Search results for "Sky"
showing 10 items of 1603 documents
Effective cloud optical depth for overcast conditions determined with a UV radiometers
2014
Using a sky camera, episodes characterized by overcast low clouds in the Valencia region of Spain have been selected for analysis. One year of cloud optical depth data have been produced by inverting UV erythemal irradiance measured with a UVB-1 radiometer from Yankee Environmental Systems using the LibRadtran radiative transfer model. Measurement uncertainties, aerosol single scattering albedo and cloud properties are, in order of decreasing importance, the most important factors influencing the accuracy of cloud optical depth retrieval when using UV erythemal radiometers. Statistics for cloud optical depth show a highly skewed frequency distribution best described by a gamma distribution …
Autonomous Measurements of Sea Surface Temperature Using In Situ Thermal Infrared Data
2004
Abstract In situ and autonomous measurements of sea surface temperature (SST) have been performed with a thermal infrared radiometer mounted on a fixed oil rig. The accuracy limit was established at ±0.3 K for these SST measurements in order to meet the requirements of the Tropical Ocean Global Atmosphere (TOGA) program for global climate research and the Soil Moisture and Ocean Salinity (SMOS) mission for salinity retrieval. With this aim, the optimal observation angle and spectral channel for SST measurements have been identified. Then, a methodology has been developed for the radiometer calibration and the emissivity correction, including the reflection of the downwelling sky radiance, w…
Long-term (1995-2018) aerosol optical depth derived using ground based AERONET and SKYNET measurements from aerosol aged-background sites
2019
Abstract We examined long-term aerosol optical depth (AOD) trends over 53 sites across the globe which comprise 49 sites from the Aerosol Robotic Network (AERONET) and 4 sites from the Sky radiometer Network (SKYNET) during 1995–2018. Most of these sites are located in remote and isolated aged-background regions, and few are in urban/semi-urban sites having averaged AOD ∼0.1 at 500 nm. These selected sites have a global distribution including tropical, mid-latitudes, high-latitudes and Polar regions. Among them, there are 14 high-altitude stations (∼1028–5050 m amsl), including Himalayan and Polar regions. The main objective of the present work is to evaluate the AOD trends over the aged-ba…
Incorporation of aerosol effects in a clear-sky semi-empirical model of UVER radiation for Valencia, Spain
2011
The study develops a simple but physically based model for estimating erythemal irradiance [(UV erythemal radiation (UVER)] for cloudless urban regions with substantial aerosol load, such as that of the Valencia environment in Spain. The model estimates direct and diffuse UVER for cloudless aerosol-free conditions using the LibRadtran model with a DISORT algorithm. Aerosol optical thickness for UVER (τaER) is obtained as a residual term by comparing measured direct UVER against modelled direct UVER in the absence of aerosol load. On average, τaER is 18% higher than τ data extrapolated to 305 nm using the CIMEL CE-318. Comparison of measured direct and diffuse UVER with model estimates provi…
Monitoring of Eyjafjallajökull volcanic aerosol by the new European Skynet Radiometers (ESR) network
2012
Abstract The passage of a volcanic plume produced by the eruption of Eyjafjallajokull volcano in April 2010 was measured by the sun–sky radiometers of the new European SkyRad (ESR) network. This network consists of several European sites located in the U.K., Poland, Spain and Italy, and therefore was particularly suitable for monitoring the transport of volcanic ash generated by this particular volcano. The atmospheric aerosol characteristics at each site affected by the passage of the volcanic cloud, during and after the eruption, have been reconstructed. For the U.K. ESR sites three events were identified by the sun–sky radiometers: the first, from April 15 to April 16 2010, related to th…
The CCSD(T) model with Cholesky decomposition of orbital energy denominators
2010
A new implementation of the coupled cluster singles and doubles with approximate triples correction method [CCSD(T)] using Cholesky decomposition of the orbital energy denominators is described. The new algorithm reduces the scaling of CCSD(T) from N-7 to N-6, where N is the number of orbitals. The Cholesky decomposition is carried out using simple analytical expressions that allow us to evaluate a priori the order in which the decomposition should be carried out and to obtain the relevant parts of the vectors whenever needed in the calculation. Several benchmarks have been carried out comparing the performance of the conventional and Cholesky CCSD(T) implementations. The Cholesky implement…
Influence of regionality and maturation time on the chemical fingerprint of whisky.
2020
International audience; Understanding the chemical composition of whisky and the impact of each step in the manufacturing process provides a basis for responding to the challenges of producing high quality spirits. In this study, the objective was to discriminate whiskies according to their geographical origin and authenticate the maturation time in cask based on the non-volatile profiles. The combination of FT-ICR-MS and chemometrics allowed the distinction of whiskies from four geographical origins in Scotland (Highlands, Lowlands, Speyside and Islay). Statistical modeling was also used to discriminate whiskies according to the maturation time in cask and reveal chemical markers associate…
Autofiction oulipienne: l'écriture au miroir
2010
L’autofiction, genre hybride qui mêle autobiographie et fiction, semble devoir s’incarner de manière originale, innovante, dans la production oulipienne. Revisitée, l’autofiction oulipienne permet de redéfinir le rapport entre œuvre et écrivain. C’est le choix stylistique qui consent aux oulipiens de renouveler l’autobiographie par l’intervention d’une écriture en apparence exclusivement fictionnelle mais qui, au contraire, recèle et dissimule des indices autobiographiques à déchiffrer pour une complète compréhension du texte : ce sont les autobiographies « impures » de Perec et celles poétiques de Roubaud. Toutefois, l’autofiction innovante n’est pas celle qui évoque le passé mais celle qu…
Mechanistic Investigations of the BZ Reaction with Oxalic Acid Substrate. I. The Oscillatory Parameter Region and Rate Constants Measured for the Rea…
2004
This paper is the first part of a study reinvestigating the mechanism of the Belousov-Zhabotinsky (BZ) reaction of oxalic acid, which is the simplest organic substrate for a BZ oscillator. New experiments are performed to find the oscillatory region in 1 M sulfuric acid at 20 °C. The removal rate of the end product bromine by an inert gas stream is a critical parameter here: oscillations can be observed only in a window of that parameter. The “rate constant” for the physical removal of bromine is measured as a function of the gas flow rate and reactor volume; furthermore, the rate constants of three component reactions important in this system are also determined. These are oxygen atom tran…