Search results for "Solid"
showing 10 items of 3575 documents
Influence of total solids concentration on membrane permeability in a submerged hollow-fibre anaerobic membrane bioreactor.
2012
The main aim of this work was to study the influence of the mixed liquor total solids (MLTS) concentration on membrane permeability (K 20) in a submerged anaerobic membrane bioreactor (SAnMBR) pilot plant, which is equipped with industrial hollow-fibre membranes and treats urban wastewater. This pilot plant was operated at 33°C and 70 days of SRT. Two different transmembrane fluxes (13.3 and 10 LMH) were tested with a gas sparging intensity of 0.23 Nm 3 m -2 h -1 (measured as Specific Gas Demand referred to membrane area). A linear dependence of K 20 on MLTS concentration was observed within a range of MLTS concentration from 13 to 32 g L -1 and J 20 of 10 LMH. K 20 was maintained at sustai…
Fe-periclase reactivity at Earth's lower mantle conditions: Ab-initio geochemical modelling
2017
Intrinsic and extrinsic stability of the (Mg, Fe) O solid mixture in the Fe-Mg-Si-O system at high P, T conditions relevant to the Earth's mantle is investigated by the combination of quantum mechanical calculations (Hartree-26 Fock/DFT hybrid scheme), cluster expansion techniques and statistical thermodynamics. Iron in the (Mg, Fe) O binary mixture is assumed to be either in the low spin (LS) or in the high spin (HS) state. Un-mixing at solid state is observed only for the LS condition in the 23-42 GPa pressure range, whereas HS does not give rise to un-mixing. LS (Mg, Fe) O un-mixings are shown to be able to incorporate iron by subsolidus reactions with a reservoir of a virtual bridgmanit…
Iridium(III) Complexes with Phenyl-tetrazoles as Cyclometalating Ligands
2014
Ir(II) cationic complexes with cyclometalating tetrazolate ligands were prepared for the first time, following a two-step strategy based on (i) a silver-assisted cyclometalation reaction of a tetrazole derivative with IrCl3 affording a bis-cyclometalated solvato-complex P ([Ir(ptrz)(2)(CH3CN)(2)](+), Hptrz = 2-methyl-5-phenyl-2H-tetrazole); (ii) a substitution reaction with five neutral ancillary ligands to get [Ir(ptrz)(2)L](+), with L = 2,2'-bypiridine (1), 4,4'-di-tert-butyl-2,2'-bipyridine (2), 1,10-phenanthroline (3), and 2-(1-phenyl-1H-1,2,3-triazol-4-yl)pyridine (4), and [Ir(ptrz)(2)L-2](+), with L = tertbutyl isocyanide (5). X-ray crystal structures of P, 2, and 3 were solved. Elect…
Phase behavior of metals at very high P–T conditions: A review of recent experimental studies
2006
Studies at extreme pressures and temperatures are helpful for understanding the physical properties of the solid state, including such classes of materials as, metals, semiconductors, superconductors, or minerals. In particular, the phase behavior of metals at extreme pressures and temperatures is a challenging problem with many implications for other fields including Earth and planetary sciences. However, despite the efforts performed, the phase behavior of metals at very high pressures (HPs) and temperatures has been proven hard to predict accurately and only a limited number of experimental methods for making measurements in the regime of megabar pressures and thousand degree temperature…
Electromagnetic behaviour of superconductive amorphous metals
2005
The penetration depth of the magnetic field into an amorphous superconductor is calculated. The ratio of the London penetration depth δL to the electron free path le under zero temperature is above unity for almost all amorphous metals. That is why pure metals, in a superconducting state, change from type I superconductors to type II superconductors during the crystalline–amorphous transition.
The effect of Fe doping on superconductivity in ZrRuP
2011
Abstract This work reports the structure and superconducting properties of the superconductor ZrRuP doped with Fe; the ZrRu 1− x Fe x P solid solution was investigated by means of X-ray powder diffraction, SQUID magnetometry and Mosbauer spectroscopy. It is shown that the modification of the superconducting properties by doping with Fe is similar to the effect of chemical pressure and that the Fe doped compounds do not show any magnetic ordering.
Quantum Criticality of Heavy-Fermion Compounds
2014
Chapter 17 is devoted to the quantum criticality of quantum spin liquids. In this chapter we continue to consider the nature of quantum criticality in HF compounds. The quantum criticality induced by the fermion condensation quantum phase transition extends over a wide range in the \(T-B\) phase diagram. As we shall see, the quantum criticality in all such different HF compounds, as high-\(T_c\) superconductors, HF metals, compounds with quantum spin liquids, quasicrystals, and 2D quantum liquids, is of the same nature. This challenging similarity between different HF compounds expresses universal physics that transcends the microscopic details of the compounds. This uniform behavior, induc…
Magnetoresistance in the HF Metal at Zero Temperature
2014
In this chapter we consider the paradoxical behavior of the residual resistivity \(\rho _0\) of HF metals in magnetic fields and under pressure. Our consideration is based on the idea of flattening of the single-particle spectrum \(\varepsilon (\mathbf{p})\) that profoundly effects on the specific heat \(C\), thermal expansion coefficient \(\alpha \) and magnetic susceptibility \(\chi \) in the normal state, the jump of \(C\) at the point of superconducting phase transition etc. We show that FC associated with flat bands contributes to the residual resistivity \(\rho _0\), while the application of the magnetic field or pressure to the system with a flat band removes the flat band and leads …
Ag/(Bi, Pb)-Sr-Ca-Cu-O superconducting tape processing: Solid state chemistry aspects
1993
Abstract Different preparation methods have been used to obtain starting powders used in the fabrication of composite tapes by the powder-in-tube method. The effect of these distinct starting powders on the superconducting properties of Ag/Bi-Sr-Ca-Cu-O monofilament tapes has been investigated. The changes in the physical properties, including the critical current density at 77 K and ac magnetic susceptibility, and microstructure, using optical and electronic microscopy, have been analyzed in relation to the solid state reactions involved in the Bi 2 Sr 2 CaCu 2 O 8+δ and Bi 2 Sr 2 Ca 2 Cu 3 O 10+δ phase transformations.