Search results for "Shale"
showing 10 items of 45 documents
Zirconium–hafnium and rare earth element signatures discriminating the effect of atmospheric fallout from hydrothermal input in volcanic lake water
2016
The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidicwaters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr a nd Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y-Ho and Zr-Hf (twin pairs) have a…
Geochemical and Petrographic Characterization of Marine-Continental Transitional Facies Shale (Qilian Basin, China): Origin of Organic Matter Input, …
2021
This study, for the first time, investigates the source, keroger pattern, evolution degree, sedimentary environment, and evaluates the hydrocarbon generating ability of marine-continental transitional facies shale from the Ebao area of the Qilian Basin in western China. The organic-rich shales of the marine-continental transitional facies were subjected to total organic carbon (TOC), rock pyrolysis, the biomarkers and kerogen microscopy analyses. The kerogen microscopy analyses indicated that the sample from ZK001 well and ZK2002 well had a mass of vitrinite and small number of exinite, so kerogen type was mainly humic. According to vitrinite reflectance, the organic matter was in the stage…
Effect of the mineralogical composition on the elastoplastic hydromechanical response of Opalinus Clay shale
2021
Abstract Opalinus Clay is the shale currently under investigation as the host formation for geological radioactive waste disposal in Switzerland. Its hydromechanical response has been widely studied, and the experimental results show a range of values whose dispersion needs to be clarified. This work aims to explain the dispersion in the literature results by correlating the hydro-mechanical response to the mineralogical variability of the tested specimens . Based on published microstructural studies, the Opalinus Clay shale is herein schematised as a sequence of two kinds of layers: the shaly (high in clay-mineral content) and the sandy (low in clay-mineral content) layers. The mineralogic…
1D Compression Behaviour of Opalinus Clay
2017
One of the main concerns related to tunnel excavations, drilling operations and wellbore stability in shales is the generation of excess pore water pressure due to changes in mechanical stress; therefore the consolidation of shales is a fundamental process that must be considered. This paper presents a compre- hensive methodology for analysing the compression and consolidation behaviour of shales. An apparatus to perform high-pressure oedometric tests is presented and an analytical method is introduced to analyse the shale consolidation behaviour, which allows information to be gathered on the coeffi cient of consolidation, stiffness, poroelastic properties, and permeability of the tested m…
Il ruolo della facies sulla resistenza a taglio di argille estremamente consistenti
2022
L’Opalinus Clay Shale è la formazione che ospiterà il deposito profondo di scorie radioattive di alta attività in Svizzera. A causa della sua composizione fortemente eterogenea, tale materiale è stato classificato in diverse facies. Inoltre, esso è caratterizzato da una struttura fissile e da un comportamento idro-meccanico anisotropo. Queste particolari complessità rendono particolarmente difficile la scelta di parametri geomeccanici unici per l’intera formazione. In questa memoria viene presentato uno studio sperimentale mirato alla caratterizzazione del limite inferiore dei parametri di resistenza al taglio, attraverso l’esecuzione di prove di compressione trias siale e prove di taglio a…
On the hydro-mechanical behaviour of remoulded and natural Opalinus Clay shale
2016
The geo-energy sector makes use of advanced technologies such as shale gas extraction, CO2 sequestration and nuclear waste geological disposal that rely on the exploitation of shale formations. Due to the great depths involved in these applications and the difficulties in retrieving intact samples, remoulded shale specimens are often adopted for hydro-mechanical testing. Remoulded and intact shales may substantially differ in their hydro-mechanical behaviour due to the particular structure of the natural material, which is the result of diagenesis and burial history. This paper presents an experimental campaign aimed at (i) characterizing the role of diagenesis and depth for Opalinus Clay s…
Sponges (Porifera) as living metazoan witnesses from the Neoproterozoic: biomineralization and the concept of their evolutionary success
2010
Terra Nova, 22, 1–11, 2010 Abstract The emergence of the Metazoa can be dated back to the Neoproterozoic Era which comprises the Cryogenian Period during which two major glaciations occurred, the Sturtian and the Varanger-Marinoan. At that time, the phylum Porifera (sponges) evolved as the first animals and developed a hard skeleton. The two classes of siliceous sponges, the Hexactinellida and the Demospongiae, are already provided with the major genetic repertoire and gene regulatory networks that also exist in modern multicellular animals. Besides these metazoan innovations, the siliceous sponges display one autapomorphic character, silicatein, an enzyme which mediates bio-silica formatio…
Multiphysical Testing of Soils and Shales. Springer, 978-3-642-32491-8, Springer Series in Geomechanics and Geoengineering, 340p.
2012
Advances in Laboratory Testing and Modelling of Soils and Shales (ATMSS).
2017
This volume contains the invited keynote and feature lectures, as well as the papers that have been presented at the workshop. The topics of the lectures and papers cover a wide range of theoretical and experimental research, including unsaturated behaviour of soils and shales, multiphysical testing of geomaterials, hydromechanical behaviour of shales and stiff clays, the geomechanical behaviour of the Opalinus Clay shale, advanced laboratory testing for site characterization and in situ applications, and soil–structure interactions.
Experimental analysis of the water retention behaviour of shales
2014
Shales are among the most commonly considered geomaterials in current energy-related geomechanical investigations, as they are involved in engineering applications such as the unconventional extraction of natural gas, CO2 sequestration and nuclear waste geological storage. A deep understanding of their behaviour with regard to variations in the degree of saturation is of primary significance for such applications. With the aim to establish a sound protocol for shale retention behaviour analysis, this paper presents an advanced experimental methodology that takes into account the specificities of shales such as small pore size dimensions and the large variations in water potential to be appl…