Search results for "Solubility"

showing 10 items of 681 documents

Effect of artificial shading on the tannin accumulation and aromatic composition of the Grillo cultivar (Vitis vinifera L.)

2013

Abstract Background White wine quality, especially in warm climates, is affected by sunlight and heat stress. These factors increase the probability that ambering processes will occur and reduce the potential flavour compounds. This study aimed to investigate the effect of sunlight reduction on the accumulation of polyphenolic and aromatic compounds. Results This study was conducted in a commercial vineyard containing V. vinifera L. cv Grillo. Opaque polypropylene boxes (100% shading) and high-density polyethylene (HDPE) net bags (50% shading) were applied at fruit set. The effect of the shaded treatments was compared to the exposed fruit treatment. The shaded treatments resulted in heavier…

GlycosylationFlavourPlant ScienceBiologyHydrocarbons AromaticCatechinsFlavour compoundsBotanyTanninProanthocyanidinsVitisCultivarchemistry.chemical_classificationTerpenesfungiTemperaturefood and beveragesSunlight Temperature Catechins Proanthocyanidins Flavour compoundsSettore AGR/03 - Arboricoltura Generale E Coltivazioni ArboreeSolubilityProanthocyanidinchemistryPolyphenolWhite WineFruitSunlightComposition (visual arts)ShadingTanninsResearch ArticleBMC Plant Biology
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Induction and tolerization of anti-male CD8+ cytotoxic T lymphocytes by in vivo immunization with an H-Y-derived peptide

1999

Abstract We have analyzed the immune response induced by a 9mer synthetic peptide derived from the male histocompatibility antigen H-Y and containing D b -binding motifs in C57BL/6 mice. In this study we report that a single, subcutaneous injection of the peptide emulsified in IFA gave rise to the development of male-specific CD8 + T cells which displayed H-Y-specific proliferative response in vitro and showed a Tc1-type pattern of cytokine production (i.e. they secreted IFN-γ and IL-2, but not IL-4 and IL-10). Development of a strong cytotoxic activity required in vitro stimulation with specific peptide and IL-2: under these culture conditions, we were able to generate potent CD8 + CTLs th…

Graft RejectionMaleTime Factorsmedicine.medical_treatmentH-Y AntigenImmunologyPeptideBiologyMajor histocompatibility complexMiceImmune systemAntigenOsmotic PressuremedicineAnimalsImmunology and AllergyCytotoxic T cellH-Y antigenchemistry.chemical_classificationSkin TransplantationGeneral MedicineMolecular biologyMice Inbred C57BLCytokineSolubilitychemistryImmunologybiology.proteinFemalePeptidesCD8T-Lymphocytes CytotoxicHuman Immunology
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Solubility and microstructural development of TiO2-containing 3Al2O3·2SiO2 and 2Al2O3·SiO2 mullites obtained from single-phase gels

2007

Abstract The interdependence of the titanium oxide amount and the anisotropic growth of mullites prepared from single-phase gels were investigated. Gels with stoichiometries 3(Al2−xTixO3)·2(SiO2) and 2(Al2−xTixO3)·(SiO2), with 0 ≤ x ≤ 0.15 were prepared by the semialkoxide method. Gels and specimens heated at temperatures between 1200 and 1600 °C were characterized by using infrared spectroscopy (IR), X-ray diffraction (XRD) and transmission and field emission scanning electron microscopies (TEM and FESEM). Al2TiO5 as minor impurity was detected in both series of mullites for gel precursor compositions x = 0.10 and x = 0.15, obtained at temperatures between 1200 and 1600 °C. Variations of l…

Grain growthMaterials scienceImpurityScanning electron microscopeMaterials ChemistryCeramics and CompositesAnalytical chemistryMineralogyInfrared spectroscopyMulliteSolubilityStoichiometryTitanium oxideJournal of the European Ceramic Society
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Compatibility of surfactants with activated-persulfate for the selective oxidation of PAH in groundwater remediation

2017

Abstract Surfactants foam technology can improve the in situ remediation of hydrophobic organic contaminants by enhancing their solubility and the delivery of remediation chemicals. However, the presence of surfactants may impair the effectiveness of the selective oxidation of those contaminants. To tackle the issue, kinetics and selectivity of phenanthrene (PHE) oxidation in aqueous suspensions and its affecting factors including surfactant concentration (CS) and nature, temperature and persulfate (PS) concentration were studied. Significant differences in selectivity were observed between surfactants, reflecting Coulomb interactions with the anionic oxidizers. Lauryl Betaine (LB) stood ou…

Groundwater remediation02 engineering and technology010501 environmental sciences01 natural sciencesMicellechemistry.chemical_compoundReaction rate constantChemical Engineering (miscellaneous)[CHIM]Chemical SciencesSolubilityWaste Management and DisposalComputingMilieux_MISCELLANEOUS0105 earth and related environmental sciences[SDE.IE]Environmental Sciences/Environmental EngineeringProcess Chemistry and TechnologyPhenanthrene021001 nanoscience & nanotechnologyPersulfatePollution6. Clean waterPhthalic acidchemistry13. Climate actionCritical micelle concentration0210 nano-technologyNuclear chemistry
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Isolation of carcinoembryonic antigen N-terminal domains (N-A1) from soluble aggregates

2011

Abstract Carcinoembryonic antigen (CEA) was identified as a prominent tumor-associated antigen in human colorectal cancer and it is still intensively investigated. However, its physiological role remains unclear. The CEA molecule is composed of seven highly hydrophobic, immunoglobulin-like domains, six of which contain a single disulphide bridge. The production of recombinant protein containing Ig-like domains in bacterial expression systems often results in partial degradation or insolubility due to aggregation hampering the analysis of their native structure and function. Here, we present a new method of expression and purification of CEA N-terminal domains (N-A1) fused to MBP in Escheric…

Guanidinium chlorideCircular dichroismRecombinant Fusion Proteinsmedicine.disease_causeMaltose-Binding Proteinslaw.inventionchemistry.chemical_compoundCarcinoembryonic antigenlawProtein purificationEscherichia colimedicineTEV proteaseHumansDisulfidesEscherichia coliGuanidinebiologyProtein StabilityCircular DichroismFusion proteinCarcinoembryonic AntigenProtein Structure TertiarySolubilitychemistryBiochemistryChromatography GelRecombinant DNAbiology.proteinElectrophoresis Polyacrylamide GelBiotechnologyProtein Expression and Purification
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Inorganic Polyphosphate in Human Osteoblast-like Cells

1998

Significant amounts of inorganic polyphosphates and of polyphosphate-degrading exopolyphosphatase activity were detected in human mandibular-derived osteoblast-like cells. The amount of both soluble and insoluble long-chain polyphosphate in unstimulated osteoblast-like cells was higher than in human gingival cells, erythrocytes, peripheral blood mononuclear cells, and human blood plasma. The cellular content of polyphosphate in osteoblast-like cells strongly decreased after a combined treatment of the cells with the stimulators of osteoblast proliferation and differentiation, dexamethasone, beta-glycerophosphate, epidermal growth factor, and ascorbic acid. The amount of soluble long-chain p…

HL60Endocrinology Diabetes and MetabolismHL-60 CellsMandibleBiologyDexamethasonechemistry.chemical_compoundCalcitriolPolyphosphatesEpidermal growth factormedicineAnimalsHumansOrthopedics and Sports MedicinePyrophosphatasesCells CulturedExopolyphosphataseOsteoblastsDiphosphonatesEpidermal Growth FactorPolyphosphateCell DifferentiationEtidronic AcidOsteoblastAlkaline PhosphataseAscorbic acidAcid Anhydride HydrolasesRatsInorganic Pyrophosphatasemedicine.anatomical_structureSolubilitychemistryBiochemistryCell cultureGlycerophosphatesAlkaline phosphataseCell DivisionJournal of Bone and Mineral Research
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Synthesis of fluorinated oxadiazoles with gelation and oxygen storage ability

2012

A new family of fluorinated low molecular weight (LMW) gelators has been synthesized through SNAr substitution of 5-polyfluoroaryl-3-perfluoroheptyl-1,2,4-oxadiazoles with glycine ester. The obtained compounds give thermal and pH-sensitive hydrogels or thermo-reversible organogels in DMSO. Oxygen solubility studies showed the ability to maintain high oxygen levels in solution and in gel blend with plate counter agar (PCA).

HalogenationOxygen storageGlycinechemistry.chemical_elementBiochemistryPhase TransitionNucleophilic aromatic substitutionOrganic chemistryDimethyl SulfoxidePhysical and Theoretical ChemistrySolubilityOxadiazolesHydrogen bondChemistryOrganic ChemistryHalogenationEstersHydrogen BondingFluorineSettore CHIM/06 - Chimica OrganicaHydrogen-Ion ConcentrationMolecular WeightOxygenSolubilityGlycineSelf-healing hydrogelsFluorineMicroscopy Electron Scanninglow molecular weight gelators(LMWG) oxadiazoles fluorinated compounds oxgyen carriersThermodynamicsGels
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Mathematical modeling of oral absorption and bioavailability of a fluoroquinolone after its precipitation in the gastrointestinal tract

2013

The objective was to characterize the in vivo absorption and bioavailability (BA) of a low solubility, high permeability fluoroquinolone (CNV97101) that precipitates in the gastrointestinal (GI) tract by mathematical modeling approach. In situ rat intestinal perfusion studies were performed to characterize the absorption mechanism. The oral fraction absorbed in vivo was lower than the predicted based on the in situ intestinal permeability. Two additional routes of administration, intraduodenal (ID) and intraperitoneal (IP) were investigated to explore if precipitation in stomach and subsequent partial re-dissolution were the causes of the lower in vivo BA. Ex vivo precipitation studies with…

Health Toxicology and MutagenesisAdministration OralBiological AvailabilityPharmacologyToxicologyBiochemistryPermeabilityIntestinal absorptionPharmacokineticsCiprofloxacinIn vivomedicineAnimalsChemical PrecipitationChromatography High Pressure LiquidPharmacologyGastrointestinal tractIntestinal permeabilityChemistryStomachGeneral MedicineHydrogen-Ion ConcentrationModels Theoreticalmedicine.diseaseRatsBioavailabilityGastrointestinal Tractmedicine.anatomical_structureIntestinal AbsorptionNonlinear DynamicsSolubilityEx vivoFluoroquinolonesXenobiotica
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Effects of Dissolved Organic Material on Binding and Toxicokinetics of Pyrene in the Waterflea Daphnia magna

2001

The binding and bioavailability of pyrene was studied in the laboratory in two humic fresh waters and in a reference water without dissolved organic material (DOM), measured as dissolved organic carbon (DOC). The uptake of pyrene by Daphnia magna in short-term (24 h) accumulation experiments was fitted to a first-order rate-kinetic equation to calculate simultaneous uptake and elimination rates. The partition coefficients of pyrene to DOC (KDOC) were 37.1 x 103 in Pielisjoki River (9.4 mg DOC L(-1)), and 34.9 x 103 in Lake Kontiolampi (17.4 mg DOC L(-1)) waters, indicating similar binding affinities of pyrene for both humic waters. The uptake clearance of pyrene (ku) in the DOC-rich Lake Ko…

Health Toxicology and MutagenesisDaphnia magnaBiological AvailabilityBioconcentrationToxicologychemistry.chemical_compoundDissolved organic carbonAnimalsEcotoxicologyTissue DistributionOrganic matterOrganic ChemicalsWater pollutionFluorescent Dyeschemistry.chemical_classificationPyrenesbiologyChemistryGeneral Medicinebiology.organism_classificationPollutionBioavailabilityDaphniaSolubilityEnvironmental chemistryPyreneWater Pollutants ChemicalArchives of Environmental Contamination and Toxicology
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Possible role of human interleukin-6 and soluble interleukin-6 receptor in hepatitis B virus infection

2001

Human interleukin-6 has been shown to promote hepatitis B virus (HBV) infection. However, it is not clear whether this influence is the result of a direct interaction between interleukin-6 (IL-6) and the HBV envelope proteins or of a rather indirect mechanism. A direct interaction of IL-6 and the preS region of the large envelope protein (L-protein) of HBV has been reported. In this study we assessed the binding of IL-6 and of the IL-6 receptor subunits to the preS region of the L-protein of HBV. Binding of IL-6 and IL-6 receptor subunits sIL-6R and gp130 to preS was assessed by immunoprecipitation with recombinant preS proteins. In patient sera IL-6 and sIL-6R concentrations were analysed …

Hepatitis B virusmedicine.disease_causeHepatitis B virus PRE betalaw.inventionHepatitis B ChroniclawVirologyEscherichia colimedicineAnimalsHumansProtein PrecursorsInterleukin 6ReceptorCells CulturedHepatitis B virusHepatitis B Surface AntigensHepatologybiologyInterleukin-6Chemistryvirus diseasesViral LoadHepatitis BGlycoprotein 130medicine.diseasePrecipitin TestsReceptors Interleukin-6VirologyMolecular biologyRecombinant ProteinsInfectious DiseasesSolubilityCOS CellsRecombinant DNAbiology.proteinViral loadCell DivisionPlasmidsJournal of Viral Hepatitis
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