Search results for "Solid"
showing 10 items of 3575 documents
Alteration of the structural properties of inulin gels
2019
Abstract In this work, inulin particle gels, prepared with a type of long chain inulin, were examined in terms of their structural properties and mechanical response, depending on the applied shear rates and temperature during gel preparation. The results are interpreted on the basis of a particle gel model, which takes into account the varying gel structure, depending on the sample preparation parameters. X-ray measurements of the inulin powder, used for the experiments, revealed a mostly amorphous powder. The temperature profiles for the sample preparation, chosen from 25 °C to 60 °C with constant stirring at 600 rpm, yielded viscoelastic particle gels with decreasing hardness. By applica…
Il destino delle cupole, tra crolli, demolizioni, consolidamenti e ricostruzioni_The destiny of domes, through collapses, demolitions, reinforcements…
2017
Le cupole sono sempre state opere di grande impegno costruttivo e di sperimentazione statica. L’ardita realizzazione o il semplice mancato crollo delle stesse rendeva celebre il progettista e la fabbrica in cui la cupola veniva inserita (spesso anche in un secondo momento, rispetto al primigenio nucleo), allo stesso modo i frequenti collassi ed i dissesti ne segnavano gli insuccessi e le qualità, sia nelle ricostruzioni che nei consolidamenti. Se il sisma costituiva il pericolo maggiore, non minore era il rischio correlato alla costruzione malfatta, prassi costante in aree marginali, che veniva spesso mascherata da finiture di alta qualità. I frequenti disastri fin dall’epoca post-rinascime…
Multi-disciplinary analysis to construct a crustal model of the Sicily Channel using geological and geophysical techniques (data): impacts on geologi…
2023
To understand the dynamics of crustal deformation and earthquakes in active orogenic systems, it is essential to have a detailed view of the lithospheric structures in three dimensions (3D). Several studies in the literature explain how 3D visualization can enable the recognition of tectonic structures or to be able to establish connections between intraplate volcanoes (Wu et al., 2016; Lei & Zhao, 2016; Tan et al., 2019). This work aims to define and discretize a 1D-velocity model of the Sicily Channel; create a detailed 3D lithospheric model of the Sicily Channel using a multidisciplinary approach to evaluate the geological hazard elements that affect the Iblean foreland integrating bathy…
Efficiency of dihydroxamic and trihydroxamic siderochelates to extract uranium and plutonium from contaminated soils
2021
International audience; Actinide-based mineral phases occurring in contaminated soils can be solubilized by organic chelators excreted by plants, such as citrate. Herein, the efficiency of citrate towards U and Pu extraction is compared to that of siderophores, whose primary function is the acquisition of iron(III) as an essential nutrient and growth factor for many soil microorganisms. To that end, we selected desferrioxamine B (DFB) as an emblematic bacterial trishydroxamic siderophore and a synthetic analog, abbreviated (LCy,Pr)H2, of the tetradentate rhodotorulic acid (RA) produced by yeasts. Firstly, the uranyl speciation with both ligands was assessed in the pH range 2–11 by potentiom…
Libre circulación de inversiones en la Unión Europea en tiempos de COVID-19
2020
Las inversiones extranjeras han fluido como nunca durante las últimas décadas, en el marco de una aceptación generalizada de sus beneficios. Esta situación, sin embargo, comienza a alterarse de forma acelerada en múltiples lugares del planeta. La presencia de un entorno geoestratégico más complejo y la aproximación crítica de muchos Estados hacia la globalización y lo que ella significa, está consolidando una visión más cautelosa hacia la libre circulación de inversiones extranjeras que, entre otros efectos, se plasma en la elaboración de normativas más restrictivas. La Unión Europea es un espacio económicamente integrado, muy abierto a las inversiones extranjeras y dotado además, de una po…
Diffusion and outgassing of O<inf>2</inf> in amorphous SiO<inf>2</inf> silica nanoparticles with specific surface properties
2014
Self-limiting and complete oxidation of silicon nanostructures produced by laser ablation in water
2016
Oxidized Silicon nanomaterials produced by 1064 nm pulsed laser ablation in deionized water are investigated. High-resolution transmission electron microscopy coupled with energy dispersive X-ray spectroscopy allows to characterize the structural and chemical properties at a sub-nanometric scale. This analysis clarifies that laser ablation induces both self-limiting and complete oxidation processes which produce polycrystalline Si surrounded by a layer of SiO2 and amorphous fully oxidized SiO2, respectively. These nanostructures exhibit a composite luminescence spectrum which is investigated by time-resolved spectroscopy with a tunable laser excitation. The origin of the observed luminescen…
Al-27 and Si-29 Solid-State NMR Characterization of Calcium-Aluminosilicate-Hydrate
2012
International audience; Calcium silicate hydrate (C-S-H) is the main constituent of hydrated cement paste and determines its cohesive properties. Because of the environmental impact of cement industry, it is more and more common to replace a part of the clinker in cement by secondary cementitious materials (SCMs). These SCMs are generally alumina-rich and as a consequence some aluminum is incorporated into the C-S-H. This may have consequences on the cohesion and durability of the material, and it is thus of importance to know the amount and the location of Al in C-S-H and what the parameters are that control these features. The present paper reports the Si-29 and Al-27 MAS NMR analyses of …
Molecular dynamics simulation of epitaxial growth of the Si(001) surface
1988
Abstract Molecular beam epitaxy on a Si(100) substrate has been studied using a molecular dynamics method with the Stillinger-Weber model potential. At high substrate temperature, 800 K, well ordered crystalline layers are found to grow underneath an amorphous overlayer of approximately 5 A thick. A limiting temperature for epitaxial growth is found to be 480 K, below which the growth does not produce ordered layers. When the sample deposited below 480 K is heated up to 800 K and the deposition is started again the original adatoms start to form ordered atomic layers. Thus the collisions of the deposited atoms in addition to the substrate temperature seem to play an essential role in the gr…
Role of the strain in the epitaxial regrowth rate of heavily doped amorphous Si films
2008
Solid phase epitaxial regrowth (SPER) of p -doped preamorphized Si was studied by time resolved reflectivity. Strain and dopant concentration were opportunely varied by implanting neutral (Ge) and isovalent (B, Ga) impurities in order to disentangle the two different effects on SPER. Larger SPER rate variations occurred in strained doped Si with respect to undoped samples. The generalized Fermi level shifting model was implemented to include the role of the strain and to fit the experimental data over a large range of temperature for p - and n -type doping. We introduced a charged defect, whose energy level is independent of the dopant species. © 2008 American Institute of Physics.