Search results for "Spectra"
showing 10 items of 3542 documents
Stimulated Raman-Spectroscopy of the Q-Branch of Nitrogen at High Pressure - Collisional Narrowing and Shifting in the 150-6800 Bar Range at Room Tem…
1992
0026-8976; The Raman Q branch of N2 has been recorded at room temperature in the pressure range 150-6800 bar, which corresponds to densities from 135 to 800 amagat. In this domain, the Raman Q branch profile is mainly determined by the well-known collisional narrowing. The experimental data have been obtained by means of a high resolution stimulated Raman spectrometer. The linewidth and line shift of the band have been accurately measured as functions of the density, and their density dependences have been fitted by polynomials. The minimum of the linewidth and the maximum of the red shift have been clearly observed at respectively 735.8 and 532.3 amagat. The lineshape was found to be Loren…
Dynamics of myoglobin in confinement: An elastic and quasi-elastic neutron scattering study
2008
In order to clarify the role of hard confinement on protein dynamics, elastic and quasi-elastic neutron scattering experiments have been performed on ferric horse myoglobin in two different systems: the protein embedded in a porous silica matrix, and the corresponding hydrated protein powder. Elastic data have been analysed using two different models (dynamical heterogeneity and anharmonic double-well potential) that take into account deviations of elastic intensity from Gaussian behaviour. The profile of quasi-elastic spectra has been approximated by a combination of Lorentzian and Gaussian components. Comparison between the data relative to the two different samples indicates that geometr…
Periodic volcanic degassing behavior: The Mount Etna example
2013
[1] In contrast to the seismic and infrasonic energy released from quiescent and erupting volcanoes, which have long been known to manifest episodes of highly periodic behavior, the spectral properties of volcanic gas flux time series remain poorly constrained, due to a previous lack of hightemporal resolution gas-sensing techniques. Here we report on SO2 flux measurements, performed on Mount Etna with a novel UV imaging technique of unprecedented sampling frequency (0.5Hz), which reveal, for the first time, a rapid periodic structure in degassing from this target. These gas flux modulations have considerable temporal variability in their characteristics and involve two period bands: 40–250…
Investigating different skin and gastrointestinal tract (GIT) pathologies ex vivo by autofluorescence spectroscopy and optical imaging
2017
The skin neoplasias are on a second place in the world statistics of cancer incidence, and gastrointestinal tract (GIT) tumours are also in the “top ten” list. For the most of cutaneous and gastrointestinal tumours could be obtained better prognoses for patients, if an earlier and precise diagnostics procedure is applied. One of the most promising approaches for development of improved diagnostic techniques, is based on optical detection, and analysis of the signatures of biological tissues for detecting the presence of pathological alterations in the investigated objects. It is important to develop and combine novel diagnostic techniques for an accurate early stage diagnosis to improve the…
Rayleigh and Rice Channels
2011
This chapter contains sections titled: System Theoretical Description of Multipath Channels Formal Description of Rayleigh and Rice Channels Elementary Properties of Rayleigh and Rice Channels Statistical Properties of Rayleigh and Rice Channels Further Reading Appendix 3.A Derivation of the Jakes Power Spectral Density and the Corresponding Autocorrelation Function Appendix 3.B Derivation of the Autocorrelation Function of the Envelope Appendix 3.C Derivation of the Autocovariance Spectrum of the Envelope Under Isotropic Scattering Conditions Appendix 3.D Derivation of the Level‐Crossing Rate of Rice Processes with Different Spectral Shapes of the Underlying Gaussian Random Processes
Pairwise effects of chlorine substituents on the13C NMR chemical shifts of dichlorobicyclo[2.2.1]heptanes (norbornanes)
1984
The 13C NMR spectra of nine dichlorinated bicyclo[2.2.1]heptanes (norbornanes) have been measured and assigned. The pairwise effects of chlorine substituents which cause deviations from the additivity of single-substituent effects were investigated and are discussed. The largest effect found is the high-field shift of carbons bearing vicinal cis substituents. In the case of geminal substitution deviations from additivity were found to be to low field and large in the γ, smaller in the β and negligible in the α chemical shifts. The observed deviations for 1,3-disubstituted cases vary from −3.2 to +1.1 ppm at different carbons, allowing no simple explanation. Replacement of α-hydrogen in a di…
GUI Implementation of VCDtools, A Program to Analyze Computed Vibrational Circular Dichroism Spectra
2020
As computing power increases, vibrational circular dichroism (VCD) calculations on molecules of larger sizes and complexities become possible. At the same time, the spectra resulting from these computations become increasingly more cumbersome to analyze. Here, we describe the GUI implementation into the Amsterdam Density Functional (ADF) software package of VCDtools, a toolbox that provides a user-friendly means to analyze VCD spectra. Key features are the use of the generalized coupled oscillator analysis methods, as well as an easy visualization of the atomic electric and magnetic transition dipole moments which together provide detailed insight in the origin of the VCD intensity. Using s…
EPR investigations of polymeric and H2O2 -modified C3N4 -based photocatalysts
2019
The C3N4 -based nanopowders prepared by thermal condensation of melamine (MCN) with subsequent thermal etching (MCN-TE) and H2O2 -treatment were investigated by Q- and X-band EPR spectroscopy in dark and upon in situ UVA or visible-light exposure. Lorentzian signal at g = 2.003, more pronounced in the case of the thermally etched material, dominates EPR spectra of MCN and MCN-TE. More complex spectra were found for H2O2 -treated photocatalysts revealing the presence of signals attributed to the radicals produced via H2O2 interaction with C/N sites in the C3N4 polymeric network. The X-band spectra monitored upon in situ irradiation of the C3N4 -based photocatalysts evidenced the intensity gr…
HyperLabelMe : A Web Platform for Benchmarking Remote-Sensing Image Classifiers
2017
HyperLabelMe is a web platform that allows the automatic benchmarking of remote-sensing image classifiers. To demonstrate this platform's attributes, we collected and harmonized a large data set of labeled multispectral and hyperspectral images with different numbers of classes, dimensionality, noise sources, and levels. The registered user can download training data pairs (spectra and land cover/use labels) and submit the predictions for unseen testing spectra. The system then evaluates the accuracy and robustness of the classifier, and it reports different scores as well as a ranked list of the best methods and users. The system is modular, scalable, and ever-growing in data sets and clas…
Detection of Signals in MC–CDMA Using a Novel Iterative Block Decision Feedback Equalizer
2022
This paper presents a technique to mitigate multiple access interference (MAI) in multicarrier code division multiple access (MC-CDMA) wireless communications systems. Although under normal circumstances the MC-CDMA system can achieve high spectral efficiency and resistance towards inter symbol interference (ISI) however when exposed to substantial nonlinear distortion the issue of MAI manifests. Such distortion results when the power amplifiers are driven into saturation or when the transmit signal experiences extreme adverse channel conditions. The proposed technique uses a modified iterative block decision feedback equalizer (IB-DFE) that uses a minimal mean square error (MMSE) receiver …