Search results for "Spectral"
showing 10 items of 3116 documents
Search for superheavy elements in monazites using chemical enrichment
1982
Evidence for the existence of superheavy elements in monazite inclusions embedded in Madagascan mica and surrounded by giant radioactive haloes was given by Gentry et al.1 who observed photons with energies corresponding to predicted Lα1 X-ray energies of element 126 (at 27.25 keV) and also of elements 116, 124 and 127 in irradiations of such crystals with collimated proton beams. For an unambiguous identification, the detection of further members of the L X-ray series would be most important. In X-ray spectra of monazite samples these transitions are buried under the strong K X-ray peaks of the lanthanide elements. They should, however, become visible after chemical enrichment of the super…
Photoluminescence study of terbium-exchanged ultrastable Y zeolites: Number of species, photoluminescence decays and decay-associated spectra
2008
Terbium-exchanged ultrastable Y (USY) zeolites were investigated by using time-resolved photoluminescence spectroscopy techniques and methods. To determine the distribution of terbium species in USY zeolites together with their photoluminescence properties, several analysis methods for the time-resolved luminescence spectra were used such as the area normalization of time-resolved photoluminescence spectra, singular value decomposition, global nonlinear least squares, and the maximum entropy. Except for a questionable long lifetime, small contribution of a terbium species with lifetime of 1.9¿2.1 ms, all the experimental and analysis results converged to a two terbium species distribution w…
Assessment of workflow feature selection on forest LAI prediction with sentinel-2A MSI, landsat 7 ETM+ and Landsat 8 OLI
2020
The European Space Agency (ESA)’s Sentinel-2A (S2A) mission is providing time series that allow the characterisation of dynamic vegetation, especially when combined with the National Aeronautics and Space Administration (NASA)/United States Geological Survey (USGS) Landsat 7 (L7) and Landsat 8 (L8) missions. Hybrid retrieval workflows combining non-parametric Machine Learning Regression Algorithms (MLRAs) and vegetation Radiative Transfer Models (RTMs) were proposed as fast and accurate methods to infer biophysical parameters such as Leaf Area Index (LAI) from these data streams. However, the exact design of optimal retrieval workflows is rarely discussed. In this study, the impact of…
Identification of the most informative wavelengths for non-invasive melanoma diagnostics in spectral region from 450 to 950 nm
2020
In this study 300 skin lesion (including 32 skin melanomas) multispectral data cubes were analyzed. The multi-step and single step machine learning approaches were analyzed to find the wavebands that provide the most information that helps discriminate skin melanoma from other benign pigmented lesions. The multi-step machine learning approach assumed training several models but proved itself to be ineffective. The reason for that is a necessity to train a segmentation model on a very small dataset and utilization of standard machine learning classifier which have shown poor classification performance. The single-step approach is based on a deep learning neural network. We have conducted 260…
Semi-Supervised Classification Method for Hyperspectral Remote Sensing Images
2004
A new approach to the classification of hyperspectral images is proposed. The main problem with supervised methods is that the learning process heavily depends on the quality of the training data set. In remote sensing, the training set is useful only for simultaneous images or for images with the same classes taken under the same conditions; and, even worse, the training set is frequently not available. On the other hand, unsupervised methods are not sensitive to the number of labelled samples since they work on the whole image. Nevertheless, relationship between clusters and classes is not ensured. In this context, we propose a combined strategy of supervised and unsupervised learning met…
The influence of storage method on the transparency of pig crystalline lens
2019
Este artículo se ha publicado de forma definitiva en: http://www.scielo.br/pdf/abo/v82n1/0004-2749-abo-82-01-0056.pdf Purpose: The porcine eye is frequently used as a research model. This paper analyzes the effect of different storage methods on the transparency of pig crystalline lens. Methods: A spectral transmission curve (from 220 to 780 nm) for the crystalline lens was determined experimentally after storage in different conditions: saline solution, formalin, castor oil, and freezing at -80°C. The total transmission in the visible spectrum, which was used as an index of transparency, was calculated from these curves. For comparative purposes, fresh lenses were evaluated and used as con…
Tracking Polariton Relaxation with Multiscale Molecular Dynamics Simulations
2019
When photoactive molecules interact strongly with confined light modes in optical cavities, new hybrid light–matter states form. They are known as polaritons and correspond to coherent superpositions of excitations of the molecules and of the cavity photon. The polariton energies and thus potential energy surfaces are changed with respect to the bare molecules, such that polariton formation is considered a promising paradigm for controlling photochemical reactions. To effectively manipulate photochemistry with confined light, the molecules need to remain in the polaritonic state long enough for the reaction on the modified potential energy surface to take place. To understand what determine…
1H and13C n.m.r. spectra of dichloro(trans-2-chlorovinyl)arsine
1977
Proton and carbon magnetic resonance spectra of Lewisite or dichloro(trans-2-chlorovinyl)arsine have been measured and the results are compared with the n.m.r. spectral parameters of other trans-1,2-substituted ethylenes. The coupling constants can be rationalized by substituent electronegativity. The chemical shifts show an unusually large paramagnetic effect from the AsCl2 group.
He-I and He-II excited photoelectron spectra of cyclohepttatrienetricarbonyl complexes of group via metals
1979
Abstract Photoelectron spectra of Group VIA metal complexes M(CO) 3 (η 6 -C 7 H 8 ) have been assigned using experimental criteria along with quantum-mechanical calculations. A general agreement between computed and measured ionization energies has been found for molecular orbitas mainly ligand in character. Similar correlations do not hold for the highest orbitals, mainly metal d based. The energies associated with ionization processes are, in this case, largely dominated by the relaxation terms. The variations of intensities of these bands on changing the energy of ionizing radiation were of crucial significance in the assignment
Indoor artificial lighting: Prediction of the circadian effects of different spectral power distributions.
2014
The study presented in this paper aims to evaluate if and how the environment affects the circadian impact of a light source by predicting circadian stimulus (CS) resulting from the exposure to different light scenes, using equations reported in studies by Rea et al. The main findings are: (1) Above 600 lx at eye level the increase of CS is little; (2) Between 50 lx and 200 lx at the eye level an increase of only 50 lx determines a significant increase of CS; (3) Light sources with correlated colour temperatures between 2900 K and 4200 K have similar impacts on the circadian system according to the calculation method used; (4) Even an almost neutral environment affects the circadian impact…