Search results for "Shear"

Transient birefringence of polymer melts in intermittent shear flow: Model analysis of the non-linear viscoelastic behaviour

1977

A non-linear viscoelastic model has been used to interpret transient flow birefringence in changing shear flow for a polymer melt. It is shown how the new model is consistent with the basic hypothesis of the linear stress-optical law. Stress growth in shear flow and relaxation after different amounts of shearing are compared with the predictions of the non-linear model. A good agreement between experimental data and theoretical predictions is found.

1985

Proposition d'une methode qui utilise l'information contenue dans la relation entre la vitesse de cisaillement et la viscosite. Solutions de polystyrene dans la trans-decaline

Interrelation between the thermodynamic and viscometric behaviour of aqueous solutions of hydrophobically modified ethyl hydroxyethyl cellulose

2000

Abstract Aqueous solutions of a commercial sample of hydrophobically modified ethyl hydroxyethyl cellulose (HC, Mw=100 kg/mol, nonylphenol substitution ca. 1.7 mol%) were studied with respect to their demixing behaviour and flow characteristics. Phase separation temperatures were measured turbidimetrically and by determining the first discernible macroscopic phase separation. In some cases demixing was also monitored viscometrically. Phase volume ratios yielded a critical polymer concentration of 1.87 wt.% HC (displaced considerably out of the minimum of the demixing curve towards higher polymer concentrations) and a lower critical solution temperature of 47°C. Model calculations of the spi…

Shear and nonisothermal elongational characterization of a liquid crystalline polymer

1989

A commercial liquid crystalline polymer (LCP) sample was characterized both in shear and in nonisothermal elongational flow over a wide range of temperatures (240–350°C). The LCP sample employed was a copolyesteramide of 2,6 hydroxynaphthoic acid, terephthalic acid, and aminophenol manufactured by Celanese and commercially known as Vectra B950. The viscosity decreases dramatically at temperatures above the crystal-nematic transition of the polymer. At lower temperatures, the extrusion of the sample is mainly due to plastic flow. Die-swell values are very small and contraction of the extrudate is also revealed, but the sample shows high elasticity. The polymer is not spinnable at very low te…

Shear flow characterization of blends containing liquid crystal polymers

1992

A simple phenomenological approach is proposed in order to predict the presence of minima in the viscosity-composition curves of blends of thermoplastic with liquid crystal polymer (LCP). When the viscosity of the liquid crystal polymer is larger than that of the thermoplastic matrix, a minimum is observed. A possible explanation of the presence of yield stress in the flow curves of these blends is also given.

Influence of xanthan gum and locust bean gum upon flow and thixotropic behaviour of food emulsions containing modified starch

2007

Abstract Low oil content mayonnaises are food emulsions which exhibit shear thinning and thixotropic behaviour. They include generally modified starch in their formulation. In this work we study the effect of substituting part of this starch with other natural gums, such as xanthan gum or locust bean gum, upon the consistency and stability of the emulsions in relation to stirring. The gels prior to final emulsification have also been analyzed. Steady flow curves of all systems are well described by the Carreau model. The emulsions containing the greatest percentage of gums presented significantly higher viscosity than the reference emulsion and the emulsions containing the synergistic mixtu…

The Role of Elongational Flow in Morphology Modification of Polyethylene/OMMt Nanocomposite System

2011

The formulation of high-performance polymer based nanocomposites depend on many factors, such as polymeric matrix type, nanoparticle type, loading and morphology, affinity between the polymeric matrix and nanoparticles, presence of compatibilizer and processing conditions [1-4]. During the industrial processing the polymer based systems are subjected to two different processing flows, i.e. the shear and elongational flow. The shear flow plays a significant role in polyethylene/OMMt manufacture processing but it is not able to change the system morphology, while, the elongational flow, involved in spinning and film-blowing processing operations, can induce considerably clay morphology variat…

CONSIDERAZIONI TEORICHE E PRATICHE SUL METODO DEL MASSIMO RETTANGOLO CIRCOSCRITTO PER LA VALUTAZIONE DELL’AMPIEZZA DELLA TENSIONE TANGENZIALE NEI CRI…

2012

The multiaxial fatigue criteria based on the approach of the critical plane require the determination of the amplitude of the alternating shear stress τ aacting on different planes passing through the point of the material analyzed. In the case of non-proportional stresses the shear stress vector varies both in modulus and direction and its tip describes a curvedefined loading path. In these cases τ ais identified and evaluated by means of special procedures the most recent, and apparently more effective, of which is that of the Maximum Circumscribed Rectangle (MCR) to the loading path itself. In particular τ ais equal to the length of the diagonal of the MCR. In this paper, the MCR method …

Postbuckling analysis of cracked stiffned plates by pb–2 Rayleigh-Ritz method

2015

A Rayleigh-Ritz approach for the analysis of buckling and post-buckling behavior of cracked composite stiffened plates is presented. The structure is thought as the assembly of plate elements modeled by the first order shear deformation theory. Continuity along the edges common to contiguous elements are enforced by using penalty techniques, which also allow to straightforwardly implement efficient crack modeling strategies. General symmetric and unsymmetric stacking sequences are considered and numerical procedures have been developed and used to validate the present solution by comparison with FEA results. Original results are also presented for post-buckling solution of multilayered stif…

SHEAR RESISTANCE OF R/C BEAMS PROVIDED WITH DIFFERENTLY-INCLINED TRANSVERSE REINFORCEMENT

2012

The model for the evaluation of shear resistance of reinforced concrete member provided with transverse web reinforcement, derived by Nielsen (1999) on the basis of the variable inclination stress field approach, is generalized here to predict the shear strength of r.c. beams equipped with two sets of differently-inclined transversal web reinforcement and longitudinal skin reinforcement. Numerical analyses emphasize the efficiency of double inclined web transverse reinforcement in providing shear strength to beams.