Search results for "Sorption"

Evidence of ice crystals at cloud top of Arctic boundary-layer mixed-phase clouds derived from airborne remote sensing

2009

Abstract. The vertical distribution of ice crystals in Arctic boundary-layer mixed-phase (ABM) clouds was investigated by airborne remote-sensing and in situ measurements during the Arctic Study of Tropospheric Aerosol, Clouds and Radiation (ASTAR) campaign in March and April 2007. Information on the spectral absorption of solar radiation by ice and liquid water cloud particles is derived from airborne measurements of solar spectral radiation reflected by these clouds. It is shown by calculation of the vertical weighting function of the measurements that the observed absorption of solar radiation is dominated by the upper cloud layers (50% within 200 m from cloud top). This vertical weighti…

Black and brown carbon over central Amazonia: long-term aerosol measurements at the ATTO site

2018

The Amazon rainforest is a sensitive ecosystem experiencing the combined pressures of progressing deforestation and climate change. Its atmospheric conditions oscillate between biogenic and biomass burning (BB) dominated states. The Amazon further represents one of the few remaining continental places where the atmosphere approaches pristine conditions during occasional wet season episodes. The Amazon Tall Tower Observatory (ATTO) has been established in central Amazonia to investigate the complex interactions between the rainforest ecosystem and the atmosphere. Physical and chemical aerosol properties have been analyzed continuously since 2012. This paper provides an in-depth analysis of t…

2016

Abstract. Scanning spectrometer networks using scattered solar radiation in the ultraviolet spectral region have become an increasingly important tool for monitoring volcanic sulfur dioxide (SO2) emissions. Often measured spectra are evaluated using the differential optical absorption spectroscopy (DOAS) technique. In order to obtain absolute column densities (CDs), the DOAS evaluation requires a Fraunhofer reference spectrum (FRS) that is free of absorption structures of the trace gas of interest. For measurements at volcanoes such a FRS can be readily obtained if the scan (i.e. series of measurements at different elevation angles) includes viewing directions where the plume is not seen. I…

Influence of clouds on the spectral actinic flux density in the lower troposphere (INSPECTRO): overview of the field campaigns

2008

Ultraviolet radiation is the key factor driving tropospheric photochemistry. It is strongly modulated by clouds and aerosols. A quantitative understanding of the radiation field and its effect on photochemistry is thus only possible with a detailed knowledge of the interaction between clouds and radiation. The overall objective of the project INSPECTRO was the characterization of the three-dimensional actinic radiation field under cloudy conditions. This was achieved during two measurement campaigns in Norfolk (East Anglia, UK) and Lower Bavaria (Germany) combining space-based, aircraft and ground-based measurements as well as simulations with the one-dimensional radiation transfer model UV…

Contrast in column-integrated aerosol optical properties during heating and non-heating seasons at Urumqi — Its causes and implications

2017

Abstract Aerosol optical properties were retrieved from two years' worth of Sunphotometer measurements at Urumqi, an urban station in western China. Distinct seasonal variations of aerosol optical properties were revealed. During the heating season, mean aerosol optical depth at 550 nm (τ a ), Angstrom exponent calculated from aerosol optical depth at wavelength of 440 and 870 nm (α) as well as PM 2.5 concentration were 0.58 ± 0.33, 1.11 ± 0.34 and 79.5 ± 69.6 μg m − 3 , respectively, which contrasted their counterparts during the non-heating season of 0.32 ± 0.22, 0.79 ± 0.26, and 35.0 ± 20.1 μg m − 3 . Seasonal variations of τ a and PM 2.5 at Urumqi contrasted with corresponding values in…

Determination and analysis of in situ spectral aerosol optical properties by a multi-instrumental approach

2014

Continuous in situ measurements of aerosol optical properties were conducted from 29 June to 29 July 2012 in Granada (Spain) with a seven-wavelength Aethalometer, a Multi-Angle Absorption Photometer, and a three-wavelength integrating nephelometer. The aim of this work is to describe a methodology to obtain the absorption coefficients (babs) for the different Aethalometer wavelengths. In this way, data have been compensated using algorithms which best estimate the compensation factors needed. Two empirical factors are used to infer the absorption coefficients from the Aethalometer measurements: C – the parameter describing the enhancement of absorption by particles in the filter matrix due …

In situ detection of atomic and molecular iodine using resonance and off-resonance fluorescence by lamp excitation: ROFLEX

2018

17 pags, 11 figs, 4 tabs

Validation of a novel automatic deposition of bacteria and yeasts on MALDI target for MALDI-TOF MS-based identification using MALDI Colonyst robot

2017

Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) -based identification of bacteria and fungi significantly changed the diagnostic process in clinical microbiology. We describe here a novel technique for bacterial and yeast deposition on MALDI target using an automated workflow resulting in an increase of the microbes' score of MALDI identification. We also provide a comparison of four different sample preparation methods. In the first step of the study, 100 Gram-negative bacteria, 100 Gram-positive bacteria, 20 anaerobic bacteria and 20 yeasts were spotted on the MALDI target using manual deposition, semi-extraction, wet deposition onto 70% formic …

2011

Abstract. The detection of primary biological material in submicron aerosol by means of thermal desorption/electron impact ionization aerosol mass spectrometry was investigated. Mass spectra of amino acids, carbohydrates, small peptides, and proteins, all of which are key building blocks of biological particles, were recorded in laboratory experiments. Several characteristic marker fragments were identified. The intensity of the marker signals relative to the total organic mass spectrum allows for an estimation of the content of primary biological material in ambient organic aerosol. The developed method was applied to mass spectra recorded during AMAZE-08, a field campaign conducted in the…

The optical constants of atmospheric aerosol particles in the 7.5–12 ?m spectral region

2011

Thin films of atmospheric aerosol particles which have been collected by an automatic jet impactor are used to obtain the real and imaginary part of the mean complex refractive index of aerosol particles of various types in the 7.5–12 ?m spectral region. A dispersion analysis of the measured ir-spectra of absorption of the particle films is performed. By applying the Lorentz theory of continuous dielectrics to the particle films a mathematical relation between the optical constants of the particle films and those of the aerosol particles themselves is obtained. The resulting complex refractive indices are applied to Mie computations to indicate the importance of scattering and absorbing aer…