Search results for "Single"

showing 10 items of 4920 documents

Confined Pt-1(1+) Water Clusters in a MOF Catalyze the Low-Temperature Water-Gas Shift Reaction with both CO2 Oxygen Atoms Coming from Water

2018

[EN] The synthesis and reactivity of single metal atoms in a low-valence state bound to just water, rather than to organic ligands or surfaces, is a major experimental challenge. Herein, we show a gram-scale wet synthesis of Pt-1(1+) stabilized in a confined space by a crystallographically well-defined first water sphere, and with a second coordination sphere linked to a metal-organic framework (MOF) through electrostatic and H-bonding interactions. The role of the water cluster is not only isolating and stabilizing the Pt atoms, but also regulating the charge of the metal and the adsorption of reactants. This is shown for the low-temperature water-gas shift reaction (WGSR: CO + H2O CO2 + H…

PhysicsWater–gas shift reactionQuímica Inorgánicabiology010405 organic chemistryWater-gas shift reactionSingle atom catalystGeneral MedicineGeneral ChemistryMetal-organic frameworks010402 general chemistrybiology.organism_classification01 natural sciencesCatalysisWater-gas shift reactionSingle-atom catalyst0104 chemical sciencesOxygen atomWater clustersPhysical chemistryValenciaMetal-organic frameworks (MOFs)Platinum
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Validation of a method for measuring the retinal thickness with Shack–Hartmann aberrometry in an artificial eye

2015

In Shack–Hartmann aberrometry, it is assumed that a wave front emerges from a single point focused on a retina. However, the retina is a multi-layered structure and reflections may occur from several layers. This may result in several overlapping spot patterns on the CCD due to different vergences of the outgoing wave fronts. The amount by which these spot patterns are displaced may contain information about the retinal thickness. In this study, we perform simulations of formation of double spots in a living eye and also apply this method to measure the thickness of an artificial retina with a simple structure. We also compare the results obtained with artificial eye and compare them to the…

PhysicsWavefrontRetinabusiness.industryRetinalLensletAtomic and Molecular Physics and Opticschemistry.chemical_compoundOpticsmedicine.anatomical_structurechemistrySimulated dataAberrometrymedicinesense organsSingle pointbusinessJournal of Modern Optics
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Spatial and spectral nonlinear shaping of multimode waves

2016

We demonstrate a novel nonlinear dynamics of multimode fibers that reshapes their spectral and spatial beam profiles, based on spatiotemporal modulation instability. Sidebands ranging from the visible to the near-infrared are carried by one and the same spatial bell-shaped profile.

Physics[PHYS.PHYS.PHYS-OPTICS] Physics [physics]/Physics [physics]/Optics [physics.optics][PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Multi-mode optical fiber[ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]business.industrySingle-mode optical fiberPhysics::OpticsPolarization-maintaining optical fiber01 natural sciencesGraded-index fiber010309 opticsAmplitude modulationNonlinear systemOpticsModulation0103 physical sciencesPhysics::Accelerator Physics010306 general physicsbusinessBeam (structure)ComputingMilieux_MISCELLANEOUS
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High repetition rates and high quality optical pulse train generator based on solitons over finite background

2013

This work proposes to fully exploit the nonlinear evolution undergone by a sinusoidal modulation with a finite background propagating along an optical fiber. For the original method to overcome this major drawback is to exploit the π phase shift that exists between the pulsed part and the background. By using a simple delay-line interferometer, it is possible to simultaneously double the repetition rate of the pulse train and to annihilate the deleterious background by imprinting a controlled π phase shift.

Physics[PHYS.PHYS.PHYS-OPTICS] Physics [physics]/Physics [physics]/Optics [physics.optics][PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Multi-mode optical fiber[ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]business.industrySingle-mode optical fiberPolarization-maintaining optical fiber02 engineering and technology01 natural sciencesOptical parametric amplifierGraded-index fiber010309 optics020210 optoelectronics & photonicsOpticsMode-lockingPulse compression0103 physical sciences0202 electrical engineering electronic engineering information engineeringPulse wavebusinessComputingMilieux_MISCELLANEOUS
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Limits of terrestrial optical fiber systems for ultra-high bit rate RZ data transmissions (from 160 Gbit/s to 1.28 Tbit/s)

2007

This article numerically investigates the fundamental limits of the terrestrial RZ data transmission systems based on SMF/DCF dispersion map for bit rates ranging from 160 Gbit/s to 1.28 Tbit/s. The system includes an erbium doped fiber amplifier and pre-and post-compensation stages. After filtering and detection, the system performance is characterized using the usual Q-factor.

Physics[PHYS.PHYS.PHYS-OPTICS] Physics [physics]/Physics [physics]/Optics [physics.optics][PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Optical fiber[ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]business.industry020208 electrical & electronic engineeringSingle-mode optical fiberchemistry.chemical_elementRanging02 engineering and technologylaw.inventionErbiumOpticschemistrylawGigabitQ factorDispersion (optics)0202 electrical engineering electronic engineering information engineeringTerabitbusinessComputingMilieux_MISCELLANEOUS
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Optical flip-flop memory and data packet switching operation based on polarization bistability in a telecommunication optical fiber

2013

We report the experimental observation of bistability and hysteresis phenomena of the polarization signal in a telecommunication optical fiber. This process occurs in a counterpropagating configuration in which the optical beam nonlinearly interacts with its own Bragg-reflected replica at the fiber output. The proof of principle of optical flip–flop memory and 10  Gbit/s routing operation is also reported based on this polarization bistability. Finally, we also provide a general physical understanding of this behavior on the basis of a geometrical analysis of an effective model of the dynamics. Good quantitative agreement between theory and experiment is obtained.

Physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Multi-mode optical fiber[ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]Bistabilitybusiness.industryOptical cross-connectSingle-mode optical fiberPhysics::OpticsStatistical and Nonlinear PhysicsPolarization-maintaining optical fiberOptical performance monitoring01 natural sciencesOptical switchAtomic and Molecular Physics and Optics010309 opticsOptics0103 physical sciencesFiber optic splitterOptoelectronics010306 general physicsTelecommunicationsbusinessComputingMilieux_MISCELLANEOUS
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Akhmediev breathers as ultra-wideband pulses

2014

We analytically calculate and discuss the radio-frequency spectrum of the so called Akhmediev breathers (ABs), a class of nonlinear solutions of the nonlinear Schrodinger equation that governs the propagation in a single mode optical fiber. We propose a practical application of ABs to the field of ultra-wideband pulse generation. © 2014 Wiley Periodicals, Inc. Microwave Opt Technol Lett 56:664–667, 2014

Physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Optical fiber[ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]Field (physics)BreatherSingle-mode optical fiberNonlinear opticsCondensed Matter PhysicsAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsPulse (physics)law.inventionsymbols.namesakeNonlinear systemlawQuantum mechanicsQuantum electrodynamicssymbolsElectrical and Electronic EngineeringNonlinear Schrödinger equation
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Temporal dynamics of incoherent waves in noninstantaneous response nonlinear Kerr media

2012

International audience; We consider the temporal evolution of an incoherent optical wave that propagates in a noninstantaneous response nonlinear medium, such as single mode optical fibers. In contrast with the expected Raman-like spectral redshift due to a delayed nonlinear response, we show that a highly noninstantaneous response leads to a genuine modulational instability of the incoherent optical wave. We derive a Vlasov-like kinetic equation that provides a detailed description of this process of incoherent modulational instability in the temporal domain.

Physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Optical fiber[ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]Wave propagationbusiness.industrySingle-mode optical fiberNonlinear optics[STAT.TH]Statistics [stat]/Statistics Theory [stat.TH]01 natural sciencesAtomic and Molecular Physics and Optics010305 fluids & plasmaslaw.invention[MATH.MATH-PR]Mathematics [math]/Probability [math.PR]Nonlinear systemModulational instabilityOpticslaw[MATH.MATH-ST]Mathematics [math]/Statistics [math.ST]Nonlinear medium0103 physical sciences010306 general physicsbusinessComputingMilieux_MISCELLANEOUSCoherence (physics)
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Spectral dynamics of modulation instability described using Akhmediev breather theory

2011

International audience; The Akhmediev breather formalism of modulation instability is extended to describe the spectral dynamics of induced multiple sideband generation from a modulated continuous wave field. Exact theoretical results describing the frequency domain evolution are compared with experiments performed using single mode fiber around 1550 nm. The spectral theory is shown to reproduce the depletion dynamics of an injected modulated continuous wave pump and to describe the Fermi-Pasta Ulam recurrence and recovery towards the initial state. Realistic simulations including higher-order dispersion, loss and Raman scattering are used to identify that the primary physical factors that …

Physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Spectral theory[ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]SidebandBreatherbusiness.industrySingle-mode optical fiber01 natural sciencesInstabilityAtomic and Molecular Physics and Optics010309 opticssymbols.namesakeOpticsFrequency domain0103 physical sciencessymbolsContinuous wave010306 general physicsbusinessRaman scattering
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Dissipative soliton in a laser cavity: A novel concept in action

2006

International audience; The recent concept of a dissipative optical soliton sheds new light for understanding the stability of optical pulses that are generated in passively mode-locked lasers. Considering in these lasers the multiple pulsing regime of operation, the dissipative soliton concept is able to explain the great diversity of interaction behaviours that have been observed experimentally. Among the most spectacular behaviours are the formation of "soliton molecules" and "elastic-type" collisions. The dissipative soliton also explains the existence of complex limit cycles of pulsations within single pulse operation.

Physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics][ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]Single pulseGeneral Physics and AstronomySoliton (optics)02 engineering and technologyLaser01 natural sciencesAction (physics)law.inventionDissipative soliton020210 optoelectronics & photonicslawOptical cavityQuantum mechanicsQuantum electrodynamics0103 physical sciencesLimit (music)0202 electrical engineering electronic engineering information engineeringDissipative system010301 acousticsNonlinear Sciences::Pattern Formation and Solitons
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