Search results for "Sisal"
showing 10 items of 35 documents
Thermal kinetics for the energy valorisation of polylactide/sisal biocomposites
2018
[EN] The thermal stability and decomposition kinetics of PLA/sisal biocomposites was discussed to evaluate the suitability of their use in energy recovery processes such as pyrolysis and combustion. The influence of the addition of sisal up to 30%wt, the presence of coupling agent, and the atmosphere of operation, i.e. inert or oxidative was discussed by means of multi-rate linear non-isothermal thermogravimetric experiments. All biocomposites showed a mean high heating value of 15 MJ/kg indicating their suitability for energy recovery processes. The thermal requirements of PLA/sisal decomposition were assessed in terms of onset decomposition temperature and apparent activation energy. A mi…
Low-velocity impact behaviour of green epoxy biocomposite laminates reinforced by sisal fibers
2020
Abstract Due to its good mechanical characteristics, low cost and high availability in the current market, sisal fiber is one of the most used for the manufacturing of biocomposites in various industrial fields (automotive, marine, civil construction etc.). The particular sub-fibrillar structure of the sisal fiber (similar to aramid fibers) and the corresponding anisotropic behavior detected by recent research activities, suggest that such biocomposites should exhibit also high impact strength, in such a way to permit their advantageously use also for the manufacturing of crashworthy components (bumpers, helmets, protection systems etc.), that are at the same time also eco-friendly, lightwe…
Water absorption and hydrothermal performance of PHBV/sisal biocomposites
2014
[EN] The performance of biocomposites of poly(hydroxybutyrate-co-valerate) (PHBV) and sisal fibre subjected to hydrothermal tests at different temperatures above the glass transition of PHBV (TH ¿ 26, 36 and 46 C) was evaluated in this study. The influences of both the fibre content and presence of coupling agent were focused. The water absorption capability and water diffusion rate were considered for a statistical factorial analysis. Afterwards, the physico-chemical properties of water-saturated biocomposites were assessed by Fourier-Transform Infrared Analysis, Size Exclusion Chromatography, Differential Scanning Calorimetry and Scanning Electron Microscopy. It was found that the water d…
Effect of sisal and hydrothermal ageing on the dielectric behaviour of polylactide/sisal biocomposites
2017
[EN] The dielectric properties of virgin polylactide (PLA) and its reinforced composites with different weight amounts of sisal fibres were assessed at broad temperature (from - 130 degrees C to 130 degrees C) and frequency ranges (from 10(-2)-10(7) Hz), before and after being subjected to accelerated hydrothermal ageing. The synergetic effects of both the loading of sisal and hydrothermal ageing were analysed by means of dielectric relaxation spectra. The relaxation time functions were evaluated by the Havriliak-Negami model, substracting the ohmic contribution of conductivity. The intramolecular and intermolecular relaxations were respectively analysed by means of Arrhenius and Vogel-Fulc…
Thermal stability of PP with acetylated sisal fiber: Romero Garc�a kinetic method
2003
This work deals the effect of acetylated and non-acetylated sisal fiber 011 thermal degradation of polypropylene. Applying the R-G method at constant conversion levels of 0.1, 0.3, 0.5, 0.7 and 0.9 to thermograms of the ”PP/untreated sisal fiber” blend, E, values of 99, 213, 224, 187, and 145 kJ/mol were obtained, whereas they were 99, 299, 255, 205, 154 kJ/mol for the “PP/treated sisal fiber” blend. On the other hand, with the R-G method at constant temperature, activation energies within the range of 156-417 kJ/mol were obtained for the “PP/treated sisal fiber” blend and within the range of 126-344 kJ/mol for the “PP/untreated sisal fiber” blend. Additionally, the method establishes as do…
Thermal and thermo-oxidative stability and kinetics of decomposition of PHBV/sisal composites
2017
The decomposition behaviours of composites made of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and sisal were assessed in terms of thermal stability and decomposition kinetics, under inert and oxidative conditions, by means of multi-rate linear non-isothermal thermogravimetric experiments. A statistical design of experiments was applied to study the influence of the addition of sisal (0-10-20-30%wt), the presence coupling agent (Yes/No) and the applied conditions of work (inert or oxidative). An improvement of the thermal and thermo-oxidative stability of PHBV with the addition of sisal was observed for all cases. An accurate methodology based on iso-conversional methods was applied…
ANALISI DEL COMPORTAMENTO MECCANICO DI SANDWICHES GREEN COSTITUITI DA PELLI IN BIOCOMPOSITO E CORE IN BALSA/SUGHERO
2022
Negli ultimi anni l’aumento della sensibilità nei confronti della salvaguardia ambientale, anche attraverso apposite norme in materia di lotta all’inquinamento e di riciclo dei materiali a fine vita, ha portato ad un notevole interesse dei ricercatori verso i cosiddetti compositi green, materiali costituiti in genere da rinforzi di origine naturale e matrici “bio-based” a basso impatto ambientale. Una categoria interessante di materiali innovativi, caratterizzati da una elevata resistenza a flessione unita ad un basso peso specifico, è rappresentata dai cosiddetti sandwiches, costituiti in genere da robuste pelli in composito fibro-rinforzato e da un core in materiale molto leggero e poco r…
A new eco-friendly chemical treatment of natural fibres: Effect of sodium bicarbonate on properties of sisal fibre and its epoxy composites
2016
Abstract Several researchers have shown how sisal fibres possess remarkable tensile properties that yield them good candidates as reinforcement in biocomposite materials. This work aims to evaluate the effect of an eco-friendly and cost effective surface treatment method based on the use of commercial sodium bicarbonate (i.e. baking soda) on properties of sisal fibre and its epoxy composites. In particular, raw sisal fibres were treated with a 10%w/w of sodium bicarbonate solution for different periods (24, 120 and 240 h), at room temperature. Changes occurring in sisal fibres were characterized through scanning electron microscope, Fourier transform infrared spectroscopy, thermogravimetric…
RESISTENZA STATICA E A FATICA DI NUOVI LAMINATI BIOCOMPOSITI RINFORZATI CON FIBRE DI AGAVE
2018
L’obiettivo di ridurre l’inquinamento legato alla produzione ed allo smaltimento dei materiali sintetici ha portato recentemente alla messa punto di normative di protezione ambientale che impongono l’uso crescente di materiali ecocompatibili e/o rinnovabili, e conseguentemente Ad un notevole interesse verso i cosiddetti biocompositi, materiali innovativi ottenuti attraverso il rinforzo di polimeri ecocompatibili o rinnovabili con fibre naturali quali lino, juta, canapa, agave ecc. Nonostante numerosi lavori di ricerca siano stati indirizzati a tali materiali, allo stato attuale pochi lavori hanno riguardato lo sviluppo di biocompositi ad elevate performance per applicazioni strutturali. Al …
Numerical model for the characterization of biocomposites reinforced by sisal fibres
2018
Abstract Although several works have been recently published in literature about biocomposites, i.e. on innovative and ecofriendly polymer matrix composites reinforced by natural fibers, there are not studies on the influence of the waviness that various natural fiber present after their extraction. In order to give a contribution to the knowledge of the effects of the fiber waviness on the main mechanical properties of biocomposites, as the longitudinal Young modulus, in the present study a systematic numerical analysis has been carried out by using parametric models properly developed, that let the user to consider the effects of the key influence parameters as the fiber concentrations an…