Search results for "Spectral bands"
showing 10 items of 88 documents
Subpicosecond transient signal spectroscopy of Prodan in dimethylformamide solution.
2008
We report a pump-probe experiment revealing the temporal evolution of subpicosecond evolution of Prodan's excited-state absorption in dimethylformamide. Also, we present calculation of the first spectral moment of this spectral band and estimation of different relaxation components on the subpicosecond time scale.
Synchrotron-based Fourier transform spectra of the ν23 and ν24 IR bands of hexamethylenetetramine C6N4H12
2015
Abstract Hexamethylenetetramine (HMT), C6N4H12 is a spherical top with nine IR-active modes. Because of its relevance for astrophysics, we recorded the absorption spectra in the full range of its fundamental bands. In total, we detected eight fundamental bands and recently published the rotational analysis of the four most intense bands ( ν 19 , ν 20 , ν 21 , ν 22 ) located in the 1000–1500 cm−1 range as a support for astronomical searches (Pirali et al., 2014). While the CH stretch modes are unresolved broad features, in this article we report the analysis of the two remaining fundamental bands exhibiting rotationally resolved structures: ν 23 –GS and ν 24 –GS located at about 820 cm−1 and…
Analysis of a multi-wavelength time-resolved observation of a coronal loop
2005
Several items on the diagnostics and interpretation of coronal loop observations are under debate. In this work, we analyze a well-defined loop system detected in a time-resolved observation in several spectral bands. The dataset includes simultaneous images in the TRACE 171 A, 195 A and 284 A bands, and Yohkoh/SXT, and two rasters taken with SoHO/CDS in twelve relevant lines. The loop is initially best visible in the TRACE 195 A filter band, and later in the 171 A filter band, with correspondence with the CDS raster images at log T \~ 6.0-6.1. We have taken as pixel-by-pixel background the latest TRACE, Yohkoh and CDS images where the loop has faded out. We examine the loop morphology evol…
HINODE /EIS SPECTROSCOPIC VALIDATION OF VERY HOT PLASMA IMAGED WITH THE SOLAR DYNAMICS OBSERVATORY IN NON-FLARING ACTIVE REGION CORES
2012
We use coronal imaging observations with SDO/AIA, and Hinode/EIS spectral data, to explore the potential of narrow band EUV imaging data for diagnosing the presence of hot (T >~5MK) coronal plasma in active regions. We analyze observations of two active regions (AR 11281, AR 11289) with simultaneous AIA imaging, and EIS spectral data, including the CaXVII line (at 192.8A) which is one of the few lines in the EIS spectral bands sensitive to hot coronal plasma even outside flares. After careful coalignment of the imaging and spectral data, we compare the morphology in a 3 color image combining the 171, 335, and 94A AIA spectral bands, with the image obtained for CaXVII emission from the an…
High-resolution IR spectrum of AsH2D: Ro-vibrational analysis of the bending triad bands , , and
2008
Abstract The infrared spectrum of the AsH2D molecule has been measured in the region of the three bending fundamental bands on a Fourier transform spectrometer with a resolution of 0.0024 cm−1 and analyzed for the first time. More than 7500 normally allowed and in addition about 600 forbidden, but perturbation-activated transitions with J max = 21 , K a max = 20 and K c max = 21 have been assigned to the bands ν 3 , ν 4 , and ν 6 . The measured transition wavenumbers were used to determine 1047 upper energy values. These energies were fitted with a Watson-type Hamiltonian in A reduction and IIIl representation taking into account resonance interactions between all three bending states, (001…
Linestrengths of the ν2 and ν4 bands of 12CH4 and 13CH4
1989
Absorption spectra recorded on the high-resolution Fourier transform spectrometer at Kitt Peak National Observatory/National Solar Observatory were used to measure individual line strengths of the nu(2) and nu(4) bands of (C-12)H4 and (C-13)H4. The measurements were used to obtain expressions that could be used to correctly predict individual line strengths through five orders of magnitude of absorption strength and high values of J-prime. Transition strengths were modeled using the dyad formalism of two interacting bands and a seven-term second-order dipole-moment expansion. The successful fitting of these data indicates that the method can be used to model measurements of 2- to 5-percent …
SphinX: A fast solar Photometer in X-rays
2008
The scientific goals and construction details of a new design, Polish X-ray spectrophotometer are given. It will be incorporated within the Russian TESIS X and EUV complex aboard the forthcoming CORO-NAS solar mission. SphinX (Solar Photometer in X-rays) will use PIN silicon detectors for high time resolution (0.01 s) measurements of the solar spectra of quiet and active corona in the range 0.5–15 keV. A new filter-fluorescence target concept will be employed to allow for a fast photometry of the solar X-ray flux variations in selected, well defined narrow spectral bands including the Fe XXVI and Fe XXV iron line groups.
Multiconfigurational perturbation theory (CASPT2) applied to the study of the low-lying singlet and triplet excited states of cyclopropene
1996
The electronic spectrum of cyclopropene has been studied using multiconfigurational second-order perturbation theory (CASPT2) with extended ANO-type basis sets. The calculation comprises two valence states and the 3s, 3p, 3d members of the Rydberg series converging to the π and σ ionization limits. A total of twenty singlet and twenty triplet excited states have been analyzed. The results confirm the valence nature of the lowest energy singlet-singlet band and yield a conclusive assignment: the first dipole-allowed transition in cyclcopropene is due to absorption to a (σ → π*) state. The (π → π*) (V) state is interleaved among a number of Rydberg states in the most intense band of the syste…
Fog attenuation prediction for optical and infrared waves
2004
The principal disadvantage of using free space optics (FSO) telecommunication systems is the disturbing role played by the atmosphere on light propagation and thus on the channel capacity, availability, and link reliability. The wavelength choice is currently a subject of disagreement among designers and users of FSO equipments. Generally this equipment operates in the visible and the near IR at 690, 780, 850, and 1550 nm. Several authors affirm that equipment working at 1550 nm presents less atmospheric attenuation in the presence of fog and thus better link availability. Others consider that for dense fogs (visibility<500 m), all wavelengths are attenuated in the same way (wavelength inde…
Compact dielectric reflective elements II Multichannel filter of closely spaced spectral bands
1994
The optical design of an interference wedge filter providing the simultaneous separation of a number of closely spaced spectral bands is studied. Multiple reflections of the incident collimated beam within the wedge are initiated, each of them characterized by a different angle of incidence and consequently by specific spectral parameters of the transmitted band. Model calculations based on the measured angular dependences of filter transmission parameters have been performed. The design is proposed for applications in optical communications (wavelength division demultiplexing), analytical spectroscopy (minipolychromators), color analysis, and similar areas.