Search results for "Stability"
showing 10 items of 3085 documents
Coping with Asymmetric Shocks in the EMU: The Role of Labour Market Flexibility
2013
The chapter discusses the economic conditions for the success of EMU when there is still a need for structural reforms in the markets of goods and services, and factors of production. In view of asymmetric shocks, experience shows that behaviour in nominal and real wage growth resulted in increased unemployment throughout the EU15. Fiscal policy, on the other hand, could mitigate to some extent the burden of wage adjustment, and could play an important role in improving productivity. In general, however, smooth shock-absorption requires a flexible wage formation process to circumvent low employment levels, but the risk of hysteresis would remain. To avoid the accumulation of wage and labour…
Family Stability and Labor Market Gender Convergence
2009
The present paper examines the historical development in the structure of the family in terms of marriage, divorce, fertility and labor 1886-2007 in order to map quantitative changes. The paper draws new information from novel Norwegian data. Along with the changing family relations we also quantify the closing of the gender gap by converging trends for both labor participation rates and wages. The paper concludes that there is a clear correspondence between gender convergence in the labor market and less stable family relations.
Modelling urban networks at mega-regional scale: Are increasingly complex urban systems sustainable?
2015
Are the dynamics of mega-regions sustainable or not? We explore the hypothesis that increasing complexity in mega-regions implies less demands on resources needed to generate organized information, thereby making the systems more efficient and stable. This article aims to identify structural indicators for measuring urban networks at the mega-regional scale. We use night-time light data from the broad band near-visible infrared channel of the DMSP-OLS to monitor the dynamics of urbanization. We study the urban networks as graphs, where nodes are cities, and the main road and railway infrastructures represent the edges. We propose four indicators for measuring the complexity, polycentricity,…
ChemInform Abstract: Pressure-Induced Transformations in PrVO4and SmVO4and Isolation of High-Pressure Metastable Phases.
2013
High-pressure phases of PrVO4 and SmVO4 are synthesized from the zircon-structured compounds at 12 GPa and room temperature (24 h).
Novel Lipophilic Lanthanide Bis-Phthalocyanines Functionalized by Pentadecylphenoxy Groups: Synthesis, Characterization and UV-Photostability
2012
Novel sandwich-type phthalocyanines containing a rare earth metal core (Pr, Nd, Eu-Lu) and macrocycles peripherally substituted by pentadecylphenoxy groups were synthesized using a cardanol-based phthalonitrile precursor and the respective lanthanide acetate. Additionally, the metal free-base analog compound was studied for comparison. The purified reaction products were all found to be thick and viscous substances at room temperature, showing liquid crystalline behavior with a distinct increase in fluidity at ca. 40 ° C. The complexes are readily soluble in chloroalkyl solvents and dissolve fairly well in DMF with some tendency to form aggregates. Besides they are strongly hydrophobic and …
FRACTAL STRUCTURES IN SINGLE CRYSTALS OF FERROELECTRIC LITHIUM NIOBATE GROWN UNDER STRONGLY UNSTABLE CONDITIONS
2009
Atomic force microscopy studies of lithium niobate single crystals containing heterogeneously distributed lanthanide (Gd) admixture and a regular domain structure of 100 nm to 1 μm steps obtained under conditions of severe thermal instability have revealed fractal structures of the size of 10 to 100 nm within regions of the regular domain structures. A super-structure of clustered defects with 1–2 nm steps explaining results of Raman spectra analysis is supposed to exist in the cation sub-lattice and formation of periodic fractal structures of the size of ∼1 nm–100 μm is suggested to take place in lithium niobate single crystals containing lanthanide admixture.
Novel structural phases and the properties of LaX (X = P, As) under high pressure: first-principles study
2020
The particle swarm optimization algorithm and density functional theory (DFT) are extensively performed to determine the structures, phase transition, mechanical stability, electronic structures, and thermodynamic properties of lanthanide phosphates (LaP and LaAs) in the pressure range of 0 to 100 GPa. Two novel high-pressure structures of LaP and LaAs are first reported here. It is found that LaX (X = P, As) undergo a phase transition from NaCl-type structure (Fm3m) to CsCl-type structure (P4/mmm) at 19.04 GPa and 17.22 GPa, respectively. With the elevation of the pressure, C2/m-LaP and Imma-LaAs are the most stable structures up to 70.08 GPa and 85.53 GPa, respectively. Finally, the analy…
Lanthanide complexation with CMPO and CMPO-calix[4]arenes in solution: spectrophotometric and electrospray mass spectrometric approaches.
2007
The binding of lanthanide(III) cations with organophosphorous ligands like CMPO and related calix[4]arene-based derivatives have been investigated using two experimental methods. The stability constants of the lanthanum, europium and ytterbium complexes were first determined in methanol by UV absorption spectrophotometry in the presence of nitrate or chloride anions. The results showed that the stoichiometry and the stability of the complexes formed depend on the position of the CMPO moieties either on the wide or the narrow rim of the calixarene scaffold, the nature of the medium, the conformational mobility of the ligands. Complexation of lanthanum was also followed by ESI-mass spectromet…
Hydrogen bond-mediated conjugates involving lanthanide diphthalocyanines and trifluoroacetic acid (Lnpc2@TFA): Structure, photoactivity, and stability
2020
The interaction between lanthanide diphthalocyanine complexes, LnPc2 (Ln = Nd, Sm, Eu, Gd, Yb, Lu
Nodal Solutions for Supercritical Laplace Equations
2015
In this paper we study radial solutions for the following equation $$\Delta u(x)+f (u(x), |x|) = 0,$$ where $${x \in {\mathbb{R}^{n}}}$$ , n > 2, f is subcritical for r small and u large and supercritical for r large and u small, with respect to the Sobolev critical exponent $${2^{*} = \frac{2n}{n-2}}$$ . The solutions are classified and characterized by their asymptotic behaviour and nodal properties. In an appropriate super-linear setting, we give an asymptotic condition sufficient to guarantee the existence of at least one ground state with fast decay with exactly j zeroes for any j ≥ 0. Under the same assumptions, we also find uncountably many ground states with slow decay, singular gro…