hydrogen microbubbles in the anodic compartmen…

Tunability by alkali metal cations of photoinduced charge separation in azacrown functionalized graphene.

2013

A modified graphene oxide containing aza-9-crown-3 ether units covalently anchored has been prepared; aqueous suspensions of this material in the presence of Li(+), Na(+) and K(+) cations exhibit enhanced electrochemical response, enhanced photoinduced charge separation and longer lifetimes, facts that can be attributed to stabilization of electrons on graphene oxide by the nearby alkali metal cation-azacrown complexes.

Investigation of gaseous discharge ion sources for isotope separation on-line

1976

Abstract Gaseous discharge ion sources with circular end extraction have been investigated with the aim of meeting the special requirements of on-line isotope separation. The studies represent an attempt to increase lifetime, temperature and ionization efficiency of the ion source under stable discharge conditions and to reduce the ion current density of usually 1–100 mA/cm2 of low intensity separator sources. The detailed investigation of a modified Nielsen Ion Source is described. The source yields in oscillating electron are operation reproducible ionization efficiencies of 32% for krypton and 45% for xenon. It was found that minor variations of geometry and potentials in a Nielsen-type …

Double-stranded RNA polyinosinic-polycytidylic acid immobilized onto gamma-Fe2O3 nanoparticles by using a multifunctional polymeric linker.

2007

Nondestructive in-line sub-picomolar detection of magnetic nanoparticles in flowing complex fluids

2018

AbstractOver the last decades, the use of magnetic nanoparticles in research and commercial applications has increased dramatically. However, direct detection of trace quantities remains a challenge in terms of equipment cost, operating conditions and data acquisition times, especially in flowing conditions within complex media. Here we present the in-line, non-destructive detection of magnetic nanoparticles using high performance atomic magnetometers at ambient conditions in flowing media. We achieve sub-picomolar sensitivities measuring ~30 nm ferromagnetic iron and cobalt nanoparticles that are suitable for biomedical and industrial applications, under flowing conditions in water and who…

Engineered Membranes for Residual Cell Trapping on Microfluidic Blood Plasma Separation Systems: A Comparison between Porous and Nanofibrous Membranes

2021

Blood-based clinical diagnostics require challenging limit-of-detection for low abundance, circulating molecules in plasma. Micro-scale blood plasma separation (BPS) has achieved remarkable results in terms of plasma yield or purity, but rarely achieving both at the same time. Here, we proposed the first use of electrospun polylactic-acid (PLA) membranes as filters to remove residual cell population from continuous hydrodynamic-BPS devices. The membranes hydrophilicity was improved by adopting a wet chemistry approach via surface aminolysis as demonstrated through Fourier Transform Infrared Spectroscopy and Water Contact Angle analysis. The usability of PLA-membranes was assessed through de…

Morphology and thermal properties of foams prepared via thermally induced phase separation based on polylactic acid blends

2012

Blends of poly-l-lactic acid with two different types of polylactic acid with different average molecular weights (50,000 and 175,000 g/mol, respectively) in different proportions (90/10, 80/20 and 70/30) were utilized in order to produce biodegradable and biocompatible scaffolds for soft tissue engineering applications. The scaffolds were produced via thermally induced phase separation starting from ternary systems where dioxane was the solvent and water the non-solvent. Morphology (average pore size and interconnection) was evaluated by scanning electron microscopy. Foams apparent density was also evaluated (porosity ranges from 87% to 92%). Moreover, a differential scanning calorimetry …

Novel Au NPs/Preyssler acid/TiO 2 nanocomposite for the photocatalytic removal of azo dye

2014

Abstract In this study, we introduced a novel nanocomposite consisting of Au nanoparticles decorated TiO 2 and Preyssler acid as a multifunctional photocatalyst linker molecule, in which gold ions reduced locally on the TiO 2 surface. The obtained nanocomposite has been characterized using Fourier Transform Infrared (FTIR), X-ray Diffraction (XRD), Electron Dispersive X-ray (EDX) Spectroscopy, Transmission Electron Microscopy (TEM) and Scanning Electron Microscope (SEM). Also, their photocatalytic activity has been studied for the degradation of model organic azo dye Malachite Green under UV light irradiation.

Suppression of stimulated Raman scattering in optical fibres by power-controlled multifrequency pumping

1999

International audience; We present a method for suppressing the stimulated Raman scattering process induced by a multifrequency pump field propagating in a normally dispersive single-mode fibre. The suppression process is completely achieved by suitably choosing the frequency separation between the pumps, as well as the power distribution among the frequency components of the pump field. The experimental spectra show the effectiveness of this suppression process for a dual-frequency pumping configuration.

Determination of90Sr in environmental samples with resonance ionization spectroscopy in collinear geometry

1994

A new, fast technique for trace analysis of the radioactive isotopes89Sr and90Sr in environmental samples has been developed. Conventional mass separation is combined with resonance ionization spectroscopy in collinear geometry, which provides high selectivity and sensitivity. In addition, a chemical separation procedure for sample preparation has been developed. The described technique was used to determine the90Sr content in ≈ 870 m3 air samples collected near Munich during and shortly after the Chernobyl reactor accident in April 1986. The content of90Sr was measured to be 1.4 mBq per m3, corresponding to 1.6 × 109 atoms of90Sr per sample. This value is in good agreement with the results…