Search results for "Spectroscopic"
showing 10 items of 119 documents
Lateral Fusion of Chemical Vapor Deposited N = 5 Armchair Graphene Nanoribbons
2017
Bottom-up synthesis of low-bandgap graphene nanoribbons with various widths is of great importance for their applications in electronic and optoelectronic devices. Here we demonstrate a synthesis of N = 5 armchair graphene nanoribbons (5-AGNRs) and their lateral fusion into wider AGNRs, by a chemical vapor deposition method. The efficient formation of 10- and 15- AGNRs is revealed by a combination of different spectroscopic methods, including Raman and UV−visnear-infrared spectroscopy as well as by scanning tunneling microscopy. The degree of fusion and thus the optical and electronic properties of the resulting GNRs can be controlled by the annealing temperature, providing GNR films with o…
The Gaia-ESO survey: Metallicity of the chamaeleon i star-forming region
2014
Context. Recent metallicity determinations in young open clusters and star-forming regions suggest that the latter may be characterized by a slightly lower metallicity than the Sun and older clusters in the solar vicinity. However, these results are based on small statistics and inhomogeneous analyses. The Gaia-ESO Survey is observing and homogeneously analyzing large samples of stars in several young clusters and star-forming regions, hence allowing us to further investigate this issue. Aims. We present a new metallicity determination of the Chamaeleon I star-forming region, based on the products distributed in the first internal release of the Gaia-ESO Survey. Methods. 48 candidate member…
SPI: The spectrometer aboard INTEGRAL
2003
SPI is a high spectral resolution gamma-ray telescope on board the ESA mission INTEGRAL (International Gamma Ray Astrophysics Laboratory). It consists of an array of 19 closely packed germanium detectors surrounded by an active anticoincidence shield of BGO. The imaging capabilities of the instrument are obtained with a tungsten coded aperture mask located 1.7 m from the Ge array. The fully coded field-of-view is 16º, the partially coded field of view amounts to 31º, and the angular resolution is 2.5º. The energy range extends from 20 keV to 8 MeV with a typical energy resolution of 2.5 keV at 1.3 MeV. Here we present the general concept of the instrument followed by a brief description of …
A study of the B and Be star population in the field of the LMC open cluster NGC 2004 with VLT-FLAMES
2005
Observations of hot stars belonging to the young cluster LMC-NGC2004 and its surrounding region have been obtained with the VLT-GIRAFFE facilities in MEDUSA mode. 25 Be stars were discovered; the proportion of Be stars compared to B-type stars is found to be of the same order in the LMC and in the Galaxy fields. 23 hot stars were discovered as spectroscopic binaries (SB1 and SB2), 5 of these are found to be eclipsing systems from the MACHO database, with periods of a few days. About 75% of the spectra in our sample are polluted by hydrogen (Halpha and Hgamma), [SII] and [NII] nebular lines. These lines are typical of HII regions. They could be associated with patchy nebulosities with a bi-m…
Spectroscopic Observations of the Delta Scorpii Binary during Its Recent Periastron Passage
2001
The bright star delta Sco has been considered a typical B0-type object for many years. Spectra of the star published prior to 1990 showed no evidence of emission, but only of short-term line profile variations attributed to nonradial pulsations. Speckle interferometric observations show that delta Sco is a binary system with a highly-eccentric orbit and a period of 10.6 years. Weak emission in the H-alpha line was detected in its spectrum for the first time during a periastron passage in 1990. Shortly before the next periastron passage in the summer of 2000, the binary entered a strong H-alpha emission and enhanced mass loss phase. We monitored the spectroscopic development of the Be outbur…
Long-term optical and X-ray variability of the Be/X-ray binary H 1145-619: Discovery of an ongoing retrograde density wave
2017
Multiwavelength monitoring of Be/X-ray binaries is crucial to understand the mechanisms producing their outbursts. H 1145-619 is one of these systems, which has recently displayed X-ray activity. We investigate the correlation between the optical emission and the X-ray activity to predict the occurrence of new X-ray outbursts from the inferred state of the circumstellar disc. We have performed a multiwavelength study of H 1145-619 from 1973 to 2017 and present here a global analysis of its variability over the last 40 years. We have used optical spectra from the SAAO, SMARTS and SALT telescopes and optical photometry from INTEGRAL/OMC and ASAS. We also used X-ray observations from INTEGRAL/…
The large-scale magnetic field of the eccentric pre-main-sequence binary system V1878 Ori
2020
We report time-resolved, high-resolution optical spectropolarimetric observations of the young double-lined spectroscopic binary V1878 Ori. Our observations were collected with the ESPaDOnS spectropolarimeter at the Canada-France-Hawaii Telescope through the BinaMIcS large programme. V1878 Ori A and B are partially convective intermediate mass weak-line T Tauri stars on an eccentric and asynchronous orbit. We also acquired X-ray observations at periastron and outside periastron. Using the least-squares deconvolution technique (LSD) to combine information from many spectral lines, we clearly detected circular polarization signals in both components throughout the orbit. We refined the orbita…
Supramolecular Construction of Cyanide-Bridged Re I Diimine Multichromophores
2019
The reactions of labile [Re(diimine)(CO)3(H2O)]+ precursors (diimine = 2,2′-bipyridine, bpy; 1,10-phenanthroline, phen) with dicyanoargentate anion produce the dirhenium cyanide-bridged compounds [{Re(diimine)(CO)3}2CN)]+ (1 and 2). Substitution of the axial carbonyl ligands in 2 for triphenylphosphine gives the derivative [{Re(phen)(CO)2(PPh3)}2CN]+ (3), while the employment of a neutral metalloligand [Au(PPh3)(CN)] affords heterobimetallic complex [{Re(phen)(CO)3}NCAu(PPh3)]+ (4). Furthermore, the utilization of [Au(CN)2]−, [Pt(CN)4]2–, and [Fe(CN)6]4–/3– cyanometallates leads to the higher nuclearity aggregates [{Re(diimine)(CO)3NC}xM]m+ (M = Au, x = 2, 5 and 6; Pt, x = 4, 7 and 8; Fe, x…
Spectroscopic signatures of the carbon buckyonions C60@C180 and C60@C240: a dispersion-corrected DFT study
2013
We have investigated, using dispersion corrected DFT methods, the structure and the spectroscopic properties of carbon buckyonions C-60@C-180 and C-60@C-240. C-60, C-180 and C-240 showed a noticeable variation of their geometries in C-60@C-180 and C-60@C-240, upon encapsulation. Inclusion of the dispersion correction term in the calculations has a significant effect on the geometry. C-60@C-180 has a large positive interaction energy, while for C-60@C-240 a negative value is found indicating that only C-240 can easily accommodate C-60. In both cases dispersion interactions strongly contribute to the stabilization of the complexes. Vibrational frequencies, electronic transitions and NMR prope…
Taxane analysis by high performance liquid chromatography-Nuclear magnetic resonance spectroscopy ofTaxus species
1998
High performance liquid chromatography–nuclear magnetic resonance spectroscopic analyses of taxane diterpenoids from three Taxus species were carried out employing a stopped-flow technique. Several taxanes have been identified from 500 mg leaf samples without prior isolation. © 1998 John Wiley & Sons, Ltd.