Search results for "Spectra"
showing 10 items of 3542 documents
Light Propagation in Heterogeneous Opal-Based Photonic Crystals
2006
Ballistic light propagation in the heterogeneous photonic crystals based on the thin triple-film opal have been studied in the wavelength range of low order photonic bandgaps. Since the scattered light experiences the diffraction attenuation, the spectra and the angle diagrams of the transmitted and forward scattered light have been used to identify the effect of heterostructuring.
Analysis of acousto-optic tunable filter performance for imaging applications
2010
Acousto-optic tunable filters (AOTFs) can be used as spec- tral filters in multispectral imaging applications. Acousto-optic crystals diffract a single wavelength from a broadband light beam, depending on the applied radio frequency signal. However, experimental measurements show that the actual performance is far from the expected behavior. We present an experimental characterization of several commercial off-the- shelf AOTFs for the implementation of multispectral imaging instruments. The diffraction performance of three bare crystals is compared, while a fourth AOTF crystal is mounted on the optical path of a multispectral im- ager to evaluate its performance. The experiments show that t…
X-ray diffraction, optical birefringence, and87Rb nuclear magnetic resonance spectroscopy of the paraelectric and antiferroelectric phases of Rb3DxH1…
2002
The antiferroelectric (AFE) phase transition of Rb3DxH1-x(SO4)2 was studied using x-ray diffraction, optical birefringence, and nuclear magnetic resonance. The orientation dependence of the resonance lines deduced from the quadrupole-perturbed 87Rb nuclear magnetic resonance of Rb3D(SO4)2 single crystals indicates slight deviations from the monoclinic symmetry in the paraelectric and the AFE phases. The dynamical critical exponents as deduced from measurements of the spin-lattice relaxation times depend on the deuteron concentration. Additionally, we have carried out x-ray single-crystal diffraction as well as optical birefringence measurements and find clear evidence for a structural phase…
New rotational levels in $^{186}$Re nucleus
2020
International audience; Excited levels of 186 Re have been studied using results of the single γ -ray spectra measurements following the thermal neutron capture reaction. Energies and intensities of more than 500 γ -transitions have been obtained with the high-resolution crystal diffraction spectrometer GAMS5 of ILL. Most of the obtained intense γ -transitions have been placed in the 186 Re level scheme. A number of new levels, as well as the depopulation for levels observed earlier in the 187 Re (p,d)186 Re reaction measurements have been proposed. Structure of 186 Re levels is interpreted in terms of two-quasiparticle plus rotor coupling model and compared with that of the neighbouring do…
Critical analysis of the spin-rotation constants of CF2 and CCl2: A theoretical investigation
2005
Quantum chemical ab initio calculations for the spin-rotation constants of difluorocarbene (CF2) and dichlorocarbene (CCl2) were carried out using coupled-cluster techniques with sequences of correlation-consistent basis sets. Theoretical best estimates were obtained using extrapolation to the complete basis-set limit and taking into account corrections for core correlation, additional diffuse functions and zero-point vibrational effects. It is demonstrated that such accurate theoretical estimates can be used either to support or to challenge the analysis of the experimental spectra and the reliability of the resulting data. 2005 Elsevier B.V. All rights reserved.
Electron paramagnetic resonance study of exchange coupled Ce3+ ions in Lu2SiO5 single crystal scintillator
2016
Abstract The Ce 3+ ions incorporation inside lutetium oxyorthosilicate (Lu 2 SiO 5 ) single crystals was studied by electron paramagnetic resonance. Already known Ce1 and Ce2 centers originating from the lattice peculiarity allowing two lutetium sites coordinated by different number of the oxygen ions were detected. Remarkably, for the Ce2 center, the determined g 2 tensor is asymmetric and could not be diagonalized as compared to the Ce1 center, for which the three principal values and corresponding axes orientation have been determined and reported previously. Besides, the much weaker resonance lines found in spectra close to those coming from the Ce1 and Ce2, and following them under cry…
Ab initio calculations for the far infrared collision induced absorption by N2 gas
2014
We present (far-infrared) Collision Induced Absorption (CIA) spectra calculations for pure gaseous N2 made for the first time, from first-principles. They were carried out using classical molecular dynamics simulations based on ab initio predictions of both the intermolecular potential and the induced-dipole moment. These calculations reproduce satisfactory well the experimental values (intensity and band profile) with agreement within 3% at 149 K. With respect to results obtained with only the long range (asymptotic) dipole moment (DM), including the short range overlap contribution improves the band intensity and profile at 149 K, but it deteriorates them at 296 K. The results show that t…
Use of the red-edge excitation effect for investigation of dielectric interactions in biomembranes
1999
Dipole moments of the fluorescent probes 1-phenylnaphthylamine (1-AN) and 1-anilinonaphthalene-8-sulfonate (1,8-ANS) are measured using electro-optical absorption and emission methods. Dipole moments in the ground and excited states were measured in cyclohexane and dioxane. It is shown that the charge distributions in the 1-AN and 1,8-ANS molecules differ substantially. The spectral dependence of the electro-optical coefficients suggests that the absorption spectrum of 1,8-ANS is due to a superposition of (at least two) electronic transitions. It is found that spectra of 1-AN in erythocyte ghosts are inhomogeneously broadened. The above effect makes it possible to selectively excite probe m…
A Theoretical Study of the Electronic Spectra of N9 and N7 Purine Tautomers
1999
The complete active space (CAS) SCF method and multiconfigurational second-order perturbation theory (CASPT2) have been used to study electronic spectra of the N(9)H and N(7)H tautomers of purine. The calculations include vertical excitation energies, oscillator strengths, dipole moments, and transition moment directions in gas phase. In accord with experiment in nonpolar solvents, the two lowest π → π* excited singlet valence states are predicted to be located at 4.7 and 5.1 eV. The latter is expected to shift to the red in aqueous solutions. A satisfactory interpretation of the electronic spectra above 5.5 eV is obtained if the experimental data are assumed to consist of the superposition…
On Boundary Value Problems for ϕ-Laplacian on the Semi-Infinite Interval
2017
The Dirichlet problem and the problem with functional boundary condition for ϕ-Laplacian on the semi-infinite interval are studied as well as solutions between the lower and upper functions.