Search results for "Specific Heat"
showing 10 items of 21 documents
Specific Heat of Amorphous Silica within the Harmonic Approximation
1999
We investigate to what extent the specific heat of amorphous silica can be calculated within the harmonic approximation. For this we use molecular dynamics computer simulations to calculate, for a simple silica model (the BKS potential), the velocity autocorrelation function and hence an effective density of states g(ν). We find that the harmonic approximation is valid for temperatures below 300 K but starts to break down at higher temperatures. We show that, to obtain a reliable description of the low-frequency part of g(ν), i.e., where the boson peak is observed, it is essential to use large systems for the simulations and small cooling rates to quench the samples. We find that the calcul…
Observation of random-field behavior in (CO)1−x(N2)xmixtures physisorbed on graphite
1993
Heat-capacity studies have been carried out on submonolayers of (CO${)}_{1\mathrm{\ensuremath{-}}\mathit{x}}$(${\mathrm{N}}_{2}$${)}_{\mathit{x}}$ mixtures physisorbed on graphite. We find that pure CO undergoes an end-to-end ordering transition at ${\mathit{T}}_{\mathit{c}}$=5.18 K, which is shown to belong to the two-dimensional Ising universality class. In diluting CO with ${\mathrm{N}}_{2}$ the heat-capacity peaks become progressively rounded until the phase transition is completely suppressed at a ${\mathrm{N}}_{2}$ concentration of only x=0.07. The analysis of the data shows that this behavior is in quantitative agreement with predictions of the random-field theory applied to adsorbed…
The impact of thermophysical properties and hysteresis effects on the energy performance simulation of PCM wallboards: Experimental studies, modellin…
2020
Abstract This paper presents a combined experimental and numerical procedure, developed to test the thermophysical behaviour of a real scale PCM wallboard, aiming at providing reliable data for the validation of building energy performance simulation tools. Data obtained from two experimental tests, conducted on real building elements integrating PCM undergoing complete and incomplete phase change, are considered for assessing the impact of thermal properties and hysteresis. A comprehensive comparative numerical analysis, performed by means of an in-house developed simulation tool, called DETECt, is carried out to investigate the reliability of several modelling and simulation approaches av…
The classical statistical mechanics of Frenkel-Kontorova models
1995
The scaling properties of the free energy, specific heat, and mean spacing are calculated for classical Frenkel-Kontorova models at low temperature, in three regimes: near the integrable limit, the anti-integrable limit, and the sliding-pinned transition (“transition by breaking of analyticity”). In particular, the renormalization scheme given in previous work for ground states of Frenkel-Kontorova models is extended to nonzero-temperature Gibbs states, and the hierarchical melting phenomenon of Vallet, Schilling, and Aubry is put on a rigorous footing.
Exact solution of the 1D Hubbard model in the atomic limit with inter-site magnetic coupling
2012
In this paper we present for the first time the exact solution in the narrow-band limit of the 1D extended Hubbard model with nearest-neighbour spin-spin interactions described by an exchange constant J. An external magnetic field h is also taken into account. This result has been obtained in the framework of the Green's functions formalism, using the Composite Operator Method. By means of this theoretical background, we have studied some relevant features such as double occupancy, magnetization, spin-spin and charge-charge correlation functions and derived a phase diagram for both ferro (J>0) and anti-ferro (J<0) coupling in the limit of zero temperature. We also report a study on de…
Oscillations in the dynamics of temperature-driven phase separation
1997
We examine the dynamics of the phase separation of a single phase of water-in-oil microemulsion droplets towards a phase of smaller droplets coexisting with a water-rich phase. Oscillations are observed in the turbidity of the mixture and in the specific heat, when this transition is induced by a continuous temperature increase. The oscillations indicate an unusual type of dynamics which involves an energy barrier only to be overcome by a large number of droplets collectively. It is due to the spontaneous curvature of the water-oil-interface, and conservation of volumes.
Performance Enhancement of Vapour-Compression Refrigeration Systems Using Nanoparticles: An Experimental Study
2021
In recent years, the development and characterization of new refrigerants with higher energetic efficiency have gained considerable interest [1], with a particular emphasis on the energetic performance of suitable replacements. Nanofluids have been proposed as possible alternative due to their role in enhancing the thermophysical proprieties of traditional refrigerants [2]. The comprehensive review in [2] suggests that thermal conductivity of nanofluid increases with temperature and volume concentration, but it is dependent on nanoparticle size distribution; specific heat is also increased if nanoparticles are added to the refrigerant.
Thermal Parameters Measurements of High-Rise Building Envelope
2016
In buildings, to ensure the thermal comfort of the occupants and to keep the energy consumption as low as possible, a correct design of the thermal system is necessary. To do so, an appropriate determination of the thermo-physical properties of the wall materials is needed, particularly; new light-weight building technologies are widely used in the construction of the building envelope. One of these parameters, particularly important in Mediterranean climatic dynamic conditions is the heat capacity, due to the presence of the sun’s energy contribution in hot and cold seasons. The value of the heat capacity in such like materials is typically quite different from the declared parameter, obta…
A hybrid method for calorimetry with subnanoliter samples using Schottky junctions
2007
A μm-scale calorimeter realized by using Schottky junctions as a thermometer is presented. Combined with a hybrid experimental method, it enables simultaneous time-resolved measurements of variations in both the energy and the heat capacity of subnanoliter samples.
Low-temperature specific heat of orientational glasses
1992
This review summarizes specific heat data measured at low temperatures (T<1 K) on orientational glasses. Three species of mixed molecular crystals exhibiting orientational disorder are considered, namely (KBr)1−x (KCN) x , (NaCN)1−x (KCN) x (Rb)1−x (NH4) x H2PO4. For intermediate concentrations of the anisotropic components, glass-like excitations have been observed. It is demonstrated that with respect to thermal properties, orientational disorder leads to the same “universal” behaviours than for structural disorder, i.e. a specific heat which varies below 1 K and for times 10−4 s–10 s as:C p(T,t)∞T 1×ln(t). The variation of the glass-like anomaly with compositional disorder is also discus…