Search results for "Soft modes"
showing 9 items of 29 documents
The quantum paraelectric phase of SrTiO$_3$ from first principles
2021
We demonstrate how the quantum paraelectric ground state of SrTiO$_3$ can be accessed via a microscopic $ab~initio$ approach based on density functional theory. At low temperature the quantum fluctuations are strong enough to stabilize the paraelectric phase even though a classical description would predict a ferroelectric phase. We find that accounting for quantum fluctuations of the lattice and for the strong coupling between the ferroelectric soft mode and lattice elongation is necessary to achieve quantitative agreement with experimental frequency of the ferroelectric soft mode. The temperature dependent properties in SrTiO$_3$ are also well captured by the present microscopic framework.
Effective description of domain wall strings
2017
The analysis of domain wall dynamics is often simplified to one-dimensional physics. For domain walls in thin films, more realistic approaches require the description as two-dimensional objects. This includes the study of vortices and curvatures along the domain walls as well as the influence of boundary effects. Here we provide a theory in terms of soft modes that allows us to analytically study the physics of extended domain walls and their stability. By considering irregularly shaped skyrmions as closed domain walls, we analyze their plasticity and compare their dynamics with those of circular skyrmions. Our theory directly provides an analytical description of the excitation modes of ma…
Magnetic excitations in TbP under hydrostatic pressure
1982
Singlet ground state magnets still attract much attention. In these systems magnetic ordering occurs via the polarization of the ground state, and noticeable dispersion of well defined excitations is expected in systems where the exchange coupling is about equal to the crystal field energy. In addition, the two singlet-triplet systems PrSbl and TbP2 where single crystals are available and which have been studied in detail showed a pronounced splitting of the Г1–Г4 magnetic excitations where the triple degeneracy was lifted along [100] and [011] by a strong anisotropy of the exchange.
Soft modes and mode splitting in paramagnetic TbP§
1980
In contrast to spin-only systems the paramagnetic phases of systems with crystal field split ground multiplets exhibit magnetic excitations of finite energy. In the presence of a magnetic exchange coupling the excitons will propagate through the lattice. A measurement of the dispersion allows in principle an insight into the exchange interaction, which is of fundamental importance for the understanding of the magnetic phenomena. Unfortunately the evolution of the dispersion at low temperatures is in most cases interrupted by the onset of magnetic order due to an alignment of the magnetic moments of the crystal field ground state. A noticeable dispersion of well-defined excitons is only expe…
Dielectric and electro-optical studies of a ferroelectric copolysiloxane.
1994
This paper reports an extensive study of the static (spontaneous polarization, ${\mathit{P}}_{\mathit{s}}$, tilt angle \ensuremath{\theta}, and pitch) and dynamic properties of a ferroelectric liquid-crystalline polymer. It is shown that a ferroelectric liquid-crystalline polymer (diluted polysiloxane) exhibits physical behavior similar to that of a low-molar-mass liquid crystal in terms of contrast ratio, pitch of the helix, and relationship between ${\mathit{P}}_{\mathit{s}}$ and \ensuremath{\theta}. The degenerated collective modes for the director rotation are shown to split into two modes at the Sm-A--Sm-${\mathit{C}}^{\mathrm{*}}$ phase transition temperature using dielectric spectros…
Local dynamics of DNA probed with optical absorption spectroscopy of bound ethidium bromide
1997
We have studied the local dynamics of calf thymus double-helical DNA by means of an "optical labeling" technique. The study has been performed by measuring the visible absorption band of the cationic dye ethidium bromide, both free in solution and bound to DNA, in the temperature interval 360-30 K and in two different solvent conditions. The temperature dependence of the absorption line shape has been analyzed within the framework of the vibronic coupling theory, to extract information on the dynamic properties of the system; comparison of the thermal behavior of the absorption band of free and DNA-bound ethidium bromide gave information on the local dynamics of the double helix in the prox…
QCD radiative corrections to the soft spectator contribution in the wide angle Compton scattering
2014
We derive the complete factorization formula for the leading power contribution in wide angle Compton scattering. It consists of the soft- and hard-spectator contributions. The hard-spectator contribution is well known and defined in the form of the convolution of a hard kernel with the nucleon distribution amplitudes. The soft-spectator contribution describes the scattering which involves the soft modes. We use the soft collinear effective theory in order to define this term in a field theoretical approach. Using the SCET framework we provide the proof of the factorization formula. We also compute the next-to-leading QCD corrections to the hard coefficient function of the soft spectator co…
Structure-dynamics-function relationships in Asian elephant (Elephas maximus) myoglobin. An optical spectroscopy and flash photolysis study on functi…
1993
In this work we report the thermal behavior (10–300 K) of the Soret band lineshape of deoxy and carbonmonoxy derivatives of Asian elephant (Elephas maximus) and horse myoglobins together with their carbon monoxide recombination kinetics after flash photolysis; the results are compared to analogous data relative to sperm whale myoglobin. The Soret band profile is modeled as a Voigt function that accounts for the coupling with high and low frequency vibrational modes, while inhomogeneous broadening is taken into account with suitable distributions of purely electronic transition frequencies. This analysis makes it possible to isolate the various contributions to the overall lineshape that; in…
Local Structure Studies of Ti for SrTi16O3 and SrTi18O3 by Advanced X-ray Absorption Spectroscopy Data Analysis
2015
Strontium titanate is a model quantum paraelectric in which in the region of dominating quantum statistics the ferroelectric instability is inhibited due to nearly complete compensation of the harmonic contribution into ferroelectric soft mode frequency by the zero-point motion contribution. The enhancement of atomic masses by the substitution of 18O for 16O decreases the zero-point atomic motion and low-T ferroelectricity in SrTi18O3 is realized. In this study we report on the local structure of Ti in SrTi16O3 and SrTi18O3 by Ti K-edge extended x-ray absorption fine structure measurements in temperature range 6 – 300 K.