Search results for "Spectral line"
showing 10 items of 1453 documents
Improved calculations of beta decay backgrounds to new physics in liquid xenon detectors
2020
We present high-precision theoretical predictions for the electron energy spectra for the ground-state to ground-state $\beta$ decays of $^{214}$Pb, $^{212}$Pb, and $^{85}$Kr most relevant to the background of liquid xenon dark matter detectors. The effects of nuclear structure on the spectral shapes are taken into account using large-scale shell model calculations. Final spectra also include atomic screening and exchange effects. The impact of nuclear structure effects on the $^{214}$Pb and $^{212}$Pb spectra below $\approx100$ keV, pertinent for several searches for new physics, are found to be comparatively larger than those from the atomic effects alone. We find that the full calculatio…
Deep traps in InGaN/GaN single quantum well structures grown with and without InGaN underlayers
2020
The electrical properties and deep trap spectra were compared for near-UV GaN/InGaN quantum well (QW) structures grown on free-standing GaN substrates. The structures differed by the presence or absence of a thin (110 nm) InGaN layer inserted between the high temperature GaN buffer and the QW region. Capacitance-voltage profiling with monochromatic illumination showed that in the InGaN underlayer (UL), the density of deep traps with optical threshold near 1.5 eV was much higher than in the QW and higher than for structures without InGaN. Irradiation with 5 MeV electrons strongly increased the concentration of these 1.5 eV traps in the QWs, with the increase more pronounced for samples witho…
The Born–Oppenheimer equilibrium bond distance of GeO from millimetre- and submillimetre-wave spectra and quantum-chemical calculations
2014
The millimetre- and submillimetre-wave spectra of the five common isotopologues of (GeO)-O-16 in their electronic and vibrational ground state have been recorded in the spectral region 115-732GHz; for (GeO)-Ge-74-O-16, the rotational spectrum in the v = 1 state has been detected as well. Exploiting the high precision of the measurements, the Born-Oppenheimer breakdown parameter Delta(Ge)(01) could be determined from a Dunham analysis of the spectral data, whereas Delta(O)(01) was obtained from quantum-chemical calculations, because of the lack of high-precision measurements for the (GeO)-O-18 isotopologues. From the rotational equilibrium constant, the Born-Oppenheimer equilibrium distance …
Rotational spectrum of silyl chloride: hyperfine structure and equilibrium geometry
2012
The Lamb-dip technique was employed to record the rotational spectra of two isotopic species of silyl chloride, namely (28)SiH3Cl and (29)SiH3Cl, in order to investigate their hyperfine structure. High-accuracy quantum-chemical computations were employed to predict the hyperfine parameters involved and to support the experimental investigation. Analysis of the experimental spectra led to an improvement in the accuracy of the known spectroscopic constants as well as allowed us to determine additional spectroscopic parameters for the first time. Furthermore, the equilibrium structure of silyl chloride was reinvestigated using both theoretical and experimental data. The best theoretical and se…
High-energy monitoring of NGC 4593 II. Broad-band spectral analysis: testing the two-corona model
2019
It is widely believed that the primary X-ray emission of AGN is due to the Comptonisation of optical-UV photons from a hot electron corona, while the origin of the 'soft-excess' is still uncertain and matter of debate. A second Comptonisation component, called warm corona, was therefore proposed to account for the soft-excess, and found in agreement with the optical-UV to X-ray emission of a sample of Seyfert galaxies. In this context, we exploit the broadband XMM-Newton and NuSTAR simultaneous observations of the Seyfert galaxy NGC 4593 to further test the so called "two corona model". The NGC 4593 spectra are well reproduced by the model, from the optical/UV to the hard X-rays. Moreover, …
Testing warm Comptonization models for the origin of the soft X-ray excess in AGNs
2018
The X-ray spectra of many active galactic nuclei (AGN) show a soft X-ray excess below 1-2 keV on top of the extrapolated high- energy power law. The origin of this component is uncertain. It could be a signature of relativistically blurred, ionized reflection, or the high-energy tail of thermal Comptonization in a warm (kT $\sim$ 1 keV), optically thick ($\tau\simeq$ 10-20) corona producing the optical/UV to soft X-ray emission. The purpose of the present paper is to test the warm corona model on a statistically significant sample of unabsorbed, radio-quiet AGN with XMM-newton archival data, providing simultaneous optical/UV and X-ray coverage. The sample has 22 objects and 100 observations…
Persistence of oxidation state III of gold in thione coordination
2017
Ligands N,N'-tetramethylthiourea and 2-mercapto-1-methyl-imidazole form stable Au(III) complexes [AuCl3(N,N'-tetramethylthiourea)] (1) and [AuCl3(2-mercapto-1-methyl-imidazole)] (2) instead of reducing the Au(III) metal center into Au(I), which would be typical for the attachment of sulfur donors. Compounds 1 and 2 were characterized by spectroscopic methods and by X-ray crystallography. The spectroscopic details were explained by simulation of the UV-Vis spectra via the TD-DFT method. Additionally, computational DFT studies were performed in order to find the reason for the unusual oxidation state in the crystalline materials. The preference for Au(III) can be explained via various weak in…
Broad-band Spectral Evolution of Scorpius X-1 along its Color-Color Diagram
2007
We analyze a large collection of RXTE archive data from April 1997 to August 2003 of the bright X-ray source Scorpius X-1 in order to study the broadband spectral evolution of the source for different values of the inferred mass accretion rate by studying energy spectra from selected regions in the Z-track of its Color-Color Diagram. A two-component model, consisting of a soft thermal component interpreted as thermal emission from an accretion disk and a thermal Comptonization component, is unable to fit the whole 3--200 keV energy spectrum at low accretion rates. Strong residuals in the highest energy band of the spectrum require the addition of a third component that can be fitted with a …
Optical Properties of Irradiated Yttrium Aluminum Garnet
2012
The results of investigation of the photoluminescence (PL) and optical absorption of crystals Y3Al5O12(YAG) doped with different concentrations of manganese ions exposed to fast neutron irradiation and electron irradiation are presented. Photoluminescence spectra of YAG before neutron irradiation at T=80 K contain fine lines in orange region of spectrum, ascribed to Mn2+ ions in octahedral position. After irradiation band broadening is observed in the luminescence spectra of garnet crystals. Electron irradiation produced broad band with a complex structure related to Mn4+ ions. Exchange interaction between radiation defect and impurity ions during neutron irradiation and electron irradiatio…
Dependence of the emission properties of the germanium lone pair center on Ge doping of silica
2011
We present an experimental investigation regarding the changes induced by the Ge doping level on the emission profile of the germanium lone pair center (GLPC) in Ge doped silica. The investigated samples have been produced by the sol-gel method and by plasma-activated chemical vapor deposition and have doping levels up to 20% by weight. The recorded photoluminescence spectra show that the GLPC emission profile is the same when the Ge content is lower than ∼ 1% by weight, whereas it changes for higher doping levels. We have also performed Raman scattering measurements that show the decrease of the D1 Raman band at 490 cm( - 1) when the Ge content is higher than 1% by weight. The data suggest…