Search results for "Solid"
showing 10 items of 3575 documents
Improved stability of solid state light emitting electrochemical cells consisting of ruthenium and iridium complexes
2006
ABSTRACTTwo charged organometallic complexes containing bulky hydrophobic ligands based on ruthenium (II) and iridium (III) were synthesized and their performance in solid state light emitting electrochemical cells is described. The complexes were chosen as due to their large ligands a diminished susceptibility towards the formation of destructive complexes during device operation is expected. The LEC device performances reveal the longest living devices reported so far under dc bias. Quantum chemical calculations confirm that the major effect of the bulky diphenylphenanthroline ligands is of steric origin and not related with changes in the molecular electronic structure of the complexes.
Understanding the Acidic Properties of the Amorphous Hydroxylated Silica Surface
2019
Amorphous silica is an intrinsic challenging system to study. In the last decades, some particular chemical properties have been discovered and described, but their description and understanding at the molecular level are experimentally difficult. Therefore, theoretical quantum chemical methods and descriptors, combined with experimental input, are a very appropriate set up to tackle this topic. In this study, the acidity of silanol groups of amorphous silica in hydrated conditions is investigated. Special attention has been drawn to the chemical shift, but also Bader charges, and vibrational frequencies with their intensities. The known bimodal acidity behavior was recovered and rationaliz…
Gluon mass and freezing of the QCD coupling
2007
Infrared finite solutions for the gluon propagator of pure QCD are obtained from the gauge-invariant non-linear Schwinger-Dyson equation formulated in the Feynman gauge of the background field method. These solutions may be fitted using a massive propagator, with the special characteristic that the effective mass employed drops asymptotically as the inverse square of the momentum transfer, in agreement with general operator-product expansion arguments. Due to the presence of the dynamical gluon mass the strong effective charge extracted from these solutions freezes at a finite value, giving rise to an infrared fixed point for QCD.
Dynamics of Phase Transition in 0.4NBT-0.4ST-0.2PT Solid Solution
2012
In this paper we present dielectric spectroscopy results of NBT-(0.6-x)ST-xPT with x = 0.2 solid solution. Dielectric investigations clearly showed a relaxor—normal ferroelectric phase transition at TPT = 419 K and low temperature and low frequency dispersion similar to coexistence of dipolar glass and ferroelectric phase. The mean relaxation time above the phase transition follows Vogel—Fulcher law with following parameters: E A = 0.179 eV, τ 0 = 3.39·10−14 s, T VF = 223 K.
Quasi-one-dimensional quantum spin liquid in the $\rm {Cu(C_4H_4N_2)(NO_3)_2}$ insulator
2015
We analyze measurements of the magnetization, differential susceptibility and specific heat of quasi-one dimensional insulator Cu(C$_4$H$_4$N$_2$)(NO$_3$)$_2$ (CuPzN) subjected to magnetic fields. We show that the thermodynamic properties are defined by quantum spin liquid formed with spinons, with the magnetic field tuning the insulator CuPzN towards quantum critical point related to fermion condensation quantum phase transition (FCQPT) at which the spinon effective mass diverges kinematically. We show that the FCQPT concept permits to reveal and explain the scaling behavior of thermodynamic characteristics. For the first time, we construct the schematic $T-H$ (temperature---magnetic field…
Magnetic breakdown and charge density wave formation: a quantum oscillation study of the rare-earth tritellurides
2020
The rare-earth tritellurides ($R$Te$_3$, where $R$ = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Y) form a charge density wave state consisting of a single unidirectional charge density wave for lighter $R$, with a second unidirectional charge density wave, perpendicular and in addition to the first, also present at low temperatures for heavier $R$. We present a quantum oscillation study in magnetic fields up to 65T that compares the single charge density wave state with the double charge density wave state both above and below the magnetic breakdown field of the second charge density wave. In the double charge density wave state it is observed that there remain several small, light pockets…
Magnetic-field-induced reentrance of Fermi-liquid behavior and spin-lattice relaxation rates in
2009
Abstract A strong departure from Landau–Fermi liquid (LFL) behavior have been recently revealed in observed anomalies in both the magnetic susceptibility χ and the muon and 63Cu nuclear spin-lattice relaxation rates 1 / T 1 of YbCu 5 − x Au x ( x = 0.6 ). We show that the above anomalies along with magnetic-field-induced reentrance of LFL properties are indeed determined by the dependence of the quasiparticle effective mass M ∗ on magnetic field B and temperature T and demonstrate that violations of the Korringa law also come from M ∗ ( B , T ) dependence. We obtain this dependence theoretically utilizing our approach based on fermion condensation quantum phase transition (FCQPT) notion. Ou…
Energy scales and magnetoresistance at a quantum critical point
2009
The magnetoresistance (MR) of CeCoIn_5 is notably different from that in many conventional metals. We show that a pronounced crossover from negative to positive MR at elevated temperatures and fixed magnetic fields is determined by the scaling behavior of quasiparticle effective mass. At a quantum critical point (QCP) this dependence generates kinks (crossover points from fast to slow growth) in thermodynamic characteristics (like specific heat, magnetization etc) at some temperatures when a strongly correlated electron system transits from the magnetic field induced Landau Fermi liquid (LFL) regime to the non-Fermi liquid (NFL) one taking place at rising temperatures. We show that the abov…
Fermi Liquid with Fermion Condensate
2014
Here we discuss the general properties of FCQPT leading to the emergence of FC. We present a microscopic derivation of the main equations of FC, and show that Fermi systems with FC form an entirely new class of Fermi liquids with its own topological structure, protecting the FC state. We construct the phase diagram, and explore the order parameter of these systems. We show that the fermion condensate has a strong impact on the observable physical properties of systems, where it is realized, up to relatively high temperatures of a few tens kelvin. Two different scenarios of the quantum critical point (QCP), a zero-temperature instability of the Landau state, related to the divergence of the …
Stability of dark matter from the D4×Z2f flavor group
2011
Abstract We study a model based on the dihedral group D 4 in which the dark matter is stabilized by the interplay between a remnant Z 2 symmetry, of the same spontaneously broken non-abelian group, and an auxiliary Z 2 f introduced to eliminate unwanted couplings in the scalar potential. In the lepton sector the model is compatible with normal hierarchy only and predicts a vanishing reactor mixing angle, θ 13 = 0 . Since m ν 1 = 0 , we also have a simple prediction for the effective mass in terms of the solar angle: | m β β | = | m ν 2 | sin 2 θ ⊙ ∼ 10 − 3 eV . There also exists a large portion of the model parameter space where the upper bounds on lepton flavor violating processes are not …