Search results for "Spectroscopy"
showing 10 items of 10293 documents
Unexpected Behavior of Enaminones: Interesting New Routes to 1,6-Naphthyridines, 2-Oxopyrrolidines and Pyrano[4,3,2-de][1,6]naphthyridines
2012
Reaction of enaminones 1a–d with 2-aminoprop-1-ene-1,1,3-tricarbonitrile (2) in the presence of AcOH/NH4OAc afforded 7-amino-5-oxo-5,6-dihydro-1,6-naphthyridine-8-carbonitrile derivatives 9a–d. On the other hand, 2-aminopyrano[4,3,2-de] [1,6]naphthyridine-3-carbonitriles 20a–c,e were the only obtained products from the reactions of 1a–d with 2 in the presence of AcOH/NaOAc, while 1d afforded [3,5-bis-(4-chloro-benzoyl)-phenyl]-(4-chloro-phenyl)-methanone 21 under the same condition. The reaction of 2 with diethyl acetylenedicarboxylate in the presence of AcOH/NH4OAc afforded (4-cyano-5-dicyanomethylene-2-oxo-2,5-dihydro-1H-pyrrol-3-yl)-acetic acid eth…
Contributions to Phase Two of AGATA electronics
2020
En el campo de la física nuclear, la espectroscopia de rayos gamma de alta resolución es un método preciso para estudiar la estructura del núcleo, extrayendo la energía y la distribución angular de los fotones gamma emitidos en las transiciones entre estados nucleares. Para obtener núcleos en un estado excitado y por tanto emitan rayos gamma, hemos de hacer chocar la materia, produciendo reacciones nucleares (espectroscopia de haz) o recurrir a desintegraciones radiactivas (espectroscopia de desintegración). Los detectores de semiconductor de germanio de alta pureza (HPGe) han demostrado tener una buena respuesta interaccionando con rayos gamma. Al igual que otros detectores de basados en s…
Optical characterization of nanowires for optoelectronic devices and energy harvesting
2019
This thesis presents a detailed investigation of the optical properties of Bi2Te3, GaN, InN, InP and GaN/AlN nanowires grown by different techniques for their application on future optoelectronic and thermoelectric devices. The thesis also includes a prototype of hybrid solar cell. The outline of the thesis is organized as follows: Chapter 1 presents a bird's eye view of the content of the thesis. Chapter 2 reviews basic notions of epitaxial growth, fundamentals in the synthesis of the nanowires and experimental techniques used for characterization and their underlying theory. Although several characterization techniques are employed in this work, Raman spectroscopy is applied as the major …
Passive direct measurement of sun-induced chlorophyll fluorescence spectrum from in vivo leaves
2022
The fluorescence of chlorophyll in vegetation is a weak signal emitted between 650 and 850 nm that is mixed with the much more intense light reflected by the leaf, which is why active methods are commonly used (through the additional contribution of controlled artificial light) or using indirect measurements instead. So, the measurement is provided just in relative units in the first case, or the accuracy of the estimate in the second case is uncertain without proper direct validation. The Thesis presents a new device, called FluoWat, for passive measurement that allows direct measurement of the fluorescence emission of leaves in vivo under natural conditions in the field with sunlight. And…
DIELECTRIC AND PIEZOELECTRIC PROPERTIES OF 0.8Na0.5 Bi0.5 TiO3-0.2BaTiO3 MODIFIED WITH SODIUM NIOBATE
2022
This work was supported by the Research Council of Lithuania (Project S-LLT-20-4). This work has been supported by Mutual Funds Taiwan–Latvia– Lithuania Cooperation Project Application LV-LT-TW/2020/10.
Atomic physics, optical technologies, and medical physics: Abstracts book, 16.-17.02.2023., Riga
2023
81h International Scientific Conference of the University of Latvia Section ‘Atomic physics, optical technologies and medical physics’ will be held by Institute of Atomic Physics and Spectroscopy (IAPS) on 16-17.02.2023. The section will present the recent results, achieved by IAPS researchers and the IAPS partners in the following research fields: optical phenomena in gas, liquid, solid state and biological samples, optical methods for diagnostics, chemical analysis and optical sensor technologies, quantum optics and telecommunication, modelling, novel nanomaterials and their biomedical applications. Total 23 abstracts.
Atomic physics, optical technologies and medical physics, 10-11.02.2022.,Riga
2022
80th International Scientific Conference of the University of Latvia Section ‘Atomic physics, optical technologies and medical physics’ will be held by Institute of Atomic Physics and Spectroscopy (IAPS) on 10-11.02.2022. The section will present the recent results, achieved by IAPS researchers and the IAPS partners in the following research fields: optical phenomena in gas, liquid, solid state and biological samples, optical methods for diagnostics, chemical analysis and optical sensor technologies, quantum optics and telecommunication, modelling, novel nanomaterials and their biomedical applications. Total 27 abstracts.
Challenges in clinical analysis by infrared spectroscopy
2014
En els últims anys, el desenvolupament de metodologies d’anàlisi clínic basades en espectroscòpia infraroja (IR) s’ha convertit en un camp molt actiu d’investigació. Millores en la instrumentació i en el processament de les dades han contribuït a que l’espectroscòpia IR s’utilitze per a obtindré informació de la composició de fluids i teixits biològics. Aquesta tesis consolida aquesta tècnica com una eina versàtil en el desenvolupament de metodologies per a extraure una gran quantitat d’informació en un ampli espectre de mostres mitjançant instrumentació senzilla, ràpida i econòmica. Tot i que la tècnica té problemes de sensibilitat i selectivitat, els resultats obtinguts en aquesta Tesi de…
Influence de la symétrie et de la taille de la molécule adsorbée sur le processus d'adsorption des composés éthyléniques sur une zéolithe de topologi…
2005
This manuscript lies within the scope of the understanding of the stepped isotherm observed during adsorption, on MFI zeolites, of some organic compounds which have a similar size to that of the pore opening of zeolite. During this work, the process of adsorption of ethylene and tetramethylethylene is initially studied by gravimetry and then by in situ infrared spectroscopy. This last technique enables to follow simultaneously the modifications of the adsorbent and the adsorbate. The analysis of these data lets suppose that the step in adsorption isotherm can be explained by taking account simultaneously of the symmetry and the size of the admolecule. In addition to the infrared bands chara…
Quantum-chemical determination of Born–Oppenheimer breakdown parameters for rotational constants: the open-shell species CN, CO+ and BO
2013
The quantum-chemical protocol for computing Born-Oppenheimer breakdown corrections to rotational constants in the case of diatomic molecules is extended to open-shell species. The deviation from the Born-Oppenheimer equilibrium rotational constant is obtained by considering three contributions: the adiabatic correction to the equilibrium bond distance, the electronic contribution to the moment of inertia requiring the computation of the rotational g-tensor, and the so-called Dunham correction. Values for the Born-Oppenheimer breakdown parameters of CN, CO+, and BO in their (2)sigma(+) electronic ground states are reported based on coupled-cluster calculations of the involved quantities and …