Search results for "Soot"

Composition and mixing state of the urban background aerosol in the Rhein-Main area (Germany)

2007

Abstract Size-resolved aerosol particle samples in the size range 0.1–10 μm aerodynamic diameter were collected in the years 2003 and 2004 at an urban background station in Mainz, Germany. Size, morphology, chemical composition and mixing state of more than 5400 individual particles of 7 selected sampling days were analyzed in detail by scanning electron microscopy and energy-dispersive X-ray microanalysis. In addition, transmission electron microscopy, aerosol mass spectrometry and atomic force microscopy were applied to obtain detailed information about the mixing state of the particles. The fine particle fraction (diameter 1 μm diameter) is strongly dependant on air mass history with var…

Transition Metal Compound Oxide Catalysts for Lowering the Light Off-Temperature of Particles from Diesel Exhaust

1993

Publisher Summary It has been realized that particle emissions from diesel engines are a severe environmental problem, which is difficult to solve by engine modifications alone. Even if the combustion occurs in a high excess of air, appreciable amounts of soot particles are found. Cracking processes, dehydrogenation, and polymerization play an important role in the formation of soot. To reduce soot fraction, several methods have been developed in the past, but most of them have fundamental disadvantages. Thus, a new procedure based on the catalytic burning of the soot in the exhaust gas is becoming important. This chapter describes the effect of several compound oxides. Further investigatio…

Airborne Measurements of Contrail Ice Properties—Dependence on Temperature and Humidity

2021

The largest share in the climate impact of aviation results from cirrus clouds. Here, the dependence of microphysical contrail ice properties and extinction on temperature and humidity is investigated. Contrail measurements were performed at various altitudes during the 2018 ECLIF II/NDMAX campaign with the NASA DC-8 chasing the DLR A320. Ice number concentrations and contrail extinction coefficients are largest at altitudes near 9.5 km, typical for short- and medium-range air traffic. At higher altitudes near 11.5 km, low ambient water vapor concentrations lead to smaller contrail particle sizes and lower extinction coefficients. In addition, contrails were detected below 8.2 km near the S…

Characterization of Diesel Soot by Sedimentation Field Flow Fractionation

1990

In Situ Observations of Ice Particle Losses in a Young Persistent Contrail

2018

We describe results of in situ observations of a 1 to 2-min old contrail in the vortex Phase generated from soot-rich exhaust (> 10^15 emitted soot particles per kg-fuel burned). Simultaneous measurements of soot (EIsoot) and apparent ice (AEIice) particle number emission indices show a pronounced anti-correlation in the vertical contrail profile. AEIice decrease by about 75% with increasing distance below the contrail-producing aircraft,while EIsoot increase by an equivalent relative fraction, therefore strongly suggesting sublimation causing the ice particle losses. Quantifying these losses in measurements helps to validate and improve contrail parameterizations used to estimate the clima…

Associations of black carbon with lung function and airway inflammation in schoolchildren

2019

Background: Few studies have investigated the 24-hour respiratory health effects of personal black carbon (BC) and ultrafine particles (UFP) exposure in schoolchildren. The objective of this study was to investigate these associations with the lung function in children 10-years old with and without persistent respiratory symptoms. Methods: We conducted a cross-sectional study in 305 children (147 and 158 with and without persistent respiratory symptoms, respectively) from three European birth-cohorts: PARIS (France) and INMA Sabadell and Valencia (Spain). Personal 24-hour measurements of exposure concentrations to BC and UFP were performed by portable devices, before lung function testing. …

Soot particle properties in the microwave range

1993

This paper outlines the study of Diesel soot particle properties in the frequency band 2.0-40.0 GHz. Using a transmission/reflection as well as a cavity perturbation method, the complex dielectric constant ?* = ?1 - j?2 was measured for multiple of samples (soot particles produced in a Diesel engine and deposited on paper filter). From the analysis of the experimental data the following conclusions appear: The complex dielectric constant - i.e. the HF electrical conductivity and the microwave power absorption efficiency - are dependent on the frequency and the soot particle thickness. Increasing the soot particle thickness causes the reflection to be stronger and results in less influence o…

Contrail ice particles in aircraft wakes and their climatic importance

2013

[1] Measurements of gaseous (NO, NOy, SO2, HONO) and ice particle concentrations in young contrails in primary and secondary wakes of aircraft of different sizes (B737, A319, A340, A380) are used to investigate ice particle formation behind aircraft. The gas concentrations are largest in the primary wake and decrease with increasing altitude in the secondary wake, as expected for passive trace gases and aircraft-dependent dilution. In contrast, the measured ice particle concentrations were found larger in the secondary wake than in the primary wake. The contrails contain more ice particles than expected for previous black carbon (soot) estimates. The ice concentrations may result from soot-…

Contrail Formation: Analysis of Sublimation Mechanisms

2018

We study losses of ice crystals in a persistent, soot-rich contra i l in the wake behind a medium-sized aircraft at cru i se. Constrain i n g a model covering ice nucleation, growth, and subl i m a t i o n phases with a n aircraft data set, we track the subl i m a t i o n history over two minutes of cont r a i l age and rela t e ice crystal numbers to the number of soot particles emitted by th e aircraft engines.

Soot-exposed mononuclear cells increase inflammatory cytokine mRNA expression and protein secretion in cocultured bronchial epithelial cells.

2000

<i>Background:</i> Soot particles are air pollutants capable of inducing airway and lung parenchymal injury. Mononuclear and bronchial epithelial cells are central to the maintenance of homeostasis and inflammation in the airways. <i>Objectives:</i> The aim of this study was to evaluate the contribution of mononuclear cells to the release of inflammatory mediators by bronchial epithelial cells. <i>Methods:</i> To model the in vivo situation, an in vitro system of cocultured blood monocytes and BEAS-2B cells was established in a transwell system. Blood monocytes were exposed to soot particles (FR 101) at concentrations of up to 100 μg/10<sup>6</su…