Search results for "Shear"

Rheological Characterization of Low-calorie Milk-based Salad Dressings

1992

Oil-in-water emulsions of different quantitative composition, containing milk powder and locust bean gum. as stabilizing agents, showed similar rheological behavior: time-dependent thixotropic character and yield stress. Thixograms obtained for each sample could be modelled through the Hahn equation for the different shear rates. The analysis of the Hahn parameter variation for each sample as a function of shear rate led to a function σ= f(γ, t). Predicted shear stress values had relative errors lower than 10% in 99.9% of the samples studied. Analysis of composition influence on the rheological parameters showed an interactive role of gum, milk and acetic acid concentrations on emulsion con…

Amorphous Silica at Surfaces and Interfaces: Simulation Studies

2003

The structure of surfaces and interfaces of silica (SiO2) is investigated by large scale molecular dynamics computer simulations. In the case of a free silica surface, the results of a classical molecular dynamics simulation are compared to those of an ab initio method, the Car—Parrinello molecular dynamics. This comparative study allows to check the accuracy of the model potential that underlies the classical simulation. By means of a pure classical MD, the interface between amorphous and crystalline SiO2 is investigated, and as a third example the structure of a silica melt between walls is studied in equilibrium and under shear. We show that in the latter three examples important structu…

Do we understand the solid-like elastic properties of confined liquids?

2021

Recently, in polymeric liquids, unexpected solid-like shear elasticity has been discovered, which gave rise to a controversial discussion about its origin (1⇓–3). The observed solid-like shear modulus G depends strongly on the distance L between the plates of the rheometer according to a power law G ∝ L − p with a nonuniversal exponent ranging between p = 2 and p = 3 . Zaccone and Trachenko (4) have published an article in which they claim to explain these findings by a nonaffine contribution to the liquid shear modulus. The latter is represented as Δ G ∝ − ∑ λ = L , T 1 V … [↵][1]1To whom correspondence may be addressed. Email: giancarlo.ruocco{at}roma1.infn.it. [1]: #xref-corresp-1-1

Heterogeneous shear elasticity of glasses: the origin of the boson peak

2013

The local elasticity of glasses is known to be inhomogeneous on a microscopic scale compared to that of crystalline materials. Their vibrational spectrum strongly deviates from that expected from Debye's elasticity theory: The density of states deviates from Debye's law, the sound velocity shows a negative dispersion in the boson-peak frequency regime and there is a strong increase of the sound attenuation near the boson-peak frequency. By comparing a mean-field theory of shear-elastic heterogeneity with a large-scale simulation of a soft-sphere glass we demonstrate that the observed anomalies in glasses are caused by elastic heterogeneity. By observing that the macroscopic bulk modulus is …

Shear elasticity of mixed cyanide orientational glass

1993

Four mixed crystals of KBr:KCN and NaCN:KCN, complemented by KCN, have been investigated by torque-shear measurements. The real and imaginary parts of the shear compliance ${\mathit{s}}_{44}$ at a measuring frequency of 2 Hz have been determined. Zero-field-cooling--field-cooling--remanent-shear-strain cycles have been performed. For (KBr${)}_{0.47}$(KCN${)}_{0.53}$ the creep after zero-field cooling and the elastic aftereffect after field cooling have been followed within a time window from 0.1 to ${10}^{4}$ s. Results on the nonlinear part of the shear compliance have been obtained. It is shown that the field-cooled strain represents the static limit of the elastic response. The results a…

Confined Crystals on Substrates: Order and Fluctuations in Between One and Two Dimensions

2010

The effect of lateral confinement on a crystal of point particles in d = 2 dimensions in a strip geometry is studied by Monte Carlo simulations and using phe- nomenological theoretical concepts. Physically, such systems confined in long strips of width D can be realized via colloidal particles at the air-water interface, or by adsorbed monolayers at suitably nanopatterned substrates, etc. As a generic model, we choose a repulsive interparticle potential decaying with the twelfth inverse power of distance. This system has been well studied in the bulk as a model for two- dimensional melting. The state of the system is found to depend very sensitively on the boundary conditions providing the …

Effective charges along the melting line of colloidal crystals

2006

The shear modulus G of charged colloidal crystals was measured at several constant particle densities n and varying salt concentrations c up to the melting salt concentration cM using torsional resonance spectroscopy. Far from the phase boundary the samples are polycrystalline and the shear modulus stays roughly constant as a function of c. Upon approaching the melting transition an increasing amount of wall based crystal material is formed surrounding a shrinking polycrystalline core and G drops nearly linearly. When the transition is complete G again stays constant. The morphologic transitions may be scaled upon a single master curve. For the polycrystalline morphology, the elastic data a…

Publisher's Note: "Thermodynamic formalism for transport coefficients with an application to the shear modulus and shear viscosity" [J. Chem. Phys. 1…

2017

Qualitative characterisation of effective interactions of charged spheres on different levels of organisation using Alexander’s renormalised charge a…

2005

Abstract Effective interactions are conveniently determined from experimental or numerical data by fitting a Debye–Huckel potential with an effective charge Z ∗ and an effective electrolyte concentration c ∗ as free parameters. In this contribution we numerically solved the Poisson–Boltzmann equation to obtain the so-called renormalised charge Z PBC ∗ . For sufficiently large bare charge Z one finds a saturation of Z ∗ which scales as Z ∗ = A a / λ B , where a is the particle radius, λ B the Bjerrum length and A a proportionality factor of order (8–10). The saturation value increases with increased total micro-ion concentration and shows a shallow minimum as a function of packing fraction. …

Ordering of two-dimensional crystals confined in strips of finite width.

2007

Monte Carlo simulations are used to study the effect of confinement on a crystal of point particles interacting with an inverse power law potential $\ensuremath{\propto}{r}^{\ensuremath{-}12}$ in $d=2$ dimensions. This system can describe colloidal particles at the air-water interface, a model system for experimental study of two-dimensional melting. It is shown that the state of the system (a strip of width $D$) depends very sensitively on the precise boundary conditions at the two ``walls'' providing the confinement. If one uses a corrugated boundary commensurate with the order of the bulk triangular crystalline structure, both orientational order and positional order is enhanced, and suc…