Search results for "Society"
showing 10 items of 1529 documents
Ternary transition metals sulfides in hydrotreating catalysis.
2007
International audience; Pure microcrystalline barium molybdate BaMoO4 and barium tungstate BaWO4 materials were prepared by molten flux reaction using alkali metal nitrates as reaction media. The obtained crystals have rhombic shape and expose mostly (111) crystallographic planes. Their mean size depends on the flux temperature and the nature of the alkali metal cation. Monomeric molybdate and tungstate used as precursors yield target products already at 673 K whereas if polymerized ammonium oxosalts were used, then higher temperatures were necessary to obtain barium salts. The optimal temperature for the preparation of pure crystals with well defined shape was found to be near 773 K. UV–vi…
Insights into Intrinsic Defects and the Incorporation of Na and K in the Cu2ZnSnSe4 Thin-Film Solar Cell Material from Hybrid-Functional Calculations
2016
We have performed density functional theory calculations using the HSE06 hybrid functional to investigate the energetics, atomic, and electronic structure of intrinsic defects as well as Na and K impurities in the kesterite structure of the Cu2ZnSnSe4 (CZTSe) solar cell material. We found that both Na and K atoms prefer to be incorporated into this material as substitutional defects in the Cu sublattice. At this site highly stable (Na–Na), (K–K), and (Na–K) dumbbells can form. While Na interstitial defects are stable in CZTSe, the formation of K interstitial defects is unlikely. In general, the calculated formation energies for Na-related defects are always lower compared to their K-related…
Anthropogenic lead distribution in soils under arable land and permanent grassland estimated by Pb isotopic compositions
2008
International audience; The role of land use on fate of metals in soils is poorly understood. In this work, we studied the incorporation of lead in two neighboring soils with comparable pedogenesis but under long-term different agricultural management. Distributions of anthropogenic Pb were assessed from concentrations and isotopic compositions determined on bulk horizon samples, systematical 5–10 cm increment samples, and on 24-h EDTA extracts. Minor amounts of anthropogenic lead were detected until 1-m depth under permanent grassland, linked to high earthworm activity. In arable land, exogenous Pb predominantly accumulated at depths <60 cm. Although the proximity between the two sites ens…
Progress on bringing together raptor collections in Europe for contaminant research and monitoring in relation to chemicals regulation.
2019
Paola Movalli et al.
Pollen and non-pollen palynomorph evidence of medieval farming activities in southwestern Greenland
2010
International audience; Radiocarbon dating, pollen and non-pollen palynomorph analyses from a lake core were used to establish the timing and effects of farming activities around Lake Igaliku, Eastern Settlement, Greenland. The absence of agro-pastoral impact before the medieval colonization by Europeans provides an opportunity to understand the development of farming activity in a pristine landscape. The results show that the first phase of clearance and grazing pressure, without the expansion of the Norse apophyte (native plant, in habitats created by humans) Rumex acetosa type, could have occurred in the 9–10th century A.D. The presence of Norse settlers and livestock is clearly recorded…
Connecting Gien Castle to its Landscape: Faunal, Environmental and Buildings Analyses (Loiret, France)
2021
International audience; Gien castle is a listed monument of French architectural heritage. Today it houses the National Museum of Hunting and its collection. Organised visits to the site have traditionally lacked any clear mention of the castle’s historical background. Recently, however, archaeological excavations and building analysis in 2011–2015 produced a wealth of new knowledge about the castle’s medieval origins and history, and about its relationship to its landscape. During the ninth and tenth centuries and then in the fifteenth century the castle occupied a strategically exceptional position reflecting the connection with its environment, notably the strong connection between the c…
Sello alimentario romano relacionado con Juno Sospita procedente del SE Hispano
2017
Roman alimentary stamps have an iconography that sometimes is difficult to interpret. In this paper, some valuations on the images displayed on both sides of one of these objects, namely an example belonging to a private collection in Murcia, are offered. In its original publication a relation to agrarian cults through motifs that would refer to the goddess Ceres was proposed. However, it is a composition having its closest parallels in a series of Roman Republican coins issued in 64 bc by Lucio Roscio Fabato. These denarii are mainly linked to Juno Sospita and secondarily also to the Egyptian cults of Mediterranean expansion. Therefore we evaluate the possibility that such religious intera…
Early Middle Ages Houses of Gien (France) from the Inside: Geoarchaeology and Archaeobotany of 9th–11th c. Floors
2018
International audience; At Gien (France), indoor floors from early Middle Ages occupation (8th–10th c. AD) are very well preserved, providing a new reference for archaeological investigation in northern France. This site is located on an outcrop, 20 m above the Loire valley, where a 15th c. castle stands now. The medieval occupation combines high-status houses with crafting and agricultural areas. They constitute a new urban nucleus, which grew 2 km east from an ancient Roman settlement. During the rescue excavation, four buildings of different status were sampled and studied using an integrated approach, combining stratigraphy, micromorphology, chemical, macro-remain and phytolith analyses…
The influence of religious identity and socio-economic status on diet over time, an example from medieval France
2019
International audience; In Southern France as in other parts of Europe, significant changes occurred in settlement patterns between the end of Antiquity and the beginning of the Middle Ages. Small communities gathered to form, by the tenth century, villages organized around a church. This development was the result of a new social and agrarian organization. Its impact on lifestyles and, more precisely, on diet is still poorly understood. The analysis of carbon and nitrogen isotopes in bone collagen from the inhabitants of the well-preserved medieval rural site Missignac-Saint Gilles le Vieux (fifth to thirteenth centuries, Gard, France) provides insight into their dietary practices and enab…
Cultural evolution and environmental change in Central Europe between 40 and 15 ka
2020
The role of environmental change in the evolution of cultural traits is a topic of long-standing scientific debate with strongly contrasting views. Major obstacles for assessing environmental impacts on the evolution of material culture are the fragmentary nature of archaeological and – to a somewhat lesser extent – geoscientific archives and the insufficient chronological resolution of these archives and related proxy data. Together these aspects are causing difficulties in data synchronization. By no means does this paper attempt to solve these issues, but rather aims at shifting the focus from demonstrating strict chains of causes and events to describing roughly contemporaneous developm…