Search results for "Slurry"
showing 10 items of 44 documents
Guidelines for the Assessment and the Validation of the Rate Law of Slurry Photocatalytic Reactions
2017
The assessment of the rate law of slurry photocatalytic reactions appears to be a hard task, mainly because in this type of reactions the average rate of reaction, which is experimentally observed in a real reactor, could be very different from the “true” (intrinsic) rate of reaction, which cannot be measured directly. In the present work, it is shown how a proper mathematical model allows the utilization of the differential and/or the integral methods of kinetic analysis. The mathematical model must take into account not only the momentum and the mass balances, but also the radiative transfer equation. However, the discrimination among different proposed kinetic laws remains difficult sinc…
Measurements of Njs and Power Requirements in Unbaffled Bioslurry Reactors
2012
The remediation of urban/industrial polluted lands is a topic of crucial importance nowadays. Bioremediation techniques are widely employed to remove organic pollutants from contaminated soils because of their simplicity and cheapness. The bioslurry reactors mechanically agitated by stirrers represent one of the most promising bioremediation techniques. In the present work an unbaffled stirred vessel filled with solids and water is experimentally investigated from a fluid dynamic point of view. Air presence within the tank is guaranteed by the central vortex formation (typical occurrence concerning stirred vessels unprovided with baffles) instead of an intrinsically more expensive insufflat…
Power requirements for complete suspension and aeration in an unbaffled bioslurry reactor
2016
Remediation of contaminated soils is spreading as a matter of crucial importance nowadays. Bioremediation via bioslurry reactors of sites polluted by recalcitrant pollutants has been proved to be a valuable option, although optimization is needed to reduce process costs. Free-surface unbaffled stirred tanks (with central air vortex) have been recently proposed as a promising alternative to the more common systems provided with baffles. In a bioslurry reactor solid-liquid interfacial area, oxygen supply, solid loading per reactor unit volume should be maximized, and, at the same time, operation costs have to be kept low. In this regard, the minimum impeller speeds for complete suspension Njs…
FORMULATION OF LIME MORTARS BASED ON NATURAL FIBERS AND WASTE MATERIALS FOR MORE SUSTAINABLE BUILDINGS
2019
Nowadays sustainability is one of the main concept in building construction, both considering energy saving buildings and life cycle assessment of building materials. According to these considerations, in this work the use of recycled and waste materials to produce a binder and the use of a natural fiber as reinforcement are investigated to obtain a sustainable mortar. Particularly, lime is obtained by kilning waste marble slurry from marbles quarries in western Sicily; pozzolanic aggregate is obtained by grinding glass powder from urban waste collection; natural fibers come from a widespread grass: Ampelodesmos Mauritanicus also known as diss. Scanning electron microscopy and helium picnom…
The influence of the tape-casting process parameters on the geometric characteristics of SiC tapes
1998
Abstract The production process of the tape-casting technique applied to the production of porous ceramic membranes, suitable for the separation of different chemical species, has been explored, with emphasis on the influence of the operative parameters on the macrogeometric characteristics of the manufactured ceramic porous tapes. The effects of the slurry casting rate, the doctor blade height and the mean particle diameter have been studied and the results reported. The characterization analyses indicate the degree of reliability of this technique to produce planar SiC components and the importance of the particle size in enhancing the structural homogeneity. A study on the variance analy…
Fluidized Bed Combustion and Gasification of Fossil and Renewable Slurry Fuels
2021
This article provides a comprehensive review of the state of the art and more recent developments of the thermochemical treatments of slurry fuels in fluidized beds (FB). The review focuses on FB combustion and gasification of slurry fuels based on coal, biomass, sludge, and wastes from industry, agriculture, and the civil sector. The investigations at research and industrial levels over the last decades are presented and discussed, highlighting the adopted technological solutions, the results in terms of feasibility and efficiency, and the perspectives of future development. The different behavior between bubbling and circulating beds was addressed, in particular the optimal choice dependi…
Particle flow modelling in slurry-fed stirred vessels
2004
In this paper experimental information on the retention time distribution (RTD) of solid particles in a high-aspect-ratio vessel, stirred by three equally spaced Rushton turbines, is presented. The relevant data were obtained by a special technique named twin system approach (TSA) that greatly simpli+es the handling of particle-laden streams and is therefore particularly suited for investigating particle RTD in 9ow systems. The technique fundamentals are +rst summarized, together with the data analysis procedure. This lastly requires a numerical deconvolution operation that is easily performed with the help of Z-transforms. Two di;erent approaches for excluding the spurious contributions of…
Guidelines for the assessment of the rate law of slurry photocatalytic reactions
2017
Abstract The assessment of the rate law of slurry photocatalytic reactions appears to be a hard task, mainly because in this type of reactions the average rate of reaction, which is experimentally observed in a real reactor, could be very different from the “true” (intrinsic) rate of reaction, which cannot be measured directly. In the present work, it is shown how a proper mathematical model allows the utilization of the differential and/or the integral methods of kinetic analysis. The mathematical model must take into account not only the momentum and the mass balances, but also the radiative transfer equation. However, the discrimination among different proposed kinetic laws remains diffi…
Optical properties of TiO2 suspensions: Influence of pH and powder concentration on mean particle size
2007
WOS: 000250584100025
A reaction engineering approach to kinetic analysis of photocatalytic reactions in slurry systems
2016
Abstract The knowledge of the rate equation is fundamental for the assessment of the activity of the photocatalytic material and for the study, design and optimization of photocatalytic reactors. In the case of photocatalytic reactions, the local volumetric rate of photon absorption (LVRPA) affects the reaction rate and its inherently uneven distribution within a “slurry” reactor makes complex a correct kinetic analysis. In the present work it is shown which are the critical aspects of the kinetic analysis in slurry reactors and how to carry out photocatalytic experiments to minimize the misinterpretations of the experimental results. In particular, the influence of the type of illumination…