Search results for "Silicate"
showing 10 items of 413 documents
Zeta-Potential Study of Calcium Silicate Hydrates Interacting with Alkaline Cations
2001
An investigation into the interaction between alkaline cations and calcium silicate hydrates (CSH) was conducted by electrokinetic measurements, which provided information on the nature of the interface between the solid and its equilibrium solution. Calcium constitutes for the CSH surface a potential-determining cation. A model of the CSH surface could be proposed, accounting for the experimental evolution of the CSH zeta potential. The necessity of studying the zeta-potential evolution of the system as a function of the calcium activity, instead of its concentration, was underlined. The results obtained suggest a specific interaction between cesium and the CSH surface, whereas sodium and …
Electrochemical Fingerprint of Archeological Lead Silicate Glasses Using the Voltammetry of Microparticles Approach
2016
9 págs.; 14 figs.; 1 tab.
Electrical conductivity of magma in the course of crystallization controlled by their residual liquid composition.
2005
International audience; The electrical conductivity of a magma in the course of crystallization was experimentally investigated in the temperature range of 1350–1018°C. Large samples of basaltic composition with a homogeneous crystal content were synthesized in a gas mixing furnace at 1 atm pressure. The samples were analyzed by electron microprobe. The relative proportions of the phases as a function of temperature were determined. Depending on temperature, the phase assemblies included quenched silicate liquid, ±plagioclase, ±pyroxene, ±Fe-Ti oxides. The crystal content varied from 0 to 80 wt %. In response to partial crystallization, the residual liquid changed composition from basalt, t…
Evidence for montmorillonite or its compositional equivalent in Columbia Hills, Mars
2007
During its exploration of the Columbia Hills, the Mars Exploration Rover ‘‘Spirit’’ encountered several similar samples that are distinctly different from Martian meteorites and known Gusev crater soils, rocks, and sediments. Occurring in a variety of contexts and locations, these ‘‘Independence class’’ samples are rough-textured, iron-poor (equivalent FeO 4 wt%), have high Al/Si ratios, and often contain unexpectedly high concentrations of one or more minor or trace elements (including Cr, Ni, Cu, Sr, and Y). Apart from accessory minerals, the major component common to these samples has a compositional profile of major and minor elements whic…
In situ and experimental evidence for acidic weathering of rocks and soils on Mars
2006
Experimental data for alteration of synthetic Martian basalts at pH=0-1 indicate that chemical fractionations at low pH are vastly different from those observed during terrestrial weathering. Rock analyses from Gusev crater are well described by the relationships apparent from low pH experimental alteration data. A model for rock surface alteration is developed which indicates that a leached alteration zone is present on rock surfaces at Gusev. This zone is not chemically fractionated to a large degree from the underlying rock interior, indicating that the rock surface alteration process has occurred at low fluid-to-rock ratio. The geochemistry of natural rock surfaces analyzed by APXS is c…
Composition-resolved size distributions of volcanic aerosols in the Mt. Etna plumes
2008
Particle size distributions for soluble and insoluble species in Mt. Etna's summit plumes were measured across an extended size range (10 nm < d < 100 μm) using a combination of techniques. Automated scanning electron microscopy (QEMSCAN) was used to chemically analyze many thousands of insoluble particles (collected on pumped filters) allowing the relationships between particle size, shape, and composition to be investigated. The size distribution of fine silicate particles (d < 10 μm) was found to be lognormal, consistent with formation by bursting of gas bubbles at the surface of the magma. The compositions of fine silicate particles were found to vary between magmatic and nearl…
Overview of the magnetic properties experiments on the Mars Explorations Rovers
2009
[1] The Mars Exploration Rovers have accumulated airborne dust on different types of permanent magnets. Images of these magnets document the dynamics of dust capture and removal over time. The strongly magnetic subset of airborne dust appears dark brown to black in Panoramic Camera (Pancam) images, while the weakly magnetic one is bright red. Images returned by the Microscopic Imager reveal the formation of magnetic chains diagnostic of magnetite-rich grains with substantial magnetization (>8 Am2 kg−1). On the basis of Mossbauer spectra the dust contains magnetite, olivine, pyroxene, and nanophase oxides in varying proportions, depending on wind regime and landing site. The dust contains a …
MZ-35, a new layered pentasil borosilicate synthesized in the presence of large alkali cations
2013
Abstract A new layered borosilicate has been synthesized in the presence of cesium and sodium cations and its structure has been solved by a combination of automated diffraction tomography (ADT) and X-ray powder diffraction (XRPD). MZ-35 has a composition NaCs 2 [BSi 7 O 16 (OH) 2 ](OH) 2 ·4H 2 O and features space group P-4m2. The unusually small unit cell ( a 7.3081 A, c 10.7520 A) is shared by two random-stacked configurations of the structure: a network of connected pentasil units related to the layer of RUB-18 and a bidimensional checkerboard of intersecting ladders of 4-membered rings. The two configurations are related by the simple face-sharing inversion of a hydroxyl-bearing tetrah…
Bioencapsulation of living bacteria (Escherichia coli) with poly(silicate) after transformation with silicatein-α gene
2007
Bioencapsulation is an intriguing way to immobilize biological materials, including cells, in silica, metal-oxides or hybrid sol-gel polymers. Until now only the sol-gel precursor technology was utilized to immobilize bacteria or yeast cells in silica. With the discovery of silicatein, an enzyme from demosponges that catalyzes the formation of poly(silicate), it became possible to synthesize poly(silicate) under physiological (ambient) conditions. Here we show that Escherichia coli can be transformed with the silicatein gene, its expression level in the presence of isopropyl beta-D-thiogalactopyranoside (IPTG) can be efficiently intensified by co-incubation with silicic acid. This effect co…
Investigation of Li/Ca variations in aragonitic shells of the ocean quahogArctica islandica, northeast Iceland
2009
Interannual and intra-annual variations in lithium-to-calcium ratio were investigated with high temporal resolution in the aragonitic outer shell layer of juvenile Arctica islandica (Mollusca; Bivalvia) collected alive in 2006 off northeast Iceland. Li/Ca shell ranged between 7.00 and 11.12 µmol mol -1 and presented well-marked seasonal cycles with minimum values recorded at the annual growth lines; a general pattern was a progressive increase in Li/Ca shell from March to May, followed by a plateau in June and a decrease down to minimum values in July-August. Li/Ca shell was correlated with d 18 O shell -derived temperature, but the strength of this relationship was weak ( r 2 p shell in A.…