Search results for "Solid"
showing 10 items of 3575 documents
Dipole surface plasmon in large K N + clusters
1993
The dipole surface plasmon forK N + clusters is analyzed using the RPA sum-rule technique within a semiclassical Density Functional Theory and the spherical jellium model. The theoretical frequencies are blue shifted as compared to the experimental ones. The discrepancies between theory and experiment are reduced when considering non-local energy contributions in the density functional and phenomenologically including atomic lattice effects by means of an electron effective mass and a static dielectric constant.
Short-wavelength soft-x-ray laser pumped in double-pulse single-beam non-normal incidence
2010
We demonstrated a $7.36$ nm Ni-like samarium soft-x-ray laser, pumped by $36$ J of a neodymium:glass chirped-pulse amplification laser. Double-pulse single-beam non-normal-incidence pumping was applied for efficient soft-x-ray laser generation. In this case, the applied technique included a single-optic focusing geometry for large beam diameters, a single-pass grating compressor, traveling-wave tuning capability, and an optimized high-energy laser double pulse. This scheme has the potential for even shorter-wavelength soft-x-ray laser pumping.
Unconstrained periodic boundary conditions for solid state elasticity
2004
We introduce a method to implement dynamics on an elastic lattice without imposing constraints via boundary or loading conditions. Using this method we are able to examine fracture processes in two-dimensional systems previously inaccessible for reliable computer simulations. We show the validity of the method by benchmarking and report a few preliminary results.
The influence of the solvent's mass on the location of the dividing surface for a model Hamiltonian
2019
The Transition State dividing surface is a key concept, not only for the precise calculation of the rate constant of a reaction, but also for the proper prediction of product ratios. The correct location of this surface is defined by the requirement that reactive trajectories do not recross it. In the case of reactions in solution the solvent plays an important role in the location of the dividing surface. In this paper we show with the aid of a model Hamiltonian that the effective mass of the solvent can dramatically change the location of the dividing surface. Keywords: Dynamical systems, Dividing surface, Reactions in solution, 2019 MSC: 00-01, 99-00
Landau Fermi Liquid Theory and Beyond
2014
In this chapter we consider the Landau theory of the Fermi liquid that has a long history and remarkable results in describing a numerous properties of the electron liquid in ordinary metals and Fermi liquids of the \(^3\)He type. The theory is based on the assumption that elementary excitations determine the physics at low temperatures, resembling that of weakly interacting Fermi gas. These excitations behave as quasiparticles with a certain effective mass. The effective mass \(M^*\) exhibits a simple universal behavior, for it is independent of the temperature, pressure, and magnetic field strength and is a parameter of the theory. Microscopically deriving the equation determining the eff…
Energy spectrum and transport properties of the two-dimensional t-J model
1992
Abstract The formation of a ferromagnetically ordered region around a hole in the two-dimensional t-J model is investigated. The energy bands characterized by different values of the z-component of the total spin are analysed. A strong anisotropy of the lower-energy bands is found. For intermediate coupling of additionally included optical phonons, this anisotropy leads to a large polaronic state with an anisotropic envelope oriented along the plane diagonals. In the strong-coupling case the competition between the hole-magnon and the hole-phonon interactions prevents the formation of ferrons. Owing to the large effective mass in both cases, the hole transport takes place via hopping, with …
Highly Correlated Fermi Liquid in Heavy-Fermion Metals: Magnetic Properties
2014
In this chapter we show how the FCQPT theory works, when describing the behavior of HF metals under the application of magnetic field. We show that a large body of experimental data regarding the thermodynamic, transport and relaxation properties collected in measurements on HF metals can be well explained. It is demonstrated that the experimental data exhibit the scaling behavior.
Highly Correlated Fermi Liquid in Heavy-Fermion Metals: The Scaling Behavior
2014
In this chapter we show how the FCQPT theory works. We do that on the base of experimentally relevant examples. Namely, as noted in the Introduction (Chap. 1), the challenge for the theories is to explain the scaling behavior of the normalized effective mass \(M^*_N(y)\) displayed in Fig. 1.3. The theories analyzing only the critical exponents characterizing \(M^*_N(y)\) at \(y\gg 1\) consider only a part of the problem. In this section we analyze and derive the scaling behavior of the normalized effective mass near QCP as reported in Fig. 1.3. We start with describing magnetic field dependence of the quasiparticle effective mass in Sect. 6.1. Quasiparticle damping and the temperature depen…
Extremely slow Drude relaxation of correlated electrons
2005
The electrical conduction of metals is governed by how freely mobile electrons can move throughout the material. This movement is hampered by scattering with other electrons, as well as with impurities or thermal excitations (phonons). Experimentally, the scattering processes of single electrons are not observed, but rather the overall response of all mobile charge carriers within a sample. The ensemble dynamics can be described by the relaxation rates, which express how fast the system approaches equilibrium after an external perturbation1,2,3. Here we measure the frequency-dependent microwave conductivity of the heavy-fermion metal UPd2Al3 (ref. 4), finding that it is accurately described…
Ordered helium trapping and bonding in compressed arsenolite: Synthesis ofAs4O6·2He
2016
Compression of arsenolite has been studied from a joint experimental and theoretical point of view. Experiments on this molecular solid at high pressures with different pressure-transmitting media have been interpreted thanks to state-of-the-art ab initio calculations. Our results confirm arsenolite as one of the most compressible minerals and provide evidence for ordered helium trapping above 3 GPa between adamantane-type $\mathrm{A}{\mathrm{s}}_{4}{\mathrm{O}}_{6}$ cages. Our calculations indicate that, at relatively small pressures, helium establishes rather localized structural bonds with arsenic forming a compound with stoichiometry $\mathrm{A}{\mathrm{s}}_{4}{\mathrm{O}}_{6}\ifmmode\c…