Search results for "Solution"

Novel solutions for closed-loop Reverse Electrodialysis: thermodynamic characterisation and perspective analysis

2019

Abstract Closed-loop Reverse Electrodialysis is a novel technology to directly convert low-grade heat into electricity. It consists of a reverse electrodialysis (RED) unit where electricity is produced exploiting the salinity gradient between two salt-water solutions, coupled with a regeneration unit where waste-heat is used to treat the solutions exiting from the RED unit and restore their initial composition. One of the most important advantages of closed-loop systems compared to the open systems is the possibility to select ad-hoc salt solutions to achieve high efficiencies. Therefore, the properties of the salt solutions are essential to assess the performance of the energy generation a…

Effect of the reference solution in the measurement of ion activity coefficients using cells with transference at T=298.15K

2010

Abstract This work reports individual activity coefficients of ions at T = 298.15 K in aqueous solutions obtained from voltage values of the respective half-cell ion-selective-electrode and a single-junction Ag–AgCl reference electrode, filled with different reference solutions at different concentrations. For potassium and chloride ions in KCl aqueous solutions, reference solutions of KCl, NaCl, or CsCl were used. For sodium and chloride ions in aqueous NaCl solutions, reference solutions of CsCl were used. Experimental runs were performed at molalities (1, 2, and 3) m of the reference solution. The concentration of the sample solution was increased, starting from around 1 · 10−3 m, up to …

Thermodynamic properties of N-octyl- and N-dodecylnicotinamide chlorides in water

1990

Densities, heat capacities and enthalpies of dilution at 25°C and osmotic coefficients at 37°C were measured for N-octyl- and N-dodecylnicotinamide chlorides in water over an extended concentration region. Partial molar volumes, heat capacities, relative enthalpies and nonideal free energies and entropies at 25°C were derived as a function of the surfactant concentration. For both surfactants, plots of volumes, enthalpies and free energies vs. concentration are regular whereas those of heat capacities and entropies present anomalies at about 0.8 and 0.1m for the octyl and dodecyl compounds, respectively. Changes in the slope of a plot of osmotic coefficients times molality vs. molality were…

Binding of basic amphipathic peptides to neutral phospholipid membranes: a thermodynamic study applied to dansyl-labeled melittin and substance P ana…

1997

A thermodynamic approach is proposed to quantitatively analyze the binding isotherms of peptides to model membranes as a function of one adjustable parameter, the actual peptide charge in solution z(p)+. The main features of this approach are a theoretical expression for the partition coefficient calculated from the molar free energies of the peptide in the aqueous and lipid phases, an equation proposed by S. Stankowski [(1991) Biophysical Journal, Vol. 60, p. 341] to evaluate the activity coefficient of the peptide in the lipid phase, and the Debye-Huckel equation that quantifies the activity coefficient of the peptide in the aqueous phase. To assess the validity of this approach we have s…

Thermodynamic properties and conductivities of some dodecylsurfactants in water

1988

Densities, heat capacities, enthalpies of dilution, osmotic coefficients and conductivities are reported for dodecylamine hydrochloride, dodecyldimethylammonium and dodecyltrimethylammonium chloride in water over a wide range of concentration. The last two properties were also measured for dodecyltrimethylammonium bromide. From the thermodynamic data partial molar volumes, heat capacities and relative enthalpies and nonideal free energies and entropies were derived as a function of the surfactant concentration. The cmc's and degree of counterion dissociation were also calculated from the transport properties. It is shown that the trends of volumes, enthalpies, free energies and entropies ar…

The impact of in-canopy wind profile formulations on heat flux estimation in an open orchard using the remote sensing-based two-source model

2010

Abstract. For open orchard and vineyard canopies containing significant fractions of exposed soil (>50%), typical of Mediterranean agricultural regions, the energy balance of the vegetation elements is strongly influenced by heat exchange with the bare soil/substrate. For these agricultural systems a "two-source" approach, where radiation and turbulent exchange between the soil and canopy elements are explicitly modelled, appears to be the only suitable methodology for reliably assessing energy fluxes. In strongly clumped canopies, the effective wind speed profile inside and below the canopy layer can strongly influence the partitioning of energy fluxes between the soil and vegetation co…

Actual evapotranspiration assessment in a sparse tall Mediterranean crops

2010

Spatial sharpening of land surface temperature for daily energy balance applications

2008

ABSTRACT Daily high spatial resolution assessment of actual evapotranspiration is essential for water management and crop water requirement estimation under stress conditions. The application of energy balance models usually requires satellite observations of radiometric surface temperat ure with high geometrical and temporal resolutions. By now, however, high spatial resolution (~ 100 m) is available with low time fre quency (approximately every two weeks); at the opposite daily acquisition are characterised by poor spatial resolution. The analysis of vegetation index (VI) and land surface temperature (LST) spatial relationship, shows in substance a scale invariant behaviour [1] ; this con…

Evaluating actual evapotranspiration by means of multi-platform remote sensing data: A case study in Sicily

2007

During the last two decades, the scientific community developed detailed mathematical models for simulating land surface energy fluxes and crop evapotranspiration rates by means of an energy balance approach. These models can be applied in large areas and with a spatial distributed approach using surface brightness temperature and some ancillary data retrieved from satellite/airborne remote sensed imagery. In this paper a district scale application, in combination with multispectral satellite and airborne data has been carried out to test the potential of two different energy balance models to estimate evapotranspiration fluxes from a set of typical Mediterranean crops (wine, olive, citrus)…

Reaching professional skills with the Final Master Thesis: Collaboration towards actual solutions

2019

[EN] In order to motivate the student through a professional experience, and to improve the teaching-learning process by letting the student gain experience, we implement a collaborative learning-through-service methodology. This method increases the student involvement level and the deep understanding of the tools. As a matter of example, we present the implementation of this method in the Final Master Thesis (FMTh) of the Master on Corporate Finance at the University of Valencia (UV). In these FMTh, students have to valuate an actual innovation developed by UV researchers (on chemistry, in this case) with the goal of helping them to transfer (sell) this innovation to the industry. This co…