Search results for "Spectral"
showing 10 items of 3116 documents
On the nature of slow β-relaxation in supercooled liquids
2000
We propose a model for reorientational motions of molecules associated with secondary beta-relaxation in supercooled liquids. The secondary relaxation is attributed to relaxation within a given local minimum, while the primary relaxation is attributed to transitions between distinct free-energy minima. We find that (i) at the temperature where the peak frequency of the extrapolated beta-relaxation intersects the alpha-relaxation, the actual and the extrapolated spectra differ in their time constants by approximately one decade; (ii) there is no clear division between the imaginary part of the dielectric susceptibility for the alpha- and the beta-relaxation for temperatures larger than 1.1 T…
Mass spectra of chlorinated esters: 2—Methyl mono- and dichlorobutanoates
1982
The mass spectral fragmentations of methyl mono- and dichlorobutanates have been studied. Deutrium labelling and metastable ion analysis were used to elucidate the fragmentation mechanisms. The molecular ion peaks of the esters are weak and show only in the spectra of the monochloro isomers. A McLafferty rearrangement gives the base peaks in the spectra of methyl 2-chloro-, 4-chloro- and 4,4-dichlorobutanoate; α-cleavage, [COOCH3]+, in methyl 2,2- and 2,4-dichlorobutanoate; [MCl]+, in methyl 3-chlorobutanoate; [MClHCl]+, in methyl 3,4-dichlorobutanoate; [MClCH2CO]+, in methyl 3,3-dichlorobutanoate and [MClCOOCH3]+˙, in methyl erythro- and threo-2,3-dichlorobutanoate. The mass spectra of the…
Use of Guided Regularized Random Forest for Biophysical Parameter Retrieval
2018
This paper introduces a feature selection method based on random forest -the Guided Regularized Random Forest (GRRF)- which can be used in classification and regression tasks. The method is based on the regularization of the information gain in the random forest nodes to obtain a subset of relevant and non-redundant features. The proposed method is used as a preliminary step In the process of retrieving biophysical parameters from a hyperspectral image. Preliminary experiments show that we can reduce the RMSE of the retrievals by around 7% for the Leaf Area Index and around 8% for the fraction of vegetation cover when compared to the results using random forest features.
Demultiplexing Visible and Near-Infrared Information in Single-Sensor Multispectral Imaging
2016
In this paper, we study a single-sensor imaging system that uses a multispectral filter array to spectrally sample the scene. Our system captures information in both visible and near-infrared bands of the electromagnetic spectrum. Due to manufacturing limitations, the visible filters in this system also transmit the NIR radiation. Similarly, visible light is transmitted by the NIR filter, leading to inaccurate mixed spectral measurements. We present an algorithm that resolves this issue by separating NIR and visible information. Our method achieves this goal by exploiting the correlation of multispectral images in both spatial and spectral domains. Simulation results show that the mean squa…
Performance of TES method over urban areas at a high spatial resolution scale
2013
The Temperature and Emissivity Separation (TES) algorithm is used to retrieve the LSE and LST values from hyperspectral sensors. In this work we analyse the performance of this methodology over urban areas. Three different sources of error in the processing chain of the remote sensing imagery are detected: the algorithm itself, the atmospheric correction and the 3D structure of the urban scenes. The TITAN tool is used to model all the radiative components of the signal registered by a sensor. Results show that: first, the TES algorithm used reproduces the LSE (LST) of urban materials within an RMSE of 0.017 (0.9 K). Second, 20 % of uncertainty in the water vapour content of the total atmosp…
A low cost and easy re-configurable instrument for power quality survey
2004
In this document the development of a low cost and user friendly PC-based instrument for power quality measurement is proposed, according to IEC 61000-4-7 and standard IEC 61000-4-30. It is an easily re-configurable instrument able to measure harmonics, interharmonics and amplitude disturbances and supply unbalance. In order to verify its accuracy, the instrument has been tested according standard test procedures, by means of a built-up calibration test bench.
On the Characterization of Dynamic Properties of Random Processes by Spectral Parameters
2000
This paper deals with the general problem of directly relating the distribution of ranges of wide band random processes to the power spectral density (PSD) by means of closed-form expressions. Various attempts to relate the statistical distribution of ranges to the PSD by means of the irregularity factor or similar parameters have been done by several authors but, unfortunately, they have not been fully successful. In the present study, introducing the so-called analytic processes, the reasons for which these parameters are insufficient to an unambiguous determination of the range distribution and the fact that parameters regarding the time-derivative processes are needed have been explaine…
Synergetic exploitation of the Sentinel-2 missions for validating the Sentinel-3 ocean and land color instrument terrestrial chlorophyll index over a…
2019
Continuity to the Medium Resolution Imaging Spectrometer (MERIS) Terrestrial Chlorophyll Index (MTCI) will be provided by the Ocean and Land Color Instrument (OLCI) on-board the Sentinel-3 missions. To ensure its utility in a wide range of scientific and operational applications, validation efforts are required. In the past, direct validation has been constrained by the need for costly airborne hyperspectral data acquisitions, due to the lack of freely available high spatial resolution imagery incorporating appropriate spectral bands. The Multispectral Instrument (MSI) on-board the Sentinel-2 missions now offers a promising alternative. We explored the synergetic use of MSI data for validat…
Monitoring water stress in Mediterranean semi-natural vegetation with satellite and meteorological data
2014
In arid and semi-arid environments, the characterization of the inter-annual variations of the light use efficiency ε due to water stress still relies mostly on meteorological data. Thus the GPP estimation based on procedures exclusively driven by remote sensing data has not found yet a widespread use. In this work, the potential to characterize the water stress in semi-natural vegetation of three spectral indices (NDWI, SIWSI and NDI7) – from MODIS broad spectral bands – has been analyzed in comparison to a meteorological factor (Cws). The study comprises 70 sites (belonging to 7 different ecosystems) uniformly distributed over Tuscany, and three eddy covariance tower sites. An operational…
Mapping wild pear trees (Pyrus bourgaeana) in Mediterranean forest using high-resolution QuickBird satellite imagery
2012
Recent advances in spatial and spectral resolution of satellite imagery as well as in processing techniques are opening new possibilities of fine-scale vegetation analysis with interesting applications in natural resource management. Here we present the main results of a study carried out in Sierra Morena, Cordoba southern Spain, aimed at assessing the potential of remote-sensing techniques to discriminate and map individual wild pear trees Pyrus bourgaeana in Mediterranean open woodland dominated by Quercus ilex . We used high spatial resolution 2.4 m multispectral/0.6 m panchromatic QuickBird satellite imagery obtained during the summer of 2008. Given the size and features of wild pear tr…