Search results for "Sintering"

Interface Diffusion Controlled Sintering of Atomically Clean Surfaces of Metals

2003

Environmental modelling of aluminium based components manufacturing routes: Additive manufacturing versus machining versus forming

2018

Abstract Additive Manufacturing represents, by now, a viable alternative for metal-based components production. Therefore the designer, often, has to select among three options at process design stage: subtractive, mass conserving, and additive approaches. The selection of a given process, besides affecting the manufacturing step impact, influences significantly the impact related to the material production step. If the process enables a part weight reduction (as the Additive Manufacturing approaches do) even the use phase is affected by the manufacturing approach selection. The present research provides a comprehensive environmental manufacturing approaches comparison for components made o…

Initial Preparation and Characterization of Single Step Fabricated Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFC)

2013

In this study, facile tape casting process has been successfully carried out to fabricate an unit anode supported intermediate temperature solid oxide fuel cell (IT-SOFC) with four different layers: a composite cathode which is a mix of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF48) and Gd0.1Ce0.9O1.9 (GDC10), GDC10 as thin electrolyte layer, NiO-GDC10 without pore former as thin anode functional layer (AFL), and anode support layer of NiO-GDC10 with carbon pore former. The multi-layer was sintered once to produce an unit planar cell. An OCV of 1.002 V at 500 °C, and maximum power density of 466 mW cm–2 at 648 °C are obtained. These results indicate negligible leakage of fuel through electrolyte. Furtherm…

Analogical Modeling and Numerical Simulation for Sintering Phenomena

2013

In this paper the authors propose an approach for analogical modeling and numerical simulation of the phenomena of sintering, taking into account different cases depending on the type of energy used in the process of aggregation and the nature of the material powder, using a software which simulates the propagation and the control of the temperature. Many physical phenomena encountered in science and engineering can be described mathematically through partial differential equations (PDE) and ordinary differential equations (ODE) such as propagation phenomena, engineering applications, hydrotechnics, chemistry, pollution a.s.o. There may be situations when the exact establish of the analytic…

Ceria-based electrolytes prepared by solution combustion synthesis: The role of fuel on the materials properties

2016

Ce0.8Sm0.2O2 − xpowders were synthesized by solution combustion synthesis using citric acid, cellulose and sucrose as single, or intimately mixed, fuels. The powders were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, N2sorption at −196 °C, H2-temperature programmed reduction and thermogravimetric analyses. Textural properties of the powders were shaped by the peculiar employed fuel. The study of reducibility revealed that oxygen vacancies formation is mainly influenced by both parameters, specific surface area and total pore volume. The different tendency toward reduction played a key role in sintering under reducing atmosphe…

Mechanical, thermal and electrical properties of nanostructured CNTs/SiC composites

2018

International audience; Dense SiC-based nanostructured composites reinforced by well-distributed carbon nanotubes (CNTs) were elaborated for the first time by spark plasma sintering (SPS) without sintering additive. Microstructures of materials containing different amounts of CNTs – up to 8.0 vol% – were correlated with their mechanical, electrical and thermal properties. A continuous decrease of the SiC grain size was observed when the amount of CNT was increased, while the evolution of density showed a different behavior that could be explained by the particular combination of SPS technique with the electrical resistivity evolution of the green bodies. Optimal effect of CNTs addition on h…

Effect of different sintering process on flexural strength of translucency monolithic zirconia

2018

Background Sintering process is responsible for the strength of zirconia restoration. This study evaluated the effect of different sintering temperatures and sintered-holding times on flexural strength of translucency monolithic zirconia. Material and Methods One hundred and thirty five zirconia bar specimens (width-length-thickness = 10×20×1.5 mm) were prepared from yttria-stabilized tetragonal zirconia polycrystalline (Y-TZP) ceramic and randomly divided into nine groups to be sintered at different temperatures [decreasing- (SD, 1350°C), regular- (SR, 1450°C), and increasing- (SI, 1550°C) sintering temperature] and different sintered-holding times [shortening- (HS, 60 min), regular- (HR, …

Metal-support interaction and redox behavior of Pt(1 wt %)/Ce0.6Zr0.4O2

2006

The catalyst Pt(1 wt %)/Ce(0.6)Zr(0.4)O(2) is studied by CO-temperature programmed reduction (CO-TPR), isothermal oxygen storage complete capacity (OSCC), X-ray absorption spectroscopy (XAS) at the Pt L(III) edge, and in situ X-ray diffraction (in situ XRD), with the aim of elucidating the role of supported metal in CO oxidation by ceria-based three-way catalysts (TWC). The redox behavior of Pt(1 wt %)/Ce(0.6)Zr(0.4)O(2) is compared to that of bare ceria-zirconia. OSCC of redox-aged Pt/ceria-zirconia is twice that of bare ceria-zirconia, and the maximum of CO consumption occurs at a temperature about 300 K lower than redox-aged ceria-zirconia. XAS analysis allows one to evidence the formati…

Manufacturing and characterization of single cell intermediate-temperature solid oxide fuel cells for APU in transportation application

2014

The fabrications of large area IT-SOFC planar cell by new simple and cost effective process were explained. The optimization of the new process with respect to pore formers, thickness of layers, sintering temperature were performed. The electrochemical results of 10cm2 performed in Fiaxell open flange set up were detailed with respect to different configuration. Long term ageing performance tests of single cells were conducted in Fiaxell device and results are discussed. Preparation of new test bench and stacking process performed till now were briefed.

Elaboration de matériaux à gradient de propriétés fonctionnelles pour les composants face au plasma des machines de fusion thermonucléaires

2014

The objective of this study was to develop a Functionally Graded Material (FGM) W / Cu to replace the compliance layer (Cu-OFHC) in the plasma facing components of thermonuclear fusion reactor like ITER. The peculiarity of this work is to elaborate these materials without exceeding the melting temperature of copper in order to control its microstructure. The co-sintering is the most attractive solution to achieve this goal.The first phase of this study has been to decrease the sintering temperature of the tungsten to achieve this co-sintering. The elaboration of a Functionally Graded Materials being delicate, thermo-mechanical calculations were performed in order to determine the number and…